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1
Content available remote Postępy w kontroli emisji SO2 i NOx w chińskim przemyśle hutniczym
PL
Dokonano przeglądu najnowszych postępów w dziedzinie technologii kontroli emisji SO₂ i NOₓ w przemyśle hutniczym w Chinach. Technologie mokrego odsiarczania gazów (WFGD), w tym metodę wapienną FGD z produkcją gipsu, dwualkaliczną FGD, amoniakalną FGD oraz magnezytową FGD stosuje się w 85,2% działających instalacji odsiarczania. Metody te charakteryzuje dojrzałość, duża wydajność oraz zadowalające możliwości dostosowawcze. Mimo to największymi problemami pozostają korozja, wtórne zanieczyszczenie powietrza oraz niepożądane produkty uboczne. W porównaniu z technologiami WFGD technologie suchego i półsuchego odsiarczania mają mniejszy udział w rynku, pomimo małego zużycia rozpuszczalników i małego wtórnego zanieczyszczenia powietrza. Technologia de-NOx dla przemysłu hutniczego wciąż pozostaje na wczesnym etapie rozwoju, zaś w chińskim przemyśle hutniczym pracuje obecnie zaledwie kilka instalacji de-NOx. W technologii selektywnej redukcji katalitycznej (SCR) drzemie wielki potencjał dotyczący kontroli emisji NOₓ, pod warunkiem że katalizatory niskotemperaturowe będą dostępne w rozsądnych cenach. Trwa rozwój technologii jednoczesnego usuwania SO₂ i NOₓ, tak aby sprostać surowym normom emisji zanieczyszczeń powietrza dla przemysłu hutniczego w Chinach.
EN
A review, with 53 refs., of wet and semi-dry flue gas desulfurization technols. as well as of processes for catalytic redn. of N oxides. In particular, maturity, high efficiency, reasonable adaptability, corrosion, secondary air pollution, and unwanted byproducts were taken into consideration.
2
Content available remote On the longest runs in Markov chains
EN
In the first n steps of a two-state (success and failure) Markov chain, the longest success run L(n) has been attracting considerable attention due to its various applications. In this paper, we study L(n) in terms of its two closely connected properties: moment generating function and large deviations. This study generalizes several existing results in the literature, and also finds an application in statistical inference. Our metod on the moment generating function is based on a global estimate of the cumulative distribution function of L(n) proposed in this paper, and the proofs of the large deviations include the Gärtner-Ellis theorem and the moment generating function.
EN
Ship collision-avoidance trajectory planning aims at searching for a theoretical safe-critical trajectory in accordance with COLREGs and good seamanship. In this paper, a novel optimal trajectory planning based on hybrid genetic algorithm is presented for ship collision avoidance in the open sea. The proposed formulation is established based on the theory of the Multiple Genetic Algorithm (MPGA) and Nonlinear Programming, which not only overcomes the inherent deficiency of the Genetic Algorithm (GA) for premature convergence, but also guarantees the practicality and consistency of the optimal trajectory. Meanwhile, the encounter type as well as the obligation of collision avoidance is determined according to COLREGs, which is then considered as the restricted condition for the operation of population initialization. Finally, this trajectory planning model is evaluated with a set of test cases simulating various traffic scenarios to demonstrate the feasibility and superiority of the optimal trajectory.
EN
The paper addresses an important issue in surface vessel motion control practice that the ship dynamics and sailing performance can be affected by speed loss. The vessel speed is significantly decreased by the added resistance generated by waves. An adaptive sliding mode course keeping control design is proposed which takes into account uncertain ship dynamics caused by forward speed variations, while avoiding performance compromises under changing operating and environmental conditions. The sliding mode control provides robust performance for time-varying wave disturbances and time-varying changes in ship parameters and actuator dynamics. After combining the unknown but bounded system uncertainties, the design of the adaptation law is obtained which is based on the Lyapunov’s direct method. Simulations on a ship with two rudders illustrate the effectiveness of the proposed solution.
EN
Application of 1-butyl-3-metyhlimidazaolium hexafl uorophosphate ([C4mim][PF6 ]), in the extraction of rubidium and cesium from brine solutions using 1,4,7,10,13,16-hexaoxacyclooctadecane (18C6) as extractant was investigated. Parameters that affect the extraction including pH of aqueous phase, equilibration time, dosage of the ionic liquid, phase ratio, concentration of 18C6 were studied. Under the optimal conditions, the single extraction effi ciency of rubidium ions and cesium ions were up 84.11% and 94.99%, respectively. The stripping of alkali metal ions from the loaded organic phase with different stripping agents and concentrations were also investigated. The initial value of the K/Cs and K/Rb ratios were 93.0 and 104.3, respectively, which have dropped 91.21% and 88.01%, respectively, after the extraction and stripping experiments. It was taken a big step in the separation and enrichment of cesium (rubidium) ion and potassium ion. The extraction mechanism was revealed most likely to be a cation exchange mode in this system.
EN
It is well documented that unavoidable ions in a pulp such as Mg2+, Ca2+, and K+ have a significant effect on the interaction for particles, especially for flotation of metallic sulfide minerals and clay minerals. In this study, the effect of electrolytes on the flotation of inherently hydrophobic mineral-graphite was studied. It was found that the zeta potential showed a dramatic decrease, and the reagent adsorption capacity of mineral enhanced in the present of electrolytes. The possible mechanism responsible for improved recovery was investigated by electrokinetic, surface tension and ions adsorption tests. It is likely that the hydrophobic force is stronger than the electrostatic force due to the reduced potential of graphite. This might be in favor of the formation of hydrophobic oil film leading to an increase in the graphite floatability. The experiments provided a new spectacle to study inherently hydrophobic mineral processing with electrolyte solution.
EN
The three-dimensional (3D) coordinate measurement of radio frequency identification (RFID) multi-tag networks is one of the important issues in the field of RFID, which affects the reading performance of RFID multi-tag networks. In this paper, a novel method for 3D coordinate measurement of RFID multi-tag networks is proposed. A dual-CCD system (vertical and horizontal cameras) is used to obtain images of RFID multi-tag networks from different angles. The iterative threshold segmentation and the morphological filtering method are used to process the images. The template matching method is respectively used to determine the two-dimensional (2D) coordinate and the vertical coordinate of each tag. After that, the 3D coordinate of each tag is obtained. Finally, a back-propagation (BP) neural network is used to model the nonlinear relationship between the RFID multi-tag network and the corresponding reading distance. The BP neural network can predict the reading distances of unknown tag groups and find out the optimal distribution structure of the tag groups corresponding to the maximum reading distance. In the future work, the corresponding in-depth research on the neural network to adjust the distribution of tags will be done.
EN
Warranty claims data contain valuable information about the quality and reliability of products. The monitoring and early-warning of warranty claims data are of great significance to the manufacturer by identifying and solving the emerging quality or reliability problem as soon as possible. However, though it has been used widely in the automobile industry, there are no studies that have been carried out on the monitoring and early-warning of claims data for products sold with two-dimensional warranty. In order to fill this gap, fitting the two-dimensional warranty claims data with accelerated failure model (AFT), a multi-stage riskadjusted control chart is proposed by this paper, for which a reasonable product sales tracking time and a monitoring time are suggested to reduce the influence of sales delay and fluctuating claim rates. Comparing with traditional Cumulative Sum Control Chart (CUSUM), the applicability and availability of the proposed model are demonstrated in the final.
PL
Roszczenia gwarancyjne stanowią cenne źródło informacji na temat jakości i niezawodności produktów. Monitorowanie danych dotyczących roszczeń gwarancyjnych i wczesne ostrzeganie w oparciu o te dane ma wielkie znaczenie dla producenta, ponieważ pozwala rozpoznawać i rozwiązywać pojawiające się problemy związane z niezawodnością w jak najkrótszym czasie. Chociaż ten rodzaj monitorowania i wczesnego ostrzegania jest szeroko stosowany w przemyśle motoryzacyjnym, nie przeprowadzono dotąd żadnych badań na temat tych procesów w odniesieniu do produktów sprzedawanych z gwarancją dwuwymiarową. W celu wypełnienia tej luki, dane o reklamacjach składanych na podstawie gwarancji dwuwymiarowych dopasowano modelem uszkodzeń przyspieszonych (accelerated failure model, AFT), a następnie przedstawiono koncepcję karty kontrolnej monitorowania wieloetapowego z korektą ryzyka, dla której zaproponowano odpowiedni czas śledzenia sprzedaży produktu i czas monitorowania, mając na uwadze zmniejszenie wpływu opóźnień w sprzedaży i wahań liczby roszczeń zgłaszanych z tytułu gwarancji. Możliwości zastosowania i dostępność proponowanego modelu porównano z tradycyjną kartą sum skumulowanych.
EN
Active contour model is a typical and effective closed edge detection algorithm, which has been widely applied in remote sensing image processing. Since the variety of the image data source, the complexity of the application background and the limitations of edge detection, the robustness and universality of active contour model are greatly reduced in the practical application of edge extraction. This study presented a fast edge detection approach based on global optimization convex model and Split Bregman algorithm. Firstly, the proposed approach defined a generalized convex function variational model which incorporated the RSF model’s principle and Chan’s global optimization idea and could get the global optimal solution. Secondly, a fast numerical minimization scheme based on split Bregman iterative algorithm is employed for overcoming drawbacks of noise and others. Finally, the curve evolves to the target boundaries quickly and accurately. The approach was applied in real special sea ice SAR images and synthetic images with noise, fuzzy boundaries and intensity inhomogeneity, and the experiment results showed that the proposed approach had a better performance than the edge detection methods based on the GMAC model and RSF model. The validity and robustness of the proposed approach were also verified.
EN
The frictional resistance coefficient of ventilation of a roadway in a coal mine is a very important technical parameter in the design and renovation of mine ventilation. Calculations based on empirical formulae and field tests to calculate the resistance coefficient have limitations. An inversion method to calculate the mine ventilation resistance coefficient by using a few representative data of air flows and node pressures is proposed in this study. The mathematical model of the inversion method is developed based on the principle of least squares. The measured pressure and the calculated pressure deviation along with the measured flow and the calculated flow deviation are considered while defining the objective function, which also includes the node pressure, the air flow, and the ventilation resistance coefficient range constraints. The ventilation resistance coefficient inversion problem was converted to a nonlinear optimisation problem through the development of the model. A genetic algorithm (GA) was adopted to solve the ventilation resistance coefficient inversion problem. The GA was improved to enhance the global and the local search abilities of the algorithm for the ventilation resistance coefficient inversion problem.
PL
Współczynnik oporu oporu wentylacji jezdni w kopalni węgla jest bardzo ważnym parametrem technicznym w projektowaniu i renowacji wentylacji kopalnianej. Obliczenia oparte na wzorach empirycznych i badaniach terenowych w celu obliczenia współczynnika oporu mają ograniczenia. W niniejszym badaniu proponuje się inwertowaną metodę obliczania współczynnika oporu wentylacji kopalni za pomocą kilku reprezentatywnych danych dotyczących przepływu powietrza i ciśnienia w węzłach. Model matematyczny metody inwersji jest opracowywany na zasadzie najmniejszych kwadratów. Zmierzone ciśnienie i obliczone odchylenie ciśnienia wraz z zmierzonym przepływem i obliczonym odchyleniem przepływu są uwzględniane przy określaniu obiektywnej funkcji, która obejmuje również ciśnienie w węźle, przepływ powietrza i ograniczenia współczynników oporu wentylacji. Problem odwrotności współczynnika oporu wentylacji został przekształcony w nieliniowy problem optymalizacji poprzez opracowanie modelu. Zastosowano algorytm genetyczny (GA) w celu rozwiązania problemu inwersji współczynnika oporu wentylacji. GA został ulepszony w celu zwiększenia globalnych i lokalnych możliwości wyszukiwania algorytmu problemu odwrotności współczynnika oporu wentylacji.
EN
For most precious metal mines, cemented tailings backfill slurry (CTBS) with different cement-sand ratio and solid concentration are transported into the gobs to keep the stability of the stope and mitigate environmental pollution by mine tailing. However, transporting several kinds of CTBS through the same pipeline will increase the risk of pipe plugging. Therefore, the joint impacts of cement-sand ratio and solid concentration on the rheological characteristics of CTBS need a more in-depth study. Based on the experiments of physical and mechanical parameters of fresh slurry, the loss of pumping pressure while transporting CTBS with different cement-sand ratio, flux and solid mass concentration were measured using pumping looping pipe experiments to investigate the joint impacts of cement-sand ratio and solid concentration on the rheological characteristics of CTBS. Meanwhile, the effect of different stopped pumping time on blockage accident was revealed and discussed by the restarting pumping experiments. Furthermore, Fluent software was applied to calculate the pressure loss and velocity distribution in the pipeline to further analysis experimental results. The overall trends of the simulation results were good agreement with the experiment results. Then, the numerical model of the pipeline in the Sanshandao gold mine was conducted to simulate the characteristics of CTBS pipeline transportation. The results show that the pumping pressure of the delivery pump can meet the transportation requirements when there is no blockage accident. This can provide a theoretical method for the parameters optimizing in the pipeline transportation system.
PL
W większości kopalń metali szlachetnych zawiesina zawierająca odpady poflotacyjne wraz z cementem w różnych proporcjach cementu i piasku oraz o różnym stężeniu części stałych transportowana jest do wyrobisk i zrobów, gdzie wykorzystywana jest następnie do stabilizacji w rejonie przodka, ponadto w ten sposób ogranicza się zanieczyszczenie środowiska odpadami poflotacyjnymi. Jednakże przetłaczanie różnych rodzajów zawiesin w tym samym układzie rurociągu zwiększa ryzyko zaczopowania rur. Zbadanie wpływu proporcji cementu do piasku w zawiesinie oraz stężenia części stałych na charakterystykę reologiczną zawiesiny wydaje się kwestią kluczową. W oparciu o badania eksperymentalne fizycznych i mechanicznych parametrów świeżej zawiesiny, dokonano pomiarów spadku ciśnienia pompowania w trakcie przetłaczania zawiesin o zawartości cementu i pisaku w różnych proporcjach, dla różnych natężeń przepływu i stężeń części stałych w eksperymentach z wykorzystaniem linii obiegowej rurociągu. Celem eksperymentu było określenie łącznego wpływu proporcji cementu do piasku oraz stężenia części stałych na właściwości reologiczne zawiesiny. Ponadto, przeanalizowano w jaki sposób długość przerw w procesie przetłaczania wpływa na zwiększenie ryzyka zatkania rur i przeprowadzono eksperymenty polegające na wznowieniu pracy pomp. Analizę wyników eksperymentów uzupełniono poprzez zastosowanie oprogramowania Fluent do obliczenia spadku ciśnienia w rurociągu oraz rozkładu prędkości. Wykazano, że wyniki symulacji pozostawały w dużej zgodności z wynikami eksperymentów. W kolejnym kroku opracowano model numeryczny rurociągu eksploatowanego w kopalni złota Sanshandao dla potrzeb symulacji procesu przetłaczania zawiesiny. Uzyskane wyniki wskazują, że ciśnienie tłoczenia w pompie jest na wymaganym poziomie gdy nie występuje zablokowanie przepływu w rurze, i wykorzystane być mogą jako uzupełnienie teoretycznych metod optymalizacji parametrów układu transportowania i przetłaczania zawiesiny.
EN
Ludwigite is the main available boron-bearing resource in China. In order to enrich the theory system and optimize its utilization processes, this paper study the mechanism and kinetics on non-isothermal decomposition of ludwigite in inert atmosphere by means of thermal analysis. Results show that, the decomposition of serpentine and szajbelyite is the main cause of mass loss in the process. At the end of decomposition, hortonolite and ludwigite are the two main phases in the sample. The average E value of structural water decomposition is 277.97 kJ/mol based on FWO method (277.17 kJ/mol based on KAS method). The results is proved to be accurate and reliable. The mechanism model function of structural water decomposition is confirmed by Satava method and Popescu method. The form of the most probable model function is G(α) = (1 – α)–1– 1 (integral form) and f (α) = (1 – α)2 (differential form), and its mechanism is chemical reaction. This is verified by the criterion based on activation energy of model-free kinetics analysis.
EN
The grinding hardening is an integrated manufacturing technology which combines the surface hardening theory and the grinding technology. However, the grinding chatter accompanies with the whole grinding hardening process. It is the existence of the grinding chatter that makes the transformation unsteady. To this end, the paper presents a three-hybrid model to investigate the relationship between the grinding chatter and the grinding hardening layers distribution. The dynamic grinding force with the analytic and numerical method is calculated firstly. Then the finite difference method (FDM) is used to obtain the dynamic temperature distribution accordingly. Thirdly, the cellular automata (CA) method is applied to calculate the transformed microstructure distribution under different chatter strengths. The study shows that the thickness of the grinding hardening layers goes up with the increase of the grinding chatter. However, the quality of the grinding hardening layers reduces with the increase of the chatter strength. In addition, the martensite content varies with different hardening layers since each layer has its own unique temperature distribution. Moreover, metallurgical experiments are conducted to validate the proposed model. The model is anticipated to be meaningful for the improvements of workpiece's mechanical properties by controlling the chatter strength in the industry manufacturing.
EN
Azimuthally averaged power spectra are widely used in the Curie point depth (CPD) estimation with the implicit assumption that the magnetization distribution is random and uncorrelated. However, the marine magnetic anomalies are caused by bands of normal and reverse magnetization and show obvious trends. To investigate the effects of the anisotropy of marine magnetic anomalies on the CPD estimates, we develop 3D fractal striped magnetization models to produce lineated marine magnetic anomalies for the first time. We analyze the spectra anisotropy of the lineated magnetic anomalies of the synthetic fractal striped magnetization models and investigate its effects on the CPD estimates. The synthetic models and actual data show that the spectra of the lineated marine magnetic anomalies are directionally anisotropic. The amplitude response is strong and the slope of the logarithmic spectrum is large in a direction perpendicular to the stripes of magnetic anomalies, whereas the amplitude response is weak and the slope of the logarithmic spectrum is small in a direction parallel to the stripes of magnetic anomalies. The depth estimates in the perpendicular direction are close to the actual values, whereas the depths estimates in the parallel direction are significantly lower than the actual values. The actual marine magnetic anomalies of the South China Sea exhibit an anisotropic power spectrum that is consistent with the spectral anisotropy of magnetic anomalies of the synthetic fractal striped magnetization models.
EN
The Fankou zinc concentrate (Guangdong province, China) was mineralogically characterized and results showed that the main germanium-bearing minerals in the sample comprised of zinc sulfide and galena, whereas gallium-bearing minerals were pyrite, sphalerite and silicate. Oxygen pressure leaching of zinc sulfide concentrate was carried out in order to investigate the effect of pressure, leaching time, sulfuric acid and copper concentrations on the leaching behavior of gallium and germanium. Under optimum conditions, leaching of Zn, Fe, Ge and Ga reached 98.21, 90.45, 97.45 and 96.65%, respectively. In the leach residues, it was determined that some new precipitates, such as PbSO4, CaSO4 and SiO2, were formed, which co-precipitated a certain amount of Ga and Ge from the leach solution. The results clearly indicated that Ga and Ge were much more difficult to leach than Zn, and provided answers to why the leaching efficiency of Ga is 10% lower when compared to Ge.
EN
In this paper, we present a simple near-field probe model that is composed of an elongated ellipsoid and a finite metal truncated cone. The elongated ellipsoid has been shown to act as a protrusion or separate particle near a truncated cone apex with strong near-field enhancement under laser excitation. By controllably varying the length of the ellipsoid protrusion from the truncated cone, the truncated cone-ellipsoid probes can be adapted to the suitability of near-field probes. The effects of substrate material and excitation wavelength on the near field enhancement for different tip apexes are also discussed. In addition, we compared the properties of the truncated cone-ellipsoid probe with the widely used hemisphere conical tip by launching surface plasmon polaritons on plasmonic waveguides to prove the suitability of the truncated cone-ellipsoid probes as high performance near-field probes. The present simple model would provide a theoretical basis for the actual construction of probes.
EN
Known-plaintext attack is considered for decrypting the image generated by iterative random phase encoding in fractional Fourier transform domains. The double random phase encoding in Fourier domains is introduced to design the known-plaintext attack procedure. The decryption test is explored without both fractional order and these random phase masks. Some numerical simulations are made to demonstrate the validity of the known-plaintext attack.
EN
The influence of the surface metal fiber (SMF) arrangement on the shielding effectiveness (SE) of electromagnetic shielding fabric (EMSF) is important, but there is no reasonable description method for it at present, making the further exploration of the relationship between SMF and SE difficult. In order to scientifically describe the SMF arrangement of EMSF, this paper constructs a binary feature matrix of SMF based on a previous study of SMF region recognition. According to the feature matrix, three parameters of the exposure ratio, the discrete mean and disorder degree are proposed and the calculation equations for the three parameters given. Experiments were designed and testing samples determined to test the SE, and the exposure ratio, discrete mean and disorder degree of each sample are calculated. The relationship between the three parameters and the SE is analysed for effectiveness validation of the three parameters. Results show that the exposure ratio, discrete mean and disorder degree can describe three aspects of the SMF arrangement: the percentage content, porosity and orientation, which are positively correlated, negatively correlated and positively correlated to the SE, respectively. The research in this paper provides a basis for the study of the shielding mechanism, the transmission model, the shielding rule and the rapid non-destructive evaluation of the EMSF, and puts forward a new idea for the study of shielding theory and the application of the EMSF.
PL
Ze względu na istotny wpływ rozmieszczenia włókien metalowych (SMF) na skuteczność ekranowania (SE) tkanin osłonowych (EMSF) w pracy przedstawiono macierz binarną opartą na trzech parametrach włókien metalowych tj.: współczynniku ekspozycji, średniej wartości odległości między włóknami metalowymi i stopniu ich nieuporządkowania. Analizowano zależności pomiędzy wyżej wymienionymi parametrami a skutecznością ekranowania. Przedstawione wyniki stanowią podstawę do opracowania szybkiej i nieniszczącej metody oceny skuteczność ekranowania oraz do dalszych badań mechanizmu ekranowania.
EN
In China, the sintering process annually emitted around 1.5 million t SO2, representing 70% of SO2 produced from the iron and steel industry. Lime based sorbent was modified with municipal sewage sludge (MSS) and the influence of the modification on the desulfurization efficiency was investigated in a laboratory-scale novel integrated desulfurization (NID) reactor. The properties of modified sorbent were characterized by the Brunauer–Emmett–Teller (BET) analyzer and X-ray fluorescence (XRD) analyzer. BET surface area was increased from 17.48 to 46.68 m2g–1. when the MSS/lime ratio increased from 0 to 0.08. Ca4Al8Si8O32, Ca1.5SiO3.5, Na2Si2O5 and CaSiO3 found in the modified lime benefited for the increase of the BET surface area and pore volume. The effects of sewage sludge/CaO weight ratio, calcination temperature and hydration time on the desulfurization efficiency were also studied. SO2 removal efficiency was increased from 88.7% to 97.3% after using the lime modified with sewage sludge.
EN
This paper proposes a permanent magnet (PM)-assisted synchronous reluctance machine (PMASynRM) using ferrite magnets with the same power density as rareearth PM synchronous motors employed in Toyota Prius 2010. A suitable rotor structure for high torque density and high power density is discussed with respect to the demagnetization of ferrite magnets, mechanical strength and torque ripple. Some electromagnetic characteristics including torque, output power, loss and efficiency are calculated by 2-D finite element analysis (FEA). The analysis results show that a high power density and high efficiency of PMASynRM are obtained by using ferrite magnets.
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