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Synthesis, Characterization and Catalytic Activity of the Manganese(III) - Schiff Base Complexes

Szypa M., Pelech R.

Polish Journal of Chemistry

2008

Vol. 82, nr 3

481-486

Symmetrical and un symmetrical mangaese(III) Schiff base complexes of the type [MnClLLc], (LLc = [ONNO] = symmetrical and unsymmetrical Schiff base derivatives of trans-1,2-diaminocyclohexane and 2-hydroxynaphthaldehyde as well as R-salicyl - aldehydes) were synthesized by the reactions of the appropriate Schiff base with Mn(CH3COO)3ź4H2O and lithium chloride. The complexes were characterized by elemental analysis, IR and UV-vis spectrometric methods. The catalytic activity of the prepared complexes was studied in the epoxidation of styrene and cyclohexene.