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Thermodynamics of uni-univalent H+/K+ and uni-bivalent H+/Ca2+ ion exchange reactions using nuclear grade resin Indion-223

Singare P. U., Mohammed A. L. K., Dixit N. N.

International Letters of Chemistry, Physics and Astronomy

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2014

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Vol. 14, iss. 2

190-198

EN

The present paper deals with the thermodynamic of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223. It was observed that with rise in temperature the equilibrium constants K values for H+/K+ uni-univalet ion exchange reaction increases from 0.01710 to 0.02374. Similarly for H+/Ca2+ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in K values with rise in temperature for both the reactions indicates its endothermic nature having the enthalpy change values of 22.72 and 38.92 kJ/ mol respectively. The technique used here can be extended further to standardise the process parameters in order to bring about the efficient separation of the desired ionic species from the solution.

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Thermodynamic study to evaluate the selectivity behaviour of nuclear grade resin Indion-223 towards some univalent ions

Singare P. U., Mohammed A. L. K., Dixit N. N.

International Letters of Chemistry, Physics and Astronomy

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2014

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Vol. 15

22--29

EN

The present paper deals with the application of thermodynamic concept in understanding the preferential selectivity of nuclear grade anion exchange resin Indion-223 in H+ form towards Na+ and K+ ions in the solution. In the study it was observed that the equilibrium constants K values for H+/Na+ and H+/K+ uni-univalet ion exchange reactions increases from 0.01389 to 0.01855 and from 0.01710 to 0.02374 respectively as the temperature increases from 35.0 °C to 45.0 °C. The increase in K values with rise in temperature suggests endothermic ion exchange reactions having the enthalpy change values of 25.55 and 22.72 kJ/ mol respectively. Based on difference in K values and enthalpy values for the two uni-univalent ion exchange reactions, the preferential selectivity of the resin for the univalent ions in the solution was predicted. From the results of present study, it appears that the experimental technique used here can be applied further to understand the ionic selectivity of different industrial grade ion exchange resins. It is expected that such studies will provide valuable information in order to decide about the selection of those resins for efficient separation of various ionic species present in the industrial waste water effluents.

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Study on preferential selectivity of nuclear grade resin Indion-223 towards some bivalent ions

Singare P. U., Mohammed A. L. K., Dixit N. N.

International Letters of Chemistry, Physics and Astronomy

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2014

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Vol. 15

11--21

EN

In the present paper attempts are made to understand the selectivity of nuclear grade cation exchange resin Indion-223 in H+ form towards Ca2+ and Mg2+ bivalent ions in the solution based on thermodynamic concept. It was observed that with rise in temperature the equilibrium constant K values for H+/Ca2+ uni-bivalet ion exchange reactions increases from 0.000397 to 0.000639. Similarly for H+/Mg2+ uni-bivalet ion exchange reactions the equilibrium constant K values increases from 0.000177 to 0.000333. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 38.92 and 51.46 kJ/ mol respectively. The difference in K values and enthalpy values were used to predict the selectivity behaviour of the resin towards the Ca2+ and Mg2+ bivalent ions in the solution. The thermodynamic concept of the present study can be applied to understand the selectivity behaviour of different nuclear as well as non-nuclear grade resins towards wide range of ionic species present in the exchanging liquid medium.

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Ion exchange equilibrium studies of uni-univalent H+/Na+ and uni-bivalent H+/Mg2+ ion exchange reactions using nuclear grade resin Indion-223

Singare P. U., Mohammed A. L. K., Dixit N. N.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 14, iss. 2

199-207

EN

In the present investigation the uni-univalent and uni-bivalent ion exchange reactions were studied using nuclear grade anion exchange resin Indion-223 in H+ form. It was observed that for H+/Na+ uni-univalet ion exchange reaction, with rise in temperature the equilibrium constants K values increases from 0.01389 to 0.01855. Similarly increase in K values was observed from 0.000177 to 0.000333 for H+/Mg2+ uni-bivalet ion exchange reaction. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 25.55 and 51.46 kJ/ mol respectively. It is expected that the present study will provide valuable information in order to decide about the selection of those resins for efficient separation of various ionic species present in the industrial waste water effluents.

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Comparative study of uni-univalent H⁺/Na⁺ and uni-bivalent H⁺/Ca²⁺ ion exchange reactions using nuclear grade resin Indion-223

Singare P. U., Mohammed A. L. K., Dixit N. N.

International Letters of Chemistry, Physics and Astronomy

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2014

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Vol. 14, iss. 2

127-135

EN

The present paper deals with the ion exchange equilibrium studies of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223 in H⁺ form towards Na⁺ and Ca²⁺ ions in the solution. It was observed that with rise in temperature the equilibrium constants K values for H⁺/Na⁺ uni-univalet ion exchange reaction increases from 0.01389 to 0.01855. Similarly for H⁺/Ca²⁺ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 25.55 and 38.92 kJ/ mol respectively.