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2 Journal of Ecological Engineering

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Indonesia's Natural Zeolite as an Adsorbent for Toxic Gases in Shrimp Ponds

Anggoro Didi Dwi, Sumantri Indro, Buchori Luqman

Journal of Ecological Engineering

2021

Vol. 22, nr 6

202--208

The objective of this research was to produce safe water for shrimp by using zeolite as adsorbent to absorb unwanted substances (NH3 and H2S). In particular, this study also aimed to design the shrimp pond water treatment equipment, effect of flow rate on zeolite ability to absorb toxic gases (NH3 and H2S), and rate of absorption (K) and reaction (k). The adsorbent is zeolite which has adsorption properties, high surface area and pores suitable for water (3Å). Then, the concentration of ammonia, hydrogen sulfide was analyzed using Ammonia Test Kit and Hydrogen Sulphide of Hach Hydrogen Sulfide Test Kit. The materials used in this study were zeolite of Malang (East Java, Indonesia) and shrimp pond water. The best result of NH3 and H2S adsorption obtained at a flow rate of 3 L•min-1. The best adsorption constant value (K) achieved by a flow rate of 3 L•min-1. On the basis of the best value of R2, NH3 and H2S adsorption, it can be classified in the first-order kinetic model with R2 of 0.9763 and a k value of 0.0007 hours-1 with a flow rate of 6 L•min-1. From the data above, it can be calculated that the adsorbent needed in the adsorption of NH3 and H2S in a scale shrimp pond requires 18 kg of Malang zeolite with a column height of 3.62 m of adsorbent, a diameter of 2.07 m, and a column volume of 12.21 m3.

Inhibitory Effect of Sodium Benzoate as Preservative Material in the Biogas Production in a Batch Anaerobic Digestion Process

Sumantri Indro, Buchori Luqman, Anggoro Didi Dwi

Journal of Ecological Engineering

2020

Vol. 21, nr 8

120--128

Sodium benzoate has been used a food preservative worldwide. The effect of sodium benzoate as a preservative in the wastewater treatment was examined from the biogas formation viewpoint. The research was conducted in batch mode reactor systems employing various ratios of activated sludge and solution of sodium benzoate volume. The MLSS of activated sludge used was 12 g/L, while the volume ratios of activated sludge and sodium benzoate ranged from 0 to 100%. The concentrations of sodium benzoate used were 50, 100, and 200 mg/L. The biogas samples were measured every two days for 60 days. The results showed that the volume ratio of activated sludge and sodium benzoate of 60% and 40% was a turning point where the existence of sodium benzoate influenced the formation of biogas. There were significant reductions of biogas formation from 200.6 mL to 66.6 mL, 159.8 mL to 66.0 mL and 130.2 mL to 54.0 mL for the initial SB concentrations of 50, 100, and 200 mg/L. The kinetic parameters of the Modified Gompertz equation exhibited the greatest degree of confidence equal to 95%.