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1 Polish Journal of Applied Chemistry

1 2002

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Synthesis of titanium-silicalite catalysts

Wróblewska A., Milchert E.

Polish Journal of Applied Chemistry

2002

Vol. 46, nr 3-4

151-175

Use of the clathrating compounds and the synthesis methods of the following titanium-silicalite catalysts: TS-1, TS-2, TS-48, ETS-10, [Al,Ti]-BETA were presented. A brief description of their catalytic performance in the oxidation process of olefins, alkanes, alcohols and aromatic compounds was reported. The results of analyses of the catalysts by IR, UV-VIS, XRD, 13C NMR, SEM, TG and DTG methods were also presented. Further directions of our works over the synthesis of titanium-silicalite catalysts and their utilization in the epoxidation processes of the olefine compounds (allyl alcohol, methallyl alcohol, methallyl chloride) and in the hydroxylation of phenol have been discussed. A potential application of obtained products was presented and the possibilities of implementation of developed, low-tonnage technologies of these compounds in Poland were discussed.