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New Bis-Linked Tetrathiafulvalenes (TTFs) to [60] Fullerene : Spectral Investigations

Olejniczak I., Graja A., Bogucki A., Gorgues A., Kreher D., Cariou M.

Polish Journal of Chemistry

2002

Vol. 76 / nr 1

95-102

Extended spectral investigations of several new bis-linked tetrathiafulvalenes (TTFs) to [60]fullerene were performed. From VIS-NIR-IR spectra it was stated, that charge redistribution on C60 and TTFs moieties in the adducts occurs after their formation. This redistribution depends not only on the nature of a substituent but also on the number of bounded donors. Vibrational features of the polyadducts were also analyzed.