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2 Physicochemical Problems of Mineral Processing

2 2022

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Research of nanobubbles enhanced reverse anionic flotation of a midlow grade phosphate ore

Zhang Tiebin, Zhang Qin

Physicochemical Problems of Mineral Processing

2022

Vol. 58, iss. 1

113--125

The reverse anionic flotation is commonly used to upgrade the mid-low grade phosphate ore in China. The mineral characterization of raw ore shows that carbonate and phosphate minerals combined with fine intergrowth, difficulty in upgrading. Flotation using nanobubbles (NBs) can significantly enhance the flotation efficiency of fine particles of minerals. To research the effect of NBs on the flotation process of this phosphate ore, two flotation tests with and without NBs were compared. The results show that the MgO removal had an increment of 10% in the case of NBs flotation versus conventional flotation in the approximate grade and recovery of P2O5. The foam product of NBs flotation had smaller dimensions than the conventional flotation. NBs enhanced the contact angle on dolomite surface from 45.8° to 64.5°, and increases the d50 of dolomite from 20.49 µm to 30.43 µm.

Effect of surface relaxation of rhodochrosite (104) and substitution of Mn by Ca on the electronic structure of rhodochrosite

Zhang Jingqi, Zhang Qin, Zhang Tiebin

Physicochemical Problems of Mineral Processing

2022

Vol. 58, iss. 3

art. no. 145991

To explore the difference between the surface and crystal structure of rhodochrosite, relaxation and reconstruction of the rhodochrosite (104) surface are studied by using Density Functional Theory. The calculation results indicated that the C and O atoms with lower reactivity tend to be enriched on the surface, while the Mn atoms with the highest reactivity moved away from the surface. The band gap width decreased from 1.814 eV to 1.614 eV after the formation of the rhodochrosite (104) surface. The electrons on the rhodochrosite (104) surface are more active than crystal. Ca substitution makes the atomic activity on the (104) surface of rhodochrosite more stable. Ca substitution reduces the ability of the surface of rhodochrosite to absorb external electrons, and the surface electrical properties decrease.