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Hydrogen ordering effects in Laves - phase YFe2

Ostrasz A.

Nukleonika

2013

Vol. 58, No. 1

77-81

Mössbauer spectroscopy and X-ray diffraction measurements were performed before and after hydrogenation of YFe2 Laves phase in order to investigate the effect of hydrogen on their structural and magnetic properties. The experimental results show an instant change of both the lattice parameters and the hyperfine field. The results are interpreted due to the phase decomposition of the parent intermetallic in the aftermath of creation of stoichiometric hydrides YHc (c = 0.9; 2.5).

Hydrogen effect on the electronic and structural properties of Nb-Fe alloys

Brzeska-Michalak B., Ostrasz A.

Nukleonika

2003

Vol. 48,suppl.1

53-57

The influence of hydrogen on the electronic and structural properties of Nb1-yFey alloys has been studied with 57Fe Mössbauer spectroscopy and X-ray diffraction. No ability of hydrogen to creation of the ferromagnetic properties has been observed in this system. The results clearly indicate the ß-NbH0.85÷0.77 hydride formation in place of ?-Nb phase. The quadrupole splitting and the isomer shift of the ß-NbHx subspectrum have been considered in terms of interaction between the interstitials and the Mössbauer atoms within the hydride phase.