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Synthesis, growth, structural, thermal and third order nonlinear optical properties of novel organic single crystal: 4-methylpyridinium 3-nitrophthalate

Reena Devi S., Suresh S., Kalaiyarasi S., NizamMohideen M., Mohan Kumar R.

Materials Science Poland

2018

Vol. 36, No. 4

597--608

A novel 4-methylpyridinium 3-nitrophthalate (4MP3NP) was synthesized and the crystals were grown by using slow evaporation method. The structural data of the grown crystal was collected by single crystal X-ray diffraction. It revealed that the 4MP3NP crystal belongs to triclinic crystal system with a space group P1. Structure of the synthesized compound was established using SHELXL 97 program package. The crystalline nature and composition of the grown crystal was established using high resolution X-ray diffraction and FT-IR analyses. UV-Vis transmittance and photoluminescence studies revealed the optical transmission window and electronic transition mechanism of ions, respectively. The laser damage threshold of the grown crystal was estimated by Nd:YAG laser and these results were mutually related to specific heat capacity of the grown crystal. The third-order nonlinear optical susceptibility of the grown crystal was studied by Z-scan technique.

Investigation on growth, optical and thermal properties of stilbazolium derivative crystal: 4-N,N-dimethylamino-40-N0-methylstilbazolium 2,4-dimethylbenzenesulfonate

Md Zahid I., Kalaiyarasi S., Kumar M. K., Ganesh T., Jaisankar V., Kumar R. M.

Materials Science Poland

2016

Vol. 34, No. 4

811--818

Metathesis ionic exchange reaction process was used to synthesize a novel nonlinear optical material: 4-N,N-dimethylamino-4′- N′-methylstilbazolium 2,4-dimethylbenzenesulfonate (DSDMS). The growth of DSDMS single crystals was carried out by adopting the solution growth technique. The crystal perfection and lattice parameters were elucidated from single XRD and powder XRD, respectively and its morphology was interpreted by WinXMorph program. FT-IR and Raman spectral analyses confirmed the existence of functional groups and their corresponding vibrational modes. UV-Vis spectral studies revealed the optical transmission region. Mechanical stability of the crystal was determined from Vickers microhardness number Hv, Meyer’s index n and elastic stiffness constant C11. Dielectric and thermal behavior of the grown crystal were elucidated by using impedance analyser and thermogravimetric analysis.