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2 Optica Applicata

2 2019

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Spectroscopic properties of Er3+-doped fluorotellurite glasses modified by Nb2O5 and WO3

Burtan-Gwizdała Bożena, Reben Manuela, Cisowski Jan, El Sayed Yousef, Lisiecki Radosław, Grelowska Iwona

Optica Applicata

2019

Vol. 49, nr 3

393--402

We have investigated the spectroscopic properties of Er3+-doped fluorotellurite glasses with the basic molar composition 75%TeO2–10%P2O5–10%ZnO–5%PbF2, modified by replacing 5% TeO2 by a metal oxide, namely WO3 or Nb2O5. The absorption edge of the glasses studied has been described within the Urbach approach, while the absorption and photoluminescence spectra have been analyzed in terms of the standard Judd–Ofelt theory, along with the photoluminescence decay of the 4I13/2 and 4S3/2 levels of the Er3+ ion. The absorption and emission spectra of the 4I15/2↔ 4I13/2infrared transition have been analyzed within the McCumber theory to yield the peak emission cross-section and figure of merit for the amplifier gain. It appears that the fluorotellurite glass containing WO3 as a modifier is characterized by the largest figure of merit, indicating this matrix as a promising new host for doping with Er3+ ions.

Influence of modifiers on thermal and optical properties of TeO2–P2O5–ZnO–PbF2 glasses

Reben Manuela, Burtan-Gwizdała Bożena, Cisowski Jan, Grelowska Iwona, El Sayed Yousef, Bukalska Julita

Optica Applicata

2019

Vol. 49, nr 3

403--413

A series of fluorotellurite glasses based on 70TeO2–5MxOy–10P2O5–10ZnO–5PbF2 in mol%, where MxOy = (WO3, Nb2O5) doped with 2400 ppm of Er2O3 have been prepared by the conventional melt quenching method. The influence of modifiers on thermal and optical properties of glasses has been analyzed. Thermal characteristics of glasses like the glass transition temperature Tg, the temperature for the crystallization onset Tx, the maximum crystallization temperature Tc, and the thermal stability parameter were determined by the DSC method. The ellipsometric data have provided Sellmeier-type dispersion relations of the refractive index of the investigated glasses. The optical parameters are used to calculate the molar refractivity, molar polarizability, oxide ion polarizability, molar cation polarizability, and a number of polarizable atoms per unit volume for every glass composition in order to interpret the refractive index of these glasses.