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EN
The formulas of spherical triangle, which are widely used to solve various navigation problems, are the important basic knowledge of nautical mathematics. Because the sine rules and the cosine rules for the sides are the fundamental formulas to derive the other spherical triangle formulas, they are also called the genetic codes of the spherical triangle formulas. In the teaching process, teachers usually use the geometric method to derive and prove these fundamental formulas. However, the derivation of geometric methods is complicated and difficult to understand. To improve the teaching process, this paper proposes the three-dimensional rotation method, which is based on conversion of two cartesian coordinate frames using the rotation matrices. This method can easily and simultaneously derive the sine rules, the cosine rules for the sides, and the five-part formulas (I), and is also helpful to solve different kinds of spherical navigation problems.
EN
A novel testing setup is developed for structural tests on segmental joints of shield tunnels. It lies on the ground and is a self-balanced system. The applied axial force and bending moment are coupled, and the combination of target axial force and bending moment at the joint can be achieved by adjusting the horizontally-applied forces. It is more economic and flexible than the traditional two-point bending testing setups. The effectiveness of internal force/moment transmission of the testing setup was verified by comparing the experimental data with theoretically-determined values and numerical simulation results. It was then applied to investigate the flexural behaviour of longitudinal joint of a deeply-buried tunnel subjected to both sagging and hogging moments. The rotational stiffnesses of the testing joint were determined. The influences of bending moment and axial force on joint defor-mation were unified through eccentricity. In both the sagging moment and hogging moment cases, the joint deformation varied with eccentricity following a bilinear trend composed of an axial-force-dominant stage and a bending-moment-dominant stage. The slopes of the relationships between eccentricity and joint rotation angle are steeper in the hogging moment case than in the sagging moment case due to the absence of bolts at the extrados.
EN
The dredger fill of Shanghai Hengsha Island Dongtan is solidified by curing agents with different fly ash content, and the shear strength index of solidified dredger fill is measured by the direct shear test. The microscopic images of solidified dredger fill are obtained by using SEM. The microscopic images are processed and analyzed by using IPP, and the fractal dimension including particle size fractal dimension Dps, aperture fractal dimension Dbs and particle surface fractal dimension Dpr is calculated by fractal theory. The quantitative analysis of the relationship between shear strength index and fractal dimension of solidified dredger fill is done. The research results show that the internal friction angle and the cohesion are closely related to the fly ash content λ and the curing period T, and the addition of fly ash can improve the effect of curing agent; There is no obvious linear relationship between the internal friction angle and the three fractal dimensions; The smaller particle surface fractal dimension Dpr and particle size fractal dimension Dps, the larger aperture fractal dimension Dbs, the greater the cohesion, and the cohesion has a good linear relationship with three fractal dimensions, and the correlation coefficient R2 is above 0.91.
EN
In this study, advanced oxidation processes (AOPs), Fenton process, was applied to degrade ten amine collectors. The experimental results indicated that most of the tested amines could be removed rapidly and effectively at pH=4, while the degradation of quaternary ammonium compounds was less than others. To research the Fenton oxidation process, the degradation-rate constants of amine collectors were calculated by the pseudo-second order kinetic model, then which was used as the dependent variable to establish a quantitative structure activity relationship (QSAR) model. Meanwhile, 16 molecular structure descriptors and quantum mechanical parameters for amine collectors were simulated and analyzed by using Materials Studio software. The optimum QSAR model was established based on the partial least squares regression (PLS) method and confirmed by the statistics analysis. The model revealed that hydrogen bond acceptor (HBA) and the maximum values of electrophilic attack in C atom sites (f(-)c) were the major effect factors for the degradation-rate constants of amine collector.
EN
The introduction of anions and cations into energetic materials can significantly improve their physicochemical and energetic properties. The K, Zn, Ba, Cu and Pb salts of 1,1,2,2-tetranitraminoethane (TNAE) were synthesized using TNAE as the starting material, and were characterized by IR spectroscopy, NMR spectroscopy and elemental analysis. All of the energetic salts exhibited relatively high thermal stabilities (decomposition temperatures ranging from 195.1 °C to 279.3 °C) and high densities (ranging from 2.1 g·cm–3 to 3.7 g·cm–3). It was demonstrated that the introduction of metal ions conveys better thermal stability than covalent TNAE itself. More importantly, the Zn, Ba and Cu salts exhibited good thermal stability, high density, low sensitivity, and therefore have the potential to be a new class of insensitive, highly energetic explosives for practical applications.
EN
Environmental changes have led to a growing conflict between water supply and demand in Qinjiang River. This paper used the data of monthly rainfall, runoff, evaporation and air temperature during the period from 1956 to 2016 and combined 3-year running mean, linear regression method, Mann–Kendall test and R/S analysis method to analyze the change trend of each factor, combined Mann–Kendall test, cumulative anomaly method and slide t test to analyze the variation of each factor and combined Morlet continuous wavelet analysis to identify periodic oscillations. In this paper, the influences of climate change and human activities on the runoff of the Qinjiang River were qualitatively assessed from the aspects of trend, variation and periodicity and the contributions of climate change and human activities to runoff reduction were quantitatively assessed using evaporation difference method and an improved comparative method of the slope changing ratio of cumulative quantity (SCRCQ).The following results were obtained: (1) From 1956 to 2016, the rainfall showed a weak increasing trend, whereas the runoff depth and the evaporation exhibited significant decreasing trend and the air temperature exhibited a significant increasing trend. The rainfall and air temperature will continuously increase, whereas runoff and evaporation will continuously decrease in the future. (2) Rainfall exhibited no significant variation, whereas there were two variation points (1986 and 2003) in the runoff, three variation points (1974, 1986 and 2011) in evaporation and one variation point (1996) in air temperature. (3) Features of rainfall exhibited similarities to periodic changes in runoff, whereas rainfall exhibited significant difference with evaporation and air temperature. (4) Human activities contributed mainly to the runoff reduction. The contribution of human activities to runoff reduction increased from 43.78 to 61.17% in BR period (1983–2003) and increased from 61.17 to 72.66% in CR period (2004–2016). This indicated that the contribution of human activities to runoff reduction increased continuously. The impact of human activities on the reduction in runoff in the Qinjiang River Basin is mainly due to the irrigation, industrial and urban residents’ water use, which is caused by the growth of population and the growth of economic index.
EN
Seismic impedance inversion is a well-known method used to obtain the image of subsurface geological structures. Utilizing the spatial coherence among seismic traces, the laterally constrained multitrace impedance inversion (LCI) is superior to trace-by-trace inversion and can produce a more realistic image of the subsurface structures. However, when the traces are numerous, it will take great computational cost and a lot of memory to solve the large-scale matrix in the multitrace inversion, which restricts the efficiency and applicability of the existing multitrace inversion algorithm. In addition, the multitrace inversion methods are not only needed to consider the lateral correlation but also should take the constraints in temporal dimension into account. As usual, these vertical constraints represent the stratigraphic characteristics of the reservoir. For instance, total-variation regularization is adopted to obtain the blocky structure. However, it still limits the magnitude of model parameter variation and therefore somewhat distorts the real image. In this paper, we propose two schemes to solve these issues. Firstly, we introduce a fast algorithm called blocky coordinate descent (BCD) to derive a new framework of laterally constrained multitrace impedance inversion. This new BCD-based inversion approach is fast and spends fewer memories. Next, we introduce a minimum gradient support regularization into the BCD-based laterally constrained inversion. This new approach can adapt to sharp layer boundaries and keep the spatial coherence. The feasibility of the proposed method is illustrated by numerical tests for both synthetic data and field seismic data.
EN
Gega lake, in southeastern Tibet, was formed by the blocking of Yarlung Tsangpo gorge by a glacier and is a well-known example of geomorphological damming. However, the evolution of the damming process at the site is still not understood in detail. Here, we use measurements of multiple magnetic parameters of the sediments from the Yusong (YS) 3 section, which is well-dated by optically stimulated luminescence, to provide a detailed history of the late stage of Gega dammed lake since 17.0 ka. Low-frequency field magnetic susceptibility (χlf) increases upwards gradually from 25 to 79 × 10−8 m3/kg above 5.5 m, but other magnetic properties, such as frequency-dependent magnetic susceptibility (χfd % and χfd), susceptibility of anhysteretic remanent magnetization (χARM), and saturation isothermal remanent magnetization (SIRM) did not show a similar degree of enhancement. The magnetic grain size indicators of χARM/χlf, χARM/SIRM, and χlf/SIRM all indicate a trend of increasing magnetic grain size from the 5.5 m to the top of section; however, the bulk sediment grain size decreases gradually within the same interval. The total organic carbon is very low (0.2–0.7%), and thus, it is unlikely that the sedimentary environment is sufficiently strongly reducing to lead to the dissolution of magnetic minerals. Therefore, we infer that the coarsening-upwards of the magnetic grain size, and the increasing magnetic susceptibility from 5.5 m, reflect the gradual preferential preservation of magnetic minerals, caused by the deepening of the lake. Thus, we interpret the magnetic record of the section as reflecting the gradual deepening of the late stage of Gega ice-dammed lake. Last, the abrupt disappearance of the lake may have resulted in an outburst flood.
EN
Under the new normal of China’s economy, the competition among the port enterprises is not only the competition of the core competence of the port, the port industry chain or the port supply chain, but also the competition of the port service ecosystem. In this paper, the concept and characteristics of the port service ecosystem is discussed, a hierarchical model of the port service ecosystem is constructed. As an extended logistic model, Lotka-Volterra model is applied to study the competitive co-evolution and mutually beneficial co-evolution of enterprises in the port service ecosystem. This paper simulates the co-evolution of enterprises in the port service ecosystem by using MATLAB programming. The simulation results show that the breadth of the niche of the enterprises is changing with the change of the competition coefficient and the coefficient of mutual benefit in the port service ecosystem. Based on that, some proposals are put forward to ensure the healthy and orderly development of the port service ecosystem.
EN
Predicting the stability of open stopes can be a challenging task for underground mine engineers. For decades, the stability graph method has been used as the first step of open stope design around the world. However, there are some shortcomings with this method. For instance, the stability graph method does not account for the relaxation zones around the stopes. Another limitation of the stability graph is that this method cannot to be used to evaluate the stability of the stopes with high walls made of backfill materials. However, there are several analytical and numerical methods that can be used to overcome these limitations. In this study, both empirical and numerical methods have been used to assess the stability of an open stope located between mine levels N9225 and N9250 at Diavik diamond underground mine. It was shown that the numerical methods can be used as complementary methods along with other analytical and empirical methods to assess the stability of open stopes. A three dimensional elastoplastic finite element model was constructed using Abaqus software. In this paper a sensitivity analysis was performed to investigate the impact of the stress ratio “k” on the extent of the yielding and relaxation zones around the hangingwall and footwall of the understudy stope.
PL
Prognozowanie stabilności przodka wybierkowego stanowi poważne wyzwanie dla inżynierów górnictwa. Przez dziesięciolecia na całym świecie do projektowania przodka wybierkowego prowadzonego bez obudowy wykorzystywano metodę graficzną jako pierwszy etap prac. Jednakże metoda ta ma pewne niedogodności. Przykładowo, nie uwzględnia występowania stref odprężania wokół przodka. Innym ograniczeniem metody graficznej jest to, iż nie może być ona wykorzystana do oceny stabilności przodków w których ściany zawierają materiał podsadzany. Istnieją jednak metody analityczne i numeryczne, które pozwalają na przezwyciężenie tych ograniczeń. W pracy tej wykorzystano zarówno metody empiryczne jak i numeryczne do oceny stabilności przodka wybierkowego zlokalizowanego pomiędzy poziomami N9225 i N9250 w podziemnej kopalni diamentów w Diavik. Wykazano, że metody numeryczne stanowią znakomite uzupełnienie metod analitycznych i empirycznych wykorzystywanych do oceny stabilności przodków wybierkowych. Opracowano trójwymiarowy model elastyczno-plastycznych elementów skończonych z wykorzystaniem oprogramowania Abaqus. W pracy tej przeprowadzono analizę wrażliwości i zbadano wpływ wskaźnika stosunku naprężeń "k" na zasięg osiadania i powstanie stref odprężenia wokół warstw stropu i spągu w badanym przodku wybierkowym.
EN
High carbon ferromanganese is used as a starting material to prepare pure ferromanganese by electrorefining in molten salts. High carbon ferromanganese was applied as the anode, molybdenum was the cathode and Ag/AgCl was the reference electrode. The anodic dissolution was investigated by linear polarization in molten NaCl-KCl system. Then potentiostatic electrolysis was carried out to produce pure ferromanganese from high carbon ferromanganese. The cathodic product was determined to be a mixture of manganese and iron by x-ray diffraction (XRD). The content of carbon in the product was analyzed by carbon and sulfur analyzer. The post-electrolysis anode was characterized by scanning electron microscope (SEM). The mechanism of the anode dissolution and the distribution of the main impurity of carbon and silicon after electrolysis were discussed.
12
EN
Vertical-axial tidal current turbine is the key for the energy converter, which has the advantages of simple structure, adaptability to flow and uncomplex convection device. It has become the hot point for research and application recently. At present, the study on the hydrodynamic performance of vertical-axial tidal current turbine is almost on 2-D numerical simulation, without the consideration of 3-D effect. CFD (Computational Fluid Dynamics) method and blade optimal control technique are used to improve accuracy in the prediction of tidal current turbine hydrodynamic performance. Numerical simulation of vertical-axial tidal current turbine is validated. Fixed and variable deflection angle turbine are comparatively studied to analysis the influence of 3-D effect and the character of fluid field and pressure field. The method, put the plate on the end of blade, of reduce the energy loss caused by 3-D effect is proposed. The 3-D CFD numerical model of vertical-axial tidal current turbine hydrodynamic performance in this study may provide theoretical, methodical and technical reference for the optimal design of turbine.
EN
Light environments can have a considerable influence on how plants respond to defoliation through influencing the biomass allocation patterns and internal C/N ratio. Seedlings of Lolium perenne, a common perennial grass species, were grown for eight weeks under three different light environments (natural light, red light and shading) and two different defoliation treatments (no defoliation versus 50% aboveground biomass removal). This study was conducted to examine (1) the effects of light regimes and defoliation on biomass accumulation, biomass allocation and internal C/N ratio status in plants; (2) how the light regimes influence the pattern of compensatory growth after defoliation; and (3) the relationship between compensatory growth and the internal C/N ratio status. We found that red light altered the shoot-to-root allometry, enhanced the leaf C concentrations and induced N deficiency. By contrast, the leaf N concentrations of L. perenne were greater during shading treatment, which simultaneously enhanced shoot growth and stopped root growth. Under defoliation, red light increased shoot growth, not at the expense of root growth, which was not the same as in natural light and shading treatment. Moreover, regardless of the unclipped (no defoliation) and defoliation conditions, the L. perenne biomass partitioning between roots and shoots was significantly correlated with the leaf N concentrations and C/N ratio, indicating that allometric biomass allocation can be largely modulated by signals related to the C and N status of the plants. These results demonstrated that the leaf C and N status would be an appropriate indicator of compensatory growth after defoliation.
EN
Zinc leaching residue is a good source of zinc and has a great potential to be utilized. However, it is very difficult to recover lead, zinc and silver from the residue by traditional technologies. In this study, a new technology based on conversions of PbSO4 and ZnSO4 in the residue to their respective sulfides by reduction roasting with coal powder followed by a flotation treatment was developed. The effects of roasting temperature, coal dosage, reaction time and pyrite dosage were investigated at a laboratory scale. The results showed that the conversion extent of PbSO4 and ZnSO4 under the optimal experimental conditions was 71.89 and 69.76%, respectively. A flotation concentrate containing 39.13% Zn, 6.93% Pb and 973.54 g/Mg Ag was obtained from the treated material, and the recovery of Zn, Pb and Ag was 48.38, 68.23 and 77.41%, respectively. The tailing containing ZnFe2O4 or Fe3O4 could be either stockpiled or further disposed.
EN
In this article, an inverted pendulum system is set up to explore the dynamics of a horizontally driven pendulum which exhibits a great variety of dynamical behavior and appears in a wide range of applications in the field of engineering. The facility is efficient to experimentally explore two kinds of coexisting movement patterns in the horizontally driven pendulum, i.e. in-phase and anti-phase patterns between the angular velocity of the pendulum rod and the direction of the driving forces. Theoretical analysis is applied to reveal the regimes of the coexistence of the two movement patterns, which is promising to control the system to a desired pattern.
EN
The low-frequency mechanical spectra of lanthanum cobaltite based mixed conducting oxides have been measured using a computer-controlled inverted torsion pendulum. The results indicate that the internal friction spectra and shear modulus depend on the Sr doping contents (x). For undoped samples, no internal friction peak is observed. However, for La0.8Sr0.2CoO3-δ, three internal friction peaks (P2, P3 and P4) are observed. In addition to these peaks, two more peaks (P0 and P1) are observed in La0.6Sr0.4CoO3‒δ. The P0 and P1 peaks show characteristics of a phase transition, while the P2, P3 and P4 peaks are of relaxation-type. Our analysis suggests that the P0 peak is due to a phase separation and the P1 peak is related to the ferromagnetic–paramagnetic phase transition. The P2, P3 and P4 peaks are associated with the motion of domain walls. The formation of this kind of domain structure is a consequence of a transformation from the paraelastic cubic phase to the ferroelastic rhombohedral phase. With partial substitution of Fe for Co, only one peak is observed, which is discussed as a result of different microstructure.
EN
Pore structure and mineral matrix elastic moduli are indispensable in rock physics models. We propose an estimation method of pore structure and mineral moduli based on Kuster-Toksöz model and Biot’s coefficient. In this technique, pore aspect ratios of five different scales from 100 to 10-4 are considered, Biot’s coefficient is used to determine bounds of mineral moduli, and an estimation procedure combined with simulated annealing (SA) algorithm to handle real logs or laboratory measurements is developed. The proposed method is applied to parameter estimations on 28 sandstone samples, the properties of which have been measured in lab. The water saturated data are used for estimating pore structure and mineral moduli, and the oil saturated data are used for testing these estimated parameters through fluid substitution in Kuster–Toksöz model. We then compare fluid substitution results with lab measurements and find that relative errors of P-wave and S-wave velocities are all less than 5%, which indicates that the estimation results are accurate.
EN
In order to recover lead from the zinc leaching residues, a new technology involving selective reduction of lead sulfate to lead sulfide with carbon followed by flotation was investigated. The reduction thermodynamics of PbSO4 was discussed and the effects of molar ratio of C to PbSO4, reaction temperature and time were examined by thermogravimetry (TG) and XRD. Verification tests were further carried out to prove the conclusions of thermodynamic and TG analyses, and the transformation extent could reach 86.45% under the optimal roasting conditions. The prepared galena was then subjected to micro-flotation tests, and the highest lead recovery could reach up to 75.32%.
EN
Fast and effective extraction of equivalent shunt resistance for each subcell of GaInP/GaInAs/Ge triple-junction concentrator solar cells is presented. The two-diode model of single junction was introduced to establish the equivalent circuit of triple-junction solar cells. The current-voltage characteristic of the triple-junction solar cells was measured under AM1.5D spectrum, C = 576 and T = 303 K. Equivalent shunt resistance of each subcell was extracted from its estimated current-voltage curve. The estimated current-voltage curve of the triple-junction solar cells shows a good agreement with the experimental data in 0.31% deviation. The degradation in the equivalent shunt resistance for Ge subcell was intentionally introduced to indicate the mechanism of current-matching operation for different subcells, with the maximum output power of the triple-junction solar cells deteriorating from 3.5 to 3.17 W. The results can offer performance analysis and optimum design of photovoltaic applications.
EN
Patrinia scabra Bunge has long been used in clinic as a traditional Chinese medicine for treating leukemia and cancer and regulating host immune response. Despite their wide use in China, no report on system analysis on their chemical constituents is available so far. The current study was designed to profile the fingerprint of ethyl acetate extract of it, and in addition, to characterize the major fingerprint peaks and determine their quantity. Therefore, a detailed gradient high-performance liquid chromatography was described to separate more than 30 compounds with satisfactory resolution in P. scabra Bunge. Based on the chromatograms of 10 batches samples, a typical high-performance liquid chromatographic (HPLC) fingerprint was established with 23 chromatographic peaks being assigned as common fingerprint peaks. Furthermore, a quadrupole time of flight mass spectrometry (Q-TOF/MS) was coupled for the characterization of major compound. As (+)-nortrachelogenin was the most predominant compound in P. scabra Bunge, the quantification on it was also carried out with the method being validated. As a result, (+)-nortrachelogenin was found to be from 1.33 to 2.21 mg g−1 in this plant material. This rapid and effective analytical method could be employed for quality assessment of P. scabra Bunge, as well as pharmaceutical products containing this herbal material.
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