Fluorenone (FTSCH) and p-anisaldehyde (ATSCH) thiosemicarbazones react with zinc(II) and cadmium(II) acetates forming M:L 1:2 complexes, characterized by IR, 1H and 13C NMR spectra and elemental analyses. The coordination mode of the ligands is discussed and four-coordinate, pseudo-tetrahedral structures are suggested.
Mercury(II) complexes, [Hg(FTSZ)Cl]2 and [Hg(TTSZH)Cl2] were prepared by reacting mercury(II) chloride and thiosemicarbazones derived from fuorenone and p-tolualdehyde. Complexes were characterized by IR, Raman, diffuse reflectance, 1Hand 13CNMR spectra and elemental analysis. Dimeric structure for [Hg(FTSZ)Cl]2 and monomeric tetrahedral for [Hg(TTSZH)Cl]2 were suggested.
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