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1

The High Temperature Oxidation Stability of STS434L/Silicon Oxide Compacts

Park J. W., Ko B. H., Jung W. Y., Park D. K., Ahn I. S.

Archives of Metallurgy and Materials

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2018

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Vol. 63, iss. 1

307--313

EN

In order to improve the high-temperature oxidation stability, a study of 434L sintered stainless steel was focused on the effect of addition of metallic oxides to form stable oxide film on the inner particle surface. In this paper, oxidation behavior of 434L compacted parts in accordance with the addition of metallic oxides were discussed with high temperature oxidative reaction, and sintering behavior analysis under 950°C. Oxidation weight gains of 434 L have increased as a form of parabolic laws. The hightemperature oxidation resistance was improved by the mixed addition of amorphous SiO2 and silica up to 2wt.%. The oxidation rate was decreased and kept constant after 60 hours. It was caused by the restraint succeeding oxidation due to the stable oxide formation of Cr2SiO4 phases on the particle surface to prevent densification and inhibition the external diffusion of Cr. High-temperature stability was confirmed by the electrical resistivity maintains the constant value of 1.3×10-2 Ω ·cm when the silica added less than 2w/o to 1w/o A-SiO2 added 434L.

2

A Study on the Electrical Characteristics and Oxidation Resistance of the STS434L-High Chrome Powder Green Compact at the High-Temperature

Park J. W., Jung W. Y., Park D. K., Ahn I. S.

Archives of Metallurgy and Materials

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2018

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Vol. 63, iss. 1

431--435

EN

Metallic oxide layer of heat resistant element contributes to the high-temperature oxidation resistance by delaying the oxidation, and also has positive effect on the electrical resistivity increase. In this study, the green compacts of Fe-Cr-Al powder mixed with STS434L were oxidized at 950°C up to 210 hrs in order to consider the effect of metal oxide on the oxidation and electrical resistance. It exhibited the low oxidation resistance in case of 434L only, however it increased as the amount of Fe-Cr-Al powder in the 434L compact. The higher electrical resistivity was observed at the Fe-Cr-Al compact with and 434L powder. The metal oxides of (Fe0.6C0.4)2O3, Cr2O3, and Fe2O3 contributed to the electrical resistivity, whereas Al2O2 took a role of oxidation resistance.

3

Synthesis And Electrochemical Characteristics Of Mechanically Alloyed Anode Materials SnS2 For Li/SnS2 Cells

Hong J. H., Liu X. J., Park D. K., Kim K. W., Ahn H. J., Ahn I. S.

Archives of Metallurgy and Materials

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2015

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Vol. 60, iss. 2B

1191--1194

EN

With the increasing demand for efficient and economic energy storage, tin disulfide (SnS2), as one of the most attractive anode candidates for the next generation high-energy rechargeable Li-ion battery, have been paid more and more attention because of its high theoretical energy density and cost effectiveness. In this study, a new, simple and effective process, mechanical alloying (MA), has been developed for preparing fine anode material tin disulfides, in which ammonium chloride (AC), referred to as process control agents (PCAs), were used to prevent excessive cold-welding and accelerate the synthesis rates to some extent. Meanwhile, in order to decrease the mean size of SnS2 powder particles and improve the contact areas between the active materials, wet milling process was also conducted with normal hexane (NH) as a solvent PCA. The prepared powders were both characterized by X-ray diffraction, Field emission-scanning electron microscopeand particle size analyzer. Finally, electrochemical measurements for Li/SnS2 cells were takenat room temperature, using a two-electrode cell assembled in an argon-filled glove box and the electrolyte of 1M LiPF6 in a mixture of ethylene carbonate(EC)/dimethylcarbonate (DMC)/ethylene methyl carbonate (EMC) (volume ratio of 1:1:1).