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2 Polish Journal of Chemistry

2 1999

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Synthesis and Crystal Structure of Copper(I) Chloride P-Complex with 1-Allylbenzotriazole of CuCl.C6H4N3(C3H5) Composition

Goreshnik E.

Polish Journal of Chemistry

1999

Vol. 73, nr 8

1253-1258

By alternating-current electrochemical synthesis crystals of CuCl.C6H4H3(C3H5) P-complex (I) have been obtained and structurally investigated. Due to the coordination of Cu(I) atoms through the nitrogen atom and olefinic group of the same molecule, organometallic chains appear. bridged Cl atoms combine these chains into a three-dimensional framework.

Cation of N-Allylbenzothiazolium as a P-Ligand in Copper(I) Halide Complexes: Synthesis and Crystal Structure of [C7H5NS(C3H5)]+.CuCIcl2.H2O and [C7H5NS(C3H5)]+.CuCl1.06Br0.94.H2O Compunds

Goreshnik E., Mys'kiv M.

Polish Journal of Chemistry

1999

Vol. 73, nr 8

1245-1252

By alternating-current electrochemical synthesis crystals of [ ] P-complexes have been obtained and structurally characterized. Owing to the cationic form, the ligand is coordinated to Cu atom only through the C=C bond. Due to the bridge role of X(2) atom [X=Cl(I) or statistic mixture Cl, Br (II))}, cyclic fragments Cu2X2 appear.