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Synthesis of 4-cyanophenyl and 4-nitrophenyl 2,6-anhydro-1,2-dithio-D-manno- and altropyranosides and their derivatives possessing antithrombotic activity

Bozo E., Boros S., Kuszmann J.

Polish Journal of Chemistry

1999

vol. 73 nr 6

989-1001

1,3,4-Tri-O-acetyl-2,6-anhydro-2-thio-D-manno- and -D-altropyranose as well as 1,4-di-O-acetyl-2,6-anhydro-3-azido-3-deoxy-2-thio-D-mannopyranose were synthesized and used as donors in the synthesis of the corresponding 4-cyano- and 4-nitrophenyl-thioglycosides, which showed significant oral antithrombotic activity in rats.