Wyniki wyszukiwania - BazTech

Ograniczanie wyników

Znaleziono wyników: 2

Liczba wyników na stronie

Wyniki wyszukiwania

Sortuj według:

Ogranicz wyniki do:

Changes in appearance and chemical structure of chosen polymer materials under accelerated aging

Brzozowska-Stanuch A., Rabiej S., Stanuch W.

Polish Journal of Applied Chemistry

2011

Vol. 55, nr 3-4

123-132

Polymers, due to their versatility, have become indispensable in human life. In outdoor applications, all polymers degrade, resulting in a change in the properties of most polymers. Symptoms of polymer degradation include changes in esthetic appearance (e.g. discoloration, changes in gloss, chalking) and alteration of some specific polymer properties. In this study, polyamides 6 and 6.6 and polypropylene were subjected to UV irradiation and high temperature. The degradation was monitored using colour measurement and FTIR spectroscopy. The effect of deterioration in the material surface due to aging can be seen in its changes in colour (by altering its chemical structure), gloss and transparency. The colour measurement was performed in CIELAB system in tristimulus colour value L', a', b". FTIR spectroscopy measurements made it possible to show in a systematic way the changes in molecular structure of tested materials according to the process of aging, as well as possible mechanism of degradation.

Wpływ warunków przyspieszonego starzenia-promieniowania UV oraz temperatury na poliamidy i polipropylen

Brzozowska-Stanuch A., Rabiej S., Stanuch W.

Czasopismo Techniczne. Mechanika

2009

R. 106, z. 1-M

43-49

Praca zawiera wyniki badań wpływu promieniowania UV oraz temperatury na strukturę cząsteczkową wybranych materiałów polimerowych. Przyspieszone starzenie poliamidów oraz polipropylenu prowadzono przy użyciu komory klimatycznej Atlas Xsenon Weather Ometer serii Ci4000, stosując jako źródło promieniowania filtrowaną lampę ksenonową. Zachodzące zmiany w czasie procesu fotoutleniania monitorowano za pomocą metod FTIR i DSC. W badanych próbkach nastąpiły wyraźne zmiany w obszarach grup: hydroksylowej, karbonylowej a także w obszarze pasm krystalicznych poliamidów.

In this work, the influence of UV radiation and temperature on the molecular structure of chosen polymeric materials was investigated . Accelerated weathering of polyamides and polypropylene was performed by means of the Atlas Xsenon Weather Ometer series Ci4000 climatic chamber, using filtered xenon lamp as a light source. The effects of photo-oxidation were studied by FTIR spectroscopy and DSC method . A clear changes were observed in the investigated samples in hydroxyl and carbonyl regions as well as in the crystalline regions of polyamide