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EN
The safety of explosives is closely related to the stress state of the explosives. Under some stress stimulation, explosives may detonate abnormally. It is of great significance to accurately describe the mechanical response of explosives for the safety evaluation of explosives. The mechanical properties of polymer bonded explosives (PBXs) strongly depend on pressure. In this study, the mechanical behaviour of PBXs under confined conditions was investigated. It was found that the stress-plastic strain response of a PBX under high confining pressures is a combination of the non-linear and linear hardening portions. However, the linear hardening portion has often been neglected in characterizing the mechanical behaviour of a PBX under such pressures. The Karagozian and Case (K&C) model was applied to characterize the mechanical behaviour of PBXs. The numerical results demonstrated that when the confining pressure was high, the K&C model could not adequately match the experimental data due to the limitation of the damage model. Therefore, a new damage model was developed by means of considering intragranular damage and transgranular damage. This modification made it possible to introduce a linear hardening process into the original K&C model. The method proposed to describe the stress-strain results under high confining pressures was to consider the stress-plastic strain curve, including the nonlinear and linear hardening portions. The damage evolution of the original K&C model and a linear hardening model were applied for the nonlinear and linear hardening portions respectively. The influence of the linear hardening model on the damage evolution of the original K&C model was included when describing the nonlinear hardening portion. A comparison between simulation and experiment showed that the modified K&C model could well describe the mechanical response of PBXs under different confining pressures.
EN
The Lagrange test was conducted to investigate the shock ignition and growth of HMX-based polymer bonded explosives (PBXs) under different temperature conditions. In this study, three temperature conditions, 25 °C, 80 °C and 120 °C were used. The pressure history values along the direction of the detonation wave propagation were obtained and presented as the characteristics of the shock ignition and growth. Manganin piezoresistive pressure gauges were used to measure the pressure. The results showed that the distance to detonation was clearly reduced as the temperature was increased. A distance greater than 9 mm at 25 °C was changed to less than 3 mm at 120 °C. In order to understand this phenomenon in more detail, the Lee-Tarver ignition and growth model was employed to simulate the Lagrange test, and the simulated pressures were compared with the measured pressures. The results demonstrated that the intrinsic mechanism of the phenomenon was that the high temperature changed both the equation of state of the unreacted explosive and the chemical reaction rate. It was remarkable that the parameter R2 in the model was reduced from −0.05835 to −0.06338, and the parameter G1 in the model was increased from 1.3 to 2.12.
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