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Distribution and characterization of organic matter within the sea surface microlayer in the Gulf of Gdańsk

Penezić Abra, Drozdowska Violetta, Novak Tihana, Gašparović Blaženka

Oceanologia

2022

No. 64 (4)

631--650

We present the characterisation and distribution of organic matter (OM) within the sea surface microlayer (SML) and underlying water (ULW) collected in October 2015 at nine stations in the Baltic Sea, Gulf of Gdańsk, encompassing the Vistula River plume. The salinity of >7 throughout the transect indicated Vistula plume was possibly displaced westward by the preceding northerly and easterly winds between 5.7 and 10.7 ms–1 during the sampling campaign. Spectral analysis pointed to the highest contribution of aromatic and high molecular weight molecules (lowest spectral slope (SR) ratios and highest absorption coefficient at 254 nm (aCDOM(254)) at the first two stations near the river mouth, demonstrating a very limited influence of the river plume. Concentrations of surface-active organic substances (SAS) ranged from 0.28 to 0.60 mg L−1 in eq. Triton-X-100 in SML, and from 0.22 to 0.47 mg L−1 in eq. Triton-X-100 in the ULW, while POC concentrations ranged from 0.27 to 0.84 mg L−1 in SML and from 0.20 to 0.37 mg L−1 in ULW. Enrichment of SAS and POC detected at the highest wind speeds indicates rapid SML recovery by OM transported from the ULW. Low lipids to POC contribution, on average 5% and 7% in SML and ULW respectively, points to eutrophic conditions. Statistically significant negative correlation between SR and the Lipid:PIG ratio in SML and ULW suggests the production of lower molecular weight OM by phytoplankton living under favourable environmental conditions. Accumulation of lipid reserves triacylglycerols (TG) in the SML indicates more stressful plankton growth conditions compared to ULW.

Effect of drag coefficient formula choice on wind stress climatology in the North Atlantic and the European Arctic

Wróbel-Niedźwiecka Iwona, Drozdowska Violetta, Piskozub Jacek

Oceanologia

2019

No. 61 (3)

291--299

Interactions between the atmosphere and the ocean determine boundary conditions for physical and biogeochemical processes in adjacent boundary layers, and the ocean surface is a complex interface where all air-sea fluxes take place and is a crucial valuable for ocean circulation and the ecosystem. We have chosen to study the differences between the relevant or most commonly used parameterizations for drag coefficient (CD) for the momentum transfer values, especially in the North Atlantic (NA) and the European Arctic (EA), using them together with realistic wind field. We studied monthly mean values of air-sea momentum flux resulting from the choice of different drag coefficient parameterizations, adapted them to momentum flux (wind stress) calculations using wind fields, sea-ice masks, as well as integrating procedures. We compared the resulting spreads in momentum flux to global values and values in the tropics, an area of prevailing low winds. We found that the spread of results stemming from the choice of drag coefficient parameterization was 14% in the Arctic, the NA and globally, but it was higher (19%) in the tropics. On monthly time scales, the differences were larger at up to 29% in the NA and 36% in the EA (in months of low winds) and even 50% locally (the area west of Spitsbergen). Comparing the values of drag coefficient from chosen parameterizations, it showed that momentum fluxes were largest for all months, in both regions with low and high winds, when the CD values increased linearly with wind speed.