Supramolecular ordering happens as an important parameter for the control of light emission processes. In this review paper, we discuss several examples of application of self-assembly to the realization of nano-structures designed in view of mastering specific photonic processes. This comprises the formation of highly localized plasmon modes in self-organized 2D assemblies of metal nanoparticles, the immobilization of dyes inside highly homogeneous 2D alveolar self-assembled molecular matrices and molecular 3D building blocks designed to combine in-plane periodicity and off-plane π-conjugated protrusions. Finally, we will discuss 3D self-assembly in solution with the example of fluorescent labelling of DNA.
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