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Significant Influence of Annealing Temperature and Thickness of Electrode on Energy Conversion Efficiency of Dye Sensitized Solar Cell: Effect of Catalyst

Uddin J., Islam J. M. M., Khan S. M. M., Hoque E., Khan M. A.

International Letters of Chemistry, Physics and Astronomy

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2014

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Vol. 20, iss. 1

78--87

EN

Dye sensitized solar cell (DSSC) shows great promise as an alternative to conventional p-n junction solar cells due to their low fabrication cost and reasonably high efficiency. DSSC was assembled by using natural dye extracted from red amaranth (Amaranthus Gangeticus) as a sensitizer and different catalysts for counter electrode were applied for maximum energy conversion efficiency. Annealing temperature and thickness of electrode were also investigated and optimized. Catalyst, annealing temperature and thickness were optimized by the determination of cell performance considering photoelectrochemical output and measuring current and voltage; then calculating efficiency and other electrical parameters. The experimental results indicated that samples having 40 μm electrode thickness and prepared at 450 o C annealing temperature showed the best performance.

2

Thermal Properties of Carbon Nanotube (CNT) Reinforced Polyvinyl Alcohol (PVA) Composites

Hasan M., Das S. K., Islam J. M. M., Gafur Md. A., Hoque E, Khan M. A.

International Letters of Chemistry, Physics and Astronomy

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2013

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Vol. 12

59--66

EN

Homogeneous Polyvinyl alcohol (PVA)/Carbon nanotube (CNT) composite has been prepared by solution casting method using gum acacia as a surfactant. CNT content in the composite was varied from 5-10 % by weight. The thermal properties of PVA/CNT composites were investigated by Thermo Gravimetric/Differential Thermal Analyzer (TG/DTA) and Thermo Mechanical Analyzer (TMA). TG/DTA results showed that higher thermal stability in higher percentage of CNT in the composites. The 10 % CNT containing PVA composite exhibit highest onset of melting, glass transition point and offset of melting temperature and the recoded values are 330.4K, 379K and 421.3K respectively. All of the result indicates that the developed PVA/CNT composite might be promising for use in solar cell application.

3

Development of Electrically Conductive Nanocrystalline Thin Film for Optoelectronic Applications

Das S K., Islam J. M. M., Hasan M., Kabir H., Gafur Md. A., Hoque E., Khan M. A.

International Letters of Chemistry, Physics and Astronomy

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2013

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Vol. 10, iss. 1

90-101

EN

Sodium alginate (TiO2) sand composites were prepared by solution casting. Purified sand was added in the composite films to increase electrical conductivity. Electrical properties such as conductivity, capacitance, dielectric constant, and loss tangent of the composites were investigated. The current voltage characteristics for all the composites showed ohmic behavior. All the electrical properties have been found to improve with the incorporation of sand (SiO2) but 6 % sand containing composite exhibits the best electrical properties. The mechanical properties tensile strength (TS), elongation at break (Eb) and Young modulus for 6 % sand containing composite film are found to be 4.445 MPa, 9.76 %, and 72.8 MPa respectively. The experimental results reveal that the blended films exhibit higher stability and improved mechanical properties of both tensile strength and elongation at break in dry state. Water absorption properties of the composites are found to decrease with the increase of sand content. Lowest water uptake properties and highest stability were demonstrated by 6 % sand containing sample. Electrically conductive composite films have useful applications for solar cells and optoelectronics. Thus, this study is very much expected to aid in the design and selection of proper composite for the potential application of solar cell and optoelectronics.