Przedstawiono aktywność powierzchniową oraz właściwości chwastobójcze amoniowych oraz pirydyniowych cieczy jonowych zawierających w swej strukturze anion [MCPA].
EN
Four ionic liqs. with 2-Me-4-ClC6H3OCH2COOө anion were studied for herbicidal activity against white mustard under std. conditions. The ionic liqs. showed higher efficiency than a com. herbicide used for comparison.
2
Dostęp do pełnego tekstu na zewnętrznej witrynie WWW
Amethod for the decomposition of ionic liquid (ILs) by photocatalysis has been demonstrated. The participation of ILs in light absorption by TiO2 was shown. The IL molar mass influence on photocatalytic decomposition was proven. The samples with a lower molarmass had higher stability under UVlight in the presence of TiO2. The degree of decomposition depends upon the cation and anion. The easiest to degrade proved to be ILs with a long alkyl substituent. Ammonium ILs (choline derivatives) with hydroxyl group proved to bemore stable than with acetyl group. Themost readily decomposable salts are phosphonium ionic liquids.
New room temperature ionic liquids - choline derivatives were prepared by Menschutkin reaction with alkyl chloromethyl ethers and anion changed to bis(trifluoromethylsulfonyl) amide ion. The newly obtained butoxymethyl(2-hydroxyethyl)dimethylammonium bis(trifluoromethanesulfonyl)amide was successfully tested as a solvent for O-acylation in two-phase reaction system. The ionic liquid-catalyst system was recycled and reused.
Several new quaternary ammonium chlorides, analogues of choline, were prepared by reaction of 2-(dimethylamino)ethanol and its derivatives with chloromethyl alkyl ethers. The obtained chlorides were examined in respect to their antielectrostatic effects: the surface resistance and half decay time on polyethylene film were measured. Application of rough set theory permitted to perform a comprehensive analysis of data and detection of structural-activity relationships. The obtained chlorides showed high antielectrostatic properties. The most active were quaternary ammonium chlorides with 11 and 12 carbon atoms in alkyl chain.
JavaScript jest wyłączony w Twojej przeglądarce internetowej. Włącz go, a następnie odśwież stronę, aby móc w pełni z niej korzystać.