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Investigation of Mechanical, Physical and Durability Properties of Metakaolin-Based Geopolymer

Ibrahim Wan Mastura Wan, Ibrahim Masdiyana, Azis Mohammad Zaki Bin, Abdullah Mohd Mustafa Al Bakri, Sauffi Ahmad Syauqi, Romisuhani Ahmad, Adnan Suraya Hani

Archives of Metallurgy and Materials

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2023

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Vol. 68, iss. 3

1069--1075

EN

Due to their potential to lower CO2 emissions linked with the cement and concrete industries, geopolymer binders are a desirable alternative for Portland cement binders. However, if they are to become a viable alternative to conventional Portland cement materials, their resilience in harsh conditions has to be further investigated. This paper presented mechanical and short-term durability properties of metakaolin based geopolymer concrete at sulphuric acid (H2SO4) solutions exposed with the concentrations of 2%, 3%, 4% and 5% for 14 days. (0%) or unexposed sample also prepared as referral and comparison. The geopolymer concretes were synthesized using an alkali activation of sodium hydroxide (NaOH) and sodium silicate (Na2SiO3). The main objective of the study was to examine the durability and deterioration mechanism parameters like different acid percentages, changes in weight, compressive strength, density and water absorption. Morphology analysis also performed in this study. The results indicated that metakaolin geopolymer experienced some strength deterioration with increasing sulphuric concentration solutions which are from 32.58 MPa, 20.67 MPa and 4.25 MPa at unexposed (0%), 2% and 5% sulphuric acid immersion respectively. Furthermore, change in weight or mass loss and water absorption after the chemical attack resulted directly proportional to sulphuric acid concentration due to increment of crack on the sample. Among that, the metakaolin geopolymer submerged in 2% acid gives the optimum results in terms of durability, mechanical and physical qualities.

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Phase Analysis of Different Liquid Ratio on Metakaolin/Dolomite Geopolymer

Sauffi Ahmad Syauqi, Ibrahim Wan Mastura Wan, Al Bakri Abdullah Mohd Mustafa, Ibrahim Masdiyana, Ahmad Romisuhani, Zaidi Fakhryna Ahmad

Archives of Metallurgy and Materials

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2022

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Vol. 67, iss. 1

247--250

EN

Geopolymer is widely studied nowadays in various scope of studies. Some of the ongoing studies are the study of the various materials towards the geopolymer strength produced. Meanwhile, some of the studies focus on the mixing of the geopolymer itself. This paper discussed the phase analysis of metakaolin/dolomite geopolymer for different solid to the liquid ratio which was, 0.4, 0.6, 0.8, and 1.0, and the properties that affected the geopolymer based on the phases. The constant parameters in this study were the percentage of metakaolin and dolomite used. The metakaolin used was 80% meanwhile dolomite usage was 20%. Besides that, the molarity of NaOH used is 10M and the alkaline activator ratio used is 2.0. All the samples were tested at 28 days of curing. The results show that the 0.8 solid to the liquid ratio used gave better properties compare to other solid to liquid ratio. The phases analyzed were quartz, sillimanite, mullite, and faujasite. The 0.8 S/L ratio shows the better properties compared to others by the test of phase analysis, compressive strength morphology analysis, and functional group analysis.

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Effect of Solid-To-Liquids and Na2SiO3-To-NaOH Ratio on Metakaolin Membrane Geopolymers

Ibrahim Masdiyana, Wan Ibrahim Wan Mastura, Al Bakri Abdullah Mohd Mustafa, Sauffi Ahmad Syauqi, Vizureanu Petrica

Archives of Metallurgy and Materials

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2022

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Vol. 67, iss. 2

695--702

EN

Geopolymer is synthesized by polycondensation of SiO4 and AlO4 aluminosilicate complexes, tetrahedral frames linked with shared sialate oxygen. This paper studies the effect of the solids-to-fluids (S/L) and Na2SiO3/NaOH proportions on the preparing of metakaolin inorganic membrane geopolymer. By consolidating a mixture of metakaolin with sodium hydroxide, sodium silicate and foaming agent, the geopolymer membrane was made in required shape about 1 cm and cured at 80°C for 24 hours. After the curing process, the properties of the samples were tested on days 7. Sodium silicate (Na2SiO3) and sodium hydroxide (NaOH) solution were utilized as an alkaline activator with a NaOH fixation fixed at 10 M. The geopolymer inorganic membrane tests were set up with various S/L proportions (0.8, 1.0, 1.2 and 1.4) and Na2SiO3/NaOH proportions (0.5, 1.0, 1.5, 2.0 and 2.5). Aluminium (Al) powder as a foaming agent was used to create bubbles in porous structure and provide details on the development of membrane geopolymers. This metakaolin membrane, based on the geopolymer, was synthesized by a suspension that depends on the fast cementing mechanism of high-temperature slurries. Porous geopolymeric circles provided a homogeneous composition and quantitative distribution of pores. The water absorption, density, impact toughness testing and microstructure analyses were studied. However, considering the promising results, an adjustment in the mix design of the metakaolin inorganic membrane geopolymer mixtures could increase their mechanical properties without negatively affecting the mechanical properties and porosity, making these sustainable materials a suitable alternative to traditional porous cement concrete.