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1 2001

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Wstępne utlenianie domieszek wody dwutlenkiem chloru i usuwanie produktów ubocznych utleniania na przykładzie wodociągu Sulejów-Łódź

Grabowski Z., Rzerzycha B., Grabowska H., Wybór M., Cyran J., Solnica J.

Ochrona Środowiska

2001

nr 3

45-48

Sulejów-Łódź Waterworks have been supplying municipal water since 1973. Because of a comparatively high pollution level and a long distance from the Sulejów reservoir to the treatment plant, the water needs preoxidation. Till 1994, preoxidation was carried out with chlorine (up to 12 g/m[3] doses), which had the disadvantage of producing large amounts of chloroform (its concentration in treated water in some instances approached 110 mg/m[3]). The substitution of chlorine with chlorine dioxide reduced chloroform concentration in the water supplied to the user much below the admissible value (mg/m[3], compared to the admissible 30 mg/m[3]). A serious drawback of including ClO2 oxidation into the treatment train was the problem of how to reduce the formation of chlorites and chlorates, the by-products of the process. The chlorine dioxide doses ranged between 0.5 and 3.2 g/m[3] (1.5 g/m[3] on average). Total chlorite + chlorate content accounted for 13 to 57% of the ClO2 doses applied (37.6% being accounted for by chlorites which convened into chlorates as a result of ozonation). Since 1999, the Water Treatment Plant of Kalinko near Łódź has been operating a system (the first of that type in Poland), which reduces the quantity of chlorites (and consequently of chlorates) by 77% on average, with the use of FeSO4. The process, however, requires thorough supervision: Overdosage of the ferrous salt increases coloured matter concentration, turbidity and total iron, whereas insufficient dosage fails to provide complete removal of chlorites. The operating cost of the system averages USD 0.001/m[3] of water.