Wyniki wyszukiwania - BazTech

Ograniczanie wyników

2 Environment Protection Engineering

2 2014

Znaleziono wyników: 2

Liczba wyników na stronie

Wyniki wyszukiwania

Sortuj według:

Ogranicz wyniki do:

Investigation of sorption characteristics of anaerobically digested dewatered municipal sewage sludge

Varank G., Demir A., Bilgili M. S., Top S., Sekman E., Yazici S., Erkan H. S.

Environment Protection Engineering

2014

Vol. 40, nr 4

119--133

Physical, chemical, morphological properties and sorption characteristics of anaerobically digested dewatered municipal sewage sludge have been investigated including the surface area, pore size distribution, chemical composition, surface chemistry structure, surface physical morphology, mineralogy, cation exchange capacity, heavy metal content, total solid, total volatile solid, total Kjeldahl-N, total phosphorus content of the sewage sludge. The sorption potential of sewage sludge for the removal of 4-CP and 2,4-DCP from aqueous solutions was examined by investigating their adsorption isotherms and kinetics in a lab-scale batch study. Findings of this study clearly showed that sewage sludge provides chlorophenol removal in the landfill body as disposed with solid wastes.

Equilibrium and kinetic studies on the removal of heavy metal ions with natural low-cost adsorbents

Varank G., Demir A., Bilgili M. S., Top S., Sekman E., Yazici S., Erkan H. S.

Environment Protection Engineering

2014

Vol. 40, nr 3

43--61

Adsorption isotherms and kinetics of the removal of heavy metal ions (Ni, Pb, Zn) from aqueous solutions by natural adsorbents (zeolite, bentonite, clay) were investigated in a lab-scale batch study. The effect of various parameters such as adsorbent dosage, initial concentration of heavy metal ions, temperature, and agitation time were studied to optimise the conditions. Under those optimized conditions (180 rpm agitation rate, 120 min agitation time, pH 4.0, 298 K, 100 mg/dm3 initial adsorbate concentration), the removal percentages of heavy metal ions for natural adsorbents have been determined. The adsorption mechanisms and characteristic parameters of the process were analyzed by two and three parameter isotherm models (Langmuir, Freundlich, Temkin, Redlich-Peterson, Toth and Sips), and kinetic models (Lagergren's pseudo-first order, Ho and McKay's pseudo-second order). Adsorption thermodynamics of heavy metal ions (changes of standard enthalpy, entropy and free energy) on zeolite, bentonite and clay were also studied at 298,318 and 338 K.