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5 Prace Naukowe Instytutu Chemii i Technologii Nafty i Węgla Politechniki Wrocławskiej. Konferencje

5 2002

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The utilization of carbon oxide in commercial waste gases.

Zakumbaeva G. D., Shapovalova L. B., Gabdrakipov A. A., Zhurtbaeva A. A.

Prace Naukowe Instytutu Chemii i Technologii Nafty i Węgla Politechniki Wrocławskiej. Konferencje

2002

Vol. 10, nr 57

271-276

A systematic study of adsorptive and catalytic properties of supported Ru-Ce catalyst for utilization of carbon oxide (by using Fischer-Tropsch synthesis) has been carried out in this work. The main products of this reaction are C1-C8 olefins and parafins of iso- and normal chain structures. The structure and the active surface state of Ru-Ce-catalysts were studied by using the methods of XPS, XPD, electron microscopy, e-diffraction, IR-spectroscopy. The formation of bimetallic Ru-Ce clusters was shown. The rearranged surface clusters influence greatly the structures, chemisorption of CO and H2, and activity and selectivity of Ru-Ce/Al2O3 catalyst in the Fischer-Tropsch synthesis.

The bimetallic Co-containing supported catalysts for the production of high value hydrocarbons from carbon dioxide and methane via synthesis-gas.

Itkulova S. S., Zakumbaeva G. D.

Prace Naukowe Instytutu Chemii i Technologii Nafty i Węgla Politechniki Wrocławskiej. Konferencje

2002

Vol. 10, nr 57

265-270

Bimetallic Co-containing alumina-supported catalysts for CO2 reforming of methane and Fischer-Tropsch synthesis were studied. High activity, stability, and resistance to coke formation of the catalysts in both reactions was observed. High value hydrocarbon fractions such as gasoline, kerosene, diesel, olefins, etc. can be selectively produced from synthesis gas from CO2 reforming of methane over these catalysts depending on the nature and content of the second metal and process conditions.

Production of eco-friendly petrol over modified zeolite-containing catalyst.

Zakumbaeva G. D., Van T. V., Lyashenko A. I.

Prace Naukowe Instytutu Chemii i Technologii Nafty i Węgla Politechniki Wrocławskiej. Konferencje

2002

Vol. 10, nr 57

323-328

Pt-Re zeolite-containing catalysts of a high isomerization activity in reforming at mild conditions (T=623 K, P=1.0 MPa) are developed. The desired products which meet the environmental requirements were produced. The structure and active centers of catalyst were studied by TEM, BET, IR spectroscopy of CO adsorption, and TPR.

New catalytic process of conversion of light n-alkanes to components of the motor fuel.

Zakumbaeva G. D, Toktabaeva N. P., Gorbacheva L. V., Kubasheva A. Z., Lyashenko A. I.

Prace Naukowe Instytutu Chemii i Technologii Nafty i Węgla Politechniki Wrocławskiej. Konferencje

2002

Vol. 10, nr 57

337-341

It was studied the effect of temperature on the behavior of heterogeneous poly-functional catalyst in the process of the interaction of pentane with C3-C4-alkanes. Zeolite-containing catalysts carries out the reactions of dehydrogenation, isomerization, cyclization and alkylation of alkanes by one step.

Hydrodesulfurisation of gasoline fraction of oil over modified iron-containing catalysts.

Zakumbaeva G. D., Tuktin B. T., Gazizova A. D.

Prace Naukowe Instytutu Chemii i Technologii Nafty i Węgla Politechniki Wrocławskiej. Konferencje

2002

Vol. 10, nr 57

373-376

It was studied the effect of modified additives on the hydrodesulfurization activity of Fe-Mo/Al2O3 catalyst. Modified KTZ-11 and KTZ-12 catalysts have a high activity in hydrodesulfurization of gasoline oil fractions. The synthesized catalysts were studied by different physico-chemical methods.