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EN
One of the actors whose role is very firmly rooted in the idea of local self-government is the village leader. It performs a support function for the commune without being provided with formal authority and financial benefits and its work is subjected to very high expectations of the local community. By analyzing the literature, you will notice that there are only few publications on determinants of the village leader efficacy. Thus, the authors of the article have undertaken the task of exploring this topic further. The purpose of this article is to present the outcome of the competency workshop for village leaders and a proposal of the village leader competency model along with behavioral indicators of village leaders’ efficient operations. This article presents the theoretical basis of the competency model, methods of its identification and pointed out the specific aspect of field research in defining the competence model.
PL
Jednym podmiotów w zarządzaniu publicznym jest sołtys, który pełni rolę wspierającą dla władz gminy. Analizując literaturę przedmiotu można zauważyć, że jest niewiele publikacji dotyczących wyróżników skuteczności pełnienia roli sołtysa, w związku z tym autorki artykułu podjęły próbę identyfikacji atrybutów kompetencyjnych współczesnego sołtysa. Celem niniejszego artykułu jest zaprezentowanie wyniku warsztatu kompetencyjnego dla sołtysów i propozycja modelu kompetencji sołtysa wraz ze wskaźnikami behawioralnymi jego efektywnego działania. W artykule przedstawiono podstawę teoretyczną modelu kompetencji, metody jego identyfikacji oraz zwrócono uwagę na aspekt specyfiki badań terenowych w definiowaniu modelu kompetencji.
EN
We propose two thermodynamic relationships which couple analyte retention with selected physicochemical properties - exponential dependence of analyte relative retention times (τ) on boiling points (TB) and molar volume (Vm) or, alternatively, on boiling points and molar refraction (Rm). The statistical performance of these retention models was tested on experimental data obtained for homologous analytes (methyl n-alkyl ketones) by use of isothermal capillary gas chromatography (CGC) on stationary phases of different polarity. Computations were performed by use of Statistica 5.0 PL software. The same models were then used to predict the thermodynamic properties selected (i.e. the molar enthalpies of vaporization of the analytes employed) and their physicochemical performance was evaluated by comparison of the results obtained with those obtained from the literature. The experiments and computations performed led to the conclusion that the models introduced enable prediction of analyte retention and that they can also prove useful for extraction of thermodynamic information from the CGC results.
EN
In this paper we present a new model of describing the temperature-dependence of Kováts retention indices. It is regarded as a "kinetic" model, because it uses certain elements of chemical kinetics (e.g. the enthalpy and entropy of activation, ΔH≠ and ΔS≠) for thermodynamic description of retention processes in gas chromatography. It was founded on the transition-state theory (TST) and involves the Eyring equation. Mathematically it can be considered as an extended Antoine-type equation, although it surpasses that relationship owing to its greater flexibility and hence its better fitting of experimental results. It also anticipates the physical minima which occasionally occur when retention indices are plotted against the measure-ment temperature.
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