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EN
In the paper critical role of including the right material parameters, as input values for computer modelling, is stressed. The presented model of diffusion, based on chemical potential gradient, in order to perform calculations, requires a parameter called mobility, which can be calculated using the diffusion coefficient. When analysing the diffusion problem, it is a common practice to assume the diffusion coefficient to be a constant within the range of temperature and chemical composition considered. By doing so the calculations are considerably simplified at the cost of the accuracy of the results. In order to make a reasoned decision, whether this simplification is desirable for particular systems and conditions, its impact on the accuracy of calculations needs to be assessed. The paper presents such evaluation by comparing results of modelling with a constant value of diffusion coefficient to results where the dependency of Di on temperature, chemical composition or both are added. The results show how a given deviation of diffusivity is correlated with the change in the final results. Simulations were performed in a single dimension for the FCC phase in Fe-C, Fe-Si and Fe-Mn systems. Different initial compositions and temperature profiles were used.
EN
The overall study objection is selection and optimization all available thermodynamic data required for using calculation of phase diagram (CALPHAD) technique within the Fe-C-Cr-Mn-Si-Ti system. Such data collected in the thermodynamic database can be used for predicting the phase constitution states of a given composition for Fe-based hardfacing materials, which often use in energy industry in order to increase the abrasion and impact wear resistance of equipment parts. In order to compare theroretical calculation results with experimental data, four different types of hardfacing were deposited using flux-cored arc welding. Microstructure and chemical composition of deposited layers was investigated using optical and scanning electron microscopy together with energy dispersive X-ray spectroscopy. Comparison of experimental and computed results shows that they are in good agreement in meaning of presence of all-important phase equilibrium regions. The developed database can be used for rational selection of hardfacing materials for energy industry equipment and reasonable choice of new alloying systems.
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