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The chemical properties of Zn and Ag composite electrodes for power sources

Koval'chuk E.P., Artymyshyn O.R., Reshetnyak O.V., Pankevych R.V.

Polish Journal of Chemistry

1998

Vol. 72, nr 6

1089-1095

Chemical properties of composite electrodes for the silver-zinc (Ag-Zn) battery have been studied. The instability of the supersaturated zincate electrolyte solutions is related to the formation of polynuclear zincate complex. In accordance with quantum-mechanical calculation it was shown that most stable is the complex with the linear structure. The influence of polycrylamide, both on the stability of the electrolyte solutions and in the inhibition of dendrite formation, has been studied.