Wyniki wyszukiwania - BazTech

Ograniczanie wyników

2 Materials Science Poland

Znaleziono wyników: 2

Liczba wyników na stronie

Wyniki wyszukiwania

Sortuj według:

Ogranicz wyniki do:

Dielectric and Raman studies of Ba0.06(Na1/2Bi1/2)0.94TiO3–NaNbO3 ceramics

Roy S. K., Chaudhuri S., Kotnala R. K., Singh D. K., Singh B. P., Singh S. N., Chandra K. P., Prasad K.

Materials Science Poland

2016

Vol. 34, No. 2

437--445

In this work the X-ray diffraction, scanning electron microscopy, Raman and dielectric studies of lead free perovskite (1 – x)Ba0.06(Na1/2Bi1/2)0.94TiO3–xNaNbO3 (0 ≤x ≤ 1.0) ceramics, prepared using a standard solid state reaction method, were investigated. X-ray diffraction studies of all the ceramics suggested the formation of single phase with crystal structure transforming from rhombohedral-tetragonal to orthorhombic symmetry with the increase in NaNbO3 content. Raman spectra also confirmed the formation of solid solution without any new phase. Dielectric studies showed that the phase transition is of diffusive character and diffusivity parameter decreases with increasing NaNbO3 content. The compositional fluctuation was considered to be the main cause of diffusivity.

Dielectric relaxation and ac conductivity of WO3 added (Na1/2Bi1/2)TiO3 ceramic

Prasad K., Kumari K., Chandra K. P., Yadav K. L., Sen S.

Materials Science Poland

2009

Vol. 27, No. 2

373--384

Ceramic samples of WO3 added (Na1/2Bi1/2)TiO3 were prepared using a high-temperature solid-state reaction method. X-ray diffraction analyses indicate the formation of a single-phase orthorhombic structure. The apparent particle size and lattice strain are estimated using the Williamson-Hall plot. Dielectric studies revealed the relaxor behaviour and addition of WO3 shifted phase transition temperature as well as depolarization temperature of (Na1/2Bi1/2)TiO3 to higher side. ac impedance plots were used to analyse the electrical behaviour of samples in function of frequency at various temperatures. The ac impedance studies revealed the presence of the grain boundary effect and evidence of a negative temperature coefficient of resistance. Cole-Cole analysis indicated a non-Debye type dielectric relaxation. The ac conductivity obeys the universal power law. The pair approximation type correlated barrier hopping model explains the universal behaviour of the s exponent. The apparent activation energy of the conduction process and density of states at the Fermi level have been discussed.