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Transmission characteristics of 85Rb and 87Rb laser-induced dichroism atomic filters at 795 nm

Peng Y F, Zhang W J

Optica Applicata

2014

Vol. 44, nr 1

55--67

The transmission characteristics for 85Rb and 87Rb laser-induced dichroism atomic filters operating on rubidium D1 lines (795 nm) transitions are analyzed. By means of semiclassical density matrix equations of motion, a three-level model for the transmission characteristics of the ground state laser-induced dichroism atomic filter is presented. Calculative results show that this filter, using two counterpropagating pump and probe beams, can obtain higher transmission, narrower bandwidth and larger tuning capability than that using two copropagating pump and probe beams; with the aid of counterpropagating pump, the 85Rb ground state laser-induced dichroism atomic filter can be more effective to achieve higher peak transmission (>34%) and larger tunability (>1 GHz) than the 87Rb ground state laser-induced dichroism atomic filter in the same operation parameters. This result may be helpful for improving peak transmission (14.6%) of Rb ground state laser-induced dichroism atomic filter reported (CERÈ A. et al., Opt. Lett. 34(7), 2009, pp. 1012–1014).

Laser aerosol time-of-flight mass spectrometry analysis of individual aerosol particles from photooxidation of toluene

Hao L. Q., Zhou L.Z., Gu X. J., Fang L., Zhang W. J.

Optica Applicata

2006

Vol. 36, nr 1

5-13

A laser aerosol time-of-flight mass spectrometry (ATOFMS) that can be used for real-time measurement of the size and composition of individual aerosol particles has been designed and manufactured in our laboratory. Particles are introduced into the instrument through a particle beam interface, sized by measuring the delay time between two scattering lasers, and compositionally analyzed using a laser desorption/ionization linear-time-of-flight mass spectrometry. Secondary organic aerosol particles from the photooxidation of toluene in the CH3ONO/NO/air mixture were generated in a home-made smog chamber and measured using it. Experimental results showed that the individual aerosol particles from photooxidation of toluene can be measured in real-time by this instrument. This unique capability is impossible in off-line methods such as chromatography and chemical method.