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EN
In this paper, to produce a saleable magnetite concentrate with a sulfur level below 0.20% and recover sulfur concentrate, flotation and magnetic separation tests were undertaken. Results showed that the optimum conditions of flotation were established as follows: grinding fineness of 90% particles passing 0.074mm, pH 6, 400 g/t of CuSO4, and 400 g/t of combined collectors. Under these conditions and magnetic separation, S grade of the magnetite concentrate was reduced from 3.20% to 0.18%, and the Fe grade improved from 57.29% to 71.17%. At the same time a sulfur concentrate with S grade of 38.05% and recovery of 91.32% was also obtained. The XPS results showed that the addition of CuSO4 benefited the formation of hydrophobic Sn2-/S0 and Cu+-xanthate, enhancing pyrrhotite floatability. The flotation separation efficiency could be enhanced using a mixture of collectors, and collector mixture demonstrated three synergetic effects, namely enhanced S recovery, improved adsorption behavior of the collectors and enhanced hydrophobicity of pyrrhotite surface.
EN
Effects of temperature on Fe and Ti in carbothermic reduction of vanadium titanomagnetite (VTM) concentrate with adding MgO at 1100~1500℃ were investigated. It was found that most of Fe in the VTM concentrate existed in the form of magnetite and a small amount existed as ilmenite; Ti in the VTM concentrate was mainly present in the form of ilmenite. The temperature had significant effects on Fe and Ti: increasing temperature was beneficial to decrease the Fe content in the magnesium titanate mixture, and the Fe content could decrease to 5.47% at 1500℃. Thermodynamic analysis showed that FeTiO3 and MgO preferentially reacted to form Mg2TiO4, followed by MgTiO3 and MgTi2O5 when the temperature increased from 1100℃ to 1500℃. Results of X-ray diffraction and scanning electron microscopy-energy dispersive spectroscopy analyzes showed that an intermediate product of MgFe2O4 would formed at 1300~1400℃ in the actual experiment. This caused the Fe content in the magnesium titanate mixture to increase from 21.32% to 22.85% when the temperature increased from 1200℃ to 1400℃. In addition, the size of magnesium titanate particles could increase from a few microns to approximately 100 µm when the temperature increased from 1100℃ to 1500℃, which was conducive to realize the separation of metallic iron and magnesium titanate.
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