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Spectroelectrochemical Behaviour of Poly(2,5-dithienylene-isothianaphthene) and Its Analogue Deuterated on the Benzene Ring

Łapkowski M., Kiebooms R., Gelan J., Vanderzande D., Proń A., Louarn G., Lefrant S.

Polish Journal of Chemistry

1999

Vol. 73, nr 8

1379-1389

Poly(2,5-dithienylene-isothianaphthene) and its analogue, deutered on the benzene ring, have been prepared by voltammetric polymerization of the corresponding monomers in Bu4NBF4/acetonitrile solutions. The polymers obtained are electroactive, showing in cyclic voltammograms two oxidation peaks associated with p-type doping and two reduction peaks, originating from the de-doping process.