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Low waste technology for the removal of nitrates from water

Trus Inna, Gomelya Mukola, Halysh Vita, Tverdokhlib Mariia, Makarenko Iryna, Pylypenko Tetiana, Chuprinov Yevhen, Benatov Daniel, Zaitsev Hennadii

Archives of Environmental Protection

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2023

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Vol. 49, no 1

74--78

EN

As a rule, nitrates are present in all natural water bodies. Their increased concentrations are connected with the discharge of insufficiently treated wastewater from industrial and communal enterprises, agricultural and livestock complexes. Recent scientific publications concerning treatment methods for nitrates removal from natural water and wastewater were analyzed in order to create effective and low-waste technology for obtaining high quality water. It has been established that the ion exchange method is quite effective for removing nitrates from water. In the paper, the processes of ion exchange removal of nitrates from water on low-axis anionite in DOWEX Marathon WBA in Сl- form were investigated. During the sorption of nitrates with a concentration of 186, 205, 223 and 2200 mg/dm3, it was established that the full exchangeable dynamic capacity was 1.075, 1.103, and 1.195, 1.698 g-eq/dm3, respectively. To regenerate anionite, solutions of ammonia as well as potassium chloride, ammonium chloride and potassium carbonate were used in this work. The choice of potassium and ammonium compounds is due to the prospect of further use of regeneration solutions for the production of liquid fertilizers.

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Development of Resource-Saving Technologies in the Use of Sedimentation Inhibitors for Reverse Osmosis Installations

Trus Inna, Gomelya Mukola, Skiba Margarita, Pylypenko Tetiana, Krysenko Tamara

Journal of Ecological Engineering

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2022

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Vol. 23, nr 1

206--215

EN

The processes of desalination of weakly mineralized waters using a reverse osmosis membrane were studied. The operational efficiency of membranes is limited mainly by membrane contamination. It was shown that the preliminary mechanical water purification helps to increase the productivity and selectivity of the membrane. One of the main causes of membrane contamination is the formation of carbonate deposits on their surface. One way to prevent membrane contamination is to dose antiscalants. It was established that the use of hydrolyzed polyacrylonitrile (HPAN) and hydrolyzed polyacrylamide (HPAA) as a stabilizer of scale formation is effective for concentrates of reverse osmosis desalination of water.

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Development of Scaling Reagent for Waters of Different Mineralization

Trus Inna, Gomelya Mukola, Levytska Olena, Pylypenko Tetiana

Ecological Engineering & Environmental Technology

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2022

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Vol. 23, iss. 4

81--87

EN

Membrane technologies are widely used for desalination of water. These technologies are environmentally friendly, economical, energy efficient and material efficient. In the absence of pre-treatment of water, the membrane is contaminated, which leads to an increase in the amount of concentrate formation. Discharge of mineralized water leads to physical and chemical pollution of water bodies. Dissolution and removal of these sediments is a complex issue, so the use of sediment inhibitors is important. The use of antiscalants allows to prolong the service life of membrane elements, which, in turn, will reduce the intake of fresh water and reduce the volume of wastewater. The efficiency of gipan as a reagent in the stabilization treatment of low-mineralized, highly mineralized waters at a temperature of 60°C was determined. The dependences of water stability on sediments on the chemical composition of water, inhibitor concentration and time of ultrasonic treatment of gipan were established.