Wyniki wyszukiwania - BazTech

Ograniczanie wyników

Znaleziono wyników: 2

Liczba wyników na stronie

Wyniki wyszukiwania

Sortuj według:

Ogranicz wyniki do:

DBSA doped polypyrrole blended with Poly(4-styrenesulfonic acid) by mechanical mixing

Jayamurugan P, Ponnuswamy V, Ashokan S, Jayaprakash R N, Ashok N, Guna K, Mariappan R

Materials Science Poland

2014

Vol. 32, No. 4

648--651

DBSA doped polypyrrole was prepared by In-situ chemical oxidative polymerization method. The reaction temperature was 0 to 20 ◦C. Different weight percentages of PSS (40 wt.%, 60 wt.% and 80 wt.%) were mechanically blended with a pestle in an agate mortar for 25 minutes by solid state mixing. The investigation of the blend focused on the optical, structural and morphological properties. SEM micrographs indicated that PSS was homogeneously distributed within DBSA doped PPy. FT-IR study confirmed the doped and blended dopants in the composite structure. UV-study revealed the π → π* transition in benzenoid rings of DBSA and presence of PSS. The semi-crystalline nature of the composites improved with increasing the weight percentage of PSS.

Structural and optical characterization of SnS thin films by electrodeposition technique

Mariappan R., Ragavendar M., Ponnuswamy V.

Optica Applicata

2011

Vol. 41, nr 4

989--997

SnS thin films were electrodeposited on ITO (indium tin oxide) glass substrates maintained at different temperatures using aqueous solutions containing 33 mM of SnCl2 and 91 mM of Na2S2O3ź5H2O. The films were characterized to study the structural, morphological and optical properties. The X-ray diffraction studies of the films show the polycrystalline nature with orthorhombic crystal structure. Microstructural parameters such as crystallite size, microstrain, and dislocation density were calculated with respect to various temperatures. The scanning electron microscope (SEM) studies reveal good surface morphology with a large number of grains at the optimized temperature. The optical band gap of the SnS film was determined from optical transmittance data, in the spectral range 400-1100 nm and the direct band gap energy (Eg) was found to be 1.2 eV, which does agree well with earlier reported values. Fourier transform infrared spectroscopy (FTIR) studies confirm the presence of SnS films in the molecular structure.