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Thermochemical and Spectral properties of Hydrates of Co(II), Ni(II) and Cu(II) Maleate. Crystal Structure of Co(II) Maleate Trihydrate

Pajtasova M.

Polish Journal of Chemistry

2001

Vol. 75, nr 9

1209-1217

The crystal and molecular structure of Co(II) maleate trihydrate, Co(C4H2O4)_3H2O, was determined by direct method and Fourier techniques. The structure was refined by full-matrix least-squares methods to a weighted R factor of 0.0263, based on independent reflections. The compound is a three-dimensional coordination polymer with distorted octahedron geometry at each cobalt(II) centre. Each cobalt atom is six-coordinated through two oxygen atoms from water molecules and four oxygen atoms from four different maleate groups. The thermal decompositions of Co(mal)_3H2O, Ni(mal)_3H2O and Cu(mal)_H2O(mal = maleate) have been investigated by means of TG, DTG, DSC and IR spectra. The release of volatile molecules after heating is either a three-step process for Co(mal)_3H2O and Ni(mal)_3H2O or a two-step process for Cu(mal)_H2O.