Wyniki wyszukiwania - BazTech

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Badania izotopów siarki w minerałach siarczkowych ze złóż rud polimetalicznych w Sudetach za pomocą mikrosondy jonowej SHRIMP IIe/MC

Mikulski S. Z., Krzemińska E., Czupyt Z., Williams I. S.

Biuletyn Państwowego Instytutu Geologicznego

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2015

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nr 464

61--77

PL

W artykule opisano wyniki analiz izotopowych siarki siarczkowej przeprowadzonych po raz pierwszy w PIG-PIB za pomocą nowoczesnej mikrosondy jonowej SHRIMP IIe/MC. Rezultaty wskazują na dużą precyzję i szybkość analiz metodą SIMS oraz na wysoką powtarzalność wyników. W porównaniu z analizą stosunków izotopowych siarki konwencjonalną metodą spektrometrii gazowej IRMS stwierdzono zdecydowaną przewagę na korzyść techniki SIMS. W metodzie tej możliwa jest obserwacja analizowanej powierzchni w skali mikronów i precyzyjne wybranie miejsca analizy (ok. 20 μm), w tym uniknięcie inkluzji lub stref spękań w badanych kryształach siarczków. W przypadku analiz izotopowych siarki metodą konwencjonalną IRMS efekt homogenizacji próbek znacznie wpływa na końcowy wynik. Technika mikrosondy jonowej SIMS, dzięki wysokiej rozdzielczości przestrzennej, dostarcza bardziej szczegółowych wyników. Skład izotopowy siarki wyznaczony w wyniku badań próbek pirytów z rejonu zarzuconego złoża Au–Cu–As w Radzimowicach w nieznacznym stopniu odbiega od δ[sup]34[/sup]S = 0‰ (średnia ważona δ34S dla próbki 10B = +0,84 ±0,24‰ , n = 60, dla próbki M20 = +0,37 ±0,13‰, n = 35, a dla próbki M21 = –0,03 ±0,32‰, n = 26), co wskazuje na źródło siarki związane z magmą odpowiadającą stopom płaszczowym lub dolnoskorupowym. Z kolei w przypadku pirytu z wyrobiska w rejonie Leszczyńca uzyskano ujemne wartości δ34S poniżej –1‰ (zakres od –3,24 ±0,08‰ do –1,19 ±0,09‰), co świadczy o udziale procesu kontaminacji i o niewielkim wpływie osadowego protolitu podczas generacji stopu.

EN

Results of sulphur isotope analyses in sulphides by use of modern ion microprobe equipment – SHRIMP IIe/MC – are described in the paper. Measurements with an application of the SIMS method indicate high precision, fast procedure as well as high repeatability of results. Considering the sulphur isotopic ratio measured by the IRMS (the conventional method of gas spectrometry), advantage of the SIMS method is clearly visible. It allows for observation of the analysed surface at the micron-scale and for very precise selection of the area of analysis (about 20 μm in diameter), including the avoiding of other mineral microinclusions or microfractures in sulphide crystals, which are common features. In the case of the IRMS sulphur isotope analyses sample homogenization strongly influenced obtained results. The SIMS ion microprobe technique provides high spatial resolution which enables more reliable results. In the case of pyrites analysed from the abandoned Au–Cu–As Radzimowice deposit results of isotopic sulphur are close to δ34S = 0‰ (weighted average of δ34S for sample 10B is +0.84 ±0.24‰, n = 60, for sample M20 +0.37 ±0.13‰, n = 35, and for sample M21 –0.03 ±0.32‰, n = 26), which indicates the source of sulphur from processes related to magmas probably of mantle or lower crust origins. On the other hand pyrites from the old mining prospect in Leszczyniec have negative δ[sup]34[/sup]S values below –1‰ (ranging from –3.24 ±0.08‰ to –1.19 ±0.09‰), which suggest a contaminationprocess and possible minor input of sedimentary protolith during the magma generation.

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Zircon U-Pb ages of granitoid apophyses in the western part of the Kłodzko–Złoty Stok Granite Pluton (SW Poland)

Mikulski S.Z., Williams I. S.

Geological Quarterly

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2014

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Vol. 58, No. 2

251--262

EN

Granitoids from the Graniec–Bardo and Myszak apophyses of the Kłodzko–Złoty Stok (KZS) Granite Pluton that intrude the Upper Paleozoic flysch of the Bardo Unit have zircon U-Pb ages, measured by SHRIMP, of 341.6 ± 2.8 Ma and 341.4 ± 2.2 Ma, respectively. These results augment our previous dating that recorded a short period of Middle Mississippian (Visean) hypabyssal magmatism that produced a variety of KZS igneous rocks of different compositions between ca. 341 and 331 Ma. The Graniec–Bardo and Myszak apophyses belong to the earliest stage of the pluton emplacement. Geochemical and petrographic studies of the dated samples indicate that they are biotite- and hornblende-rich tonalite and syenogabbro of diverse composition and typical of rocks originating from hybrid magmas formed in the geotectonic transition from an early stage collisional granitoid emplacement to its fast orogenic uplift. The polymetallic auriferous ore mineralisation of contact metasomatic type found in intimate contact with the Graniec–Bardo apophysis near Bardo Śląskie may also be of Visean age.

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Zircon U-Pb dating of igneous rocks in the Radzimowice and Wielisław Złotoryjski auriferous polymetallic deposits, Sudetes, SW Poland

Mikulski S. Z., Williams I. S.

Annales Societatis Geologorum Poloniae

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2014

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Vol. 84, No. 3

213--233

EN

A rhyolite porphyry in the Radzimowice deposit at Bukowinka Hill has a SHRIMP zircon U-Pb age of 314.9 ± 3.1 Ma. This is consistent with previous zircon dating of a monzogranite and a rhyodacite (ca. 315 Ma) in the Żeleźniak sub-volcanic intrusion (ZI), considered to be the igneous rocks, representing the oldest magmatic pulses in the region. First-stage mesothermal auriferous sulphide mineralization in the deposit was connected to hydrothermal processes, associated with the rhyodacite intrusions. This was followed by tectonic activity and younger alkaline magmatism in a post-collisional geotectonic setting. The first-stage Au-bearing sulphide mineralization was cataclased and overprinted by younger epithermal base-metal sulphides with microscopic Au, associated with Bi-Te-Ag minerals. The younger magmatic pulses are represented by porphyritic andesites and lamprophyric dykes, which cut the ZI. Zircon from these dykes yielded ages of 312.8 ± 2.8 Ma for an andesite porphyry and 312.4 ± 4 Ma for a lamprophyre. All these magmatic pulses, evidenced in the Radzimowice deposit, are considered to be the oldest post-orogenic sub-volcanic magmatism cutting the basement of the intramontane basins in the Sudetes, on the NE margin of the Bohemian Massif. A rhyolite porphyry in the famous 'Organy' exposure at Wielisław Złotoryjski (WZ) on the SE margin of the North-Sudetic Basin is younger, 297.5 ± 2.8 Ma. Vein-type auriferous ore mineralization, hosted by Early Palaeozoic graphitic schists in intimate contact with rhyolite porphyry in WZ, is also correlated with this magmatism. The auriferous ore mineralization at Radzimowice and Wielisław Złotoryjski formed at different times, during different magmatic pulses and successive hydrothermal stages, despite several similarities in geologic setting and country- and host-rock compositions. There was a transition from a post-collisional to a within-plate setting over about 20 Ma in Late Carboniferous-Early Permian times, with the older Żeleźniak and Bukowinka sub-volcanic intrusions in the uplifted part of the Kaczawa Metamorphic Complex (ZI) and the younger Wielisław Złotoryjski sub-volcanic intrusion in the metamorphic basement of an intramontane basin.

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Late Svecofennian sedimentary basins in the crystalline basement of NE Poland and adjacent area of Lithuania: ages, major sources of detritus, and correlations

Krzeminska E., Wiszniewska J., Skridlaite G., Williams I. S.

Geological Quarterly

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2009

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Vol. 53, No 3

255-272

EN

The Pre cam brian base ment of Lith u a nia and NE Po land, much of which is metasedimentary paragneiss, can be ac cessed only by cores from deep bore holes. Ion microprobe dat ing of de tri tal zir cons from sam ples of these meta sedi ments and the geo chem i cal sig na tures of the rocks pro vide new in sights into their age and prov e nance. De tri tal zir cons from meta sedi ments from Jastrzebna and Monki have Pb iso to pic ages in the ranges 3.14–1.83 and 3.53–1.82 Ga, re spec tively. Sim i lar re sults have been ob tained from the Lith u a nian Lazdijai and Bliudziai paragneisses. About 30% of the ana lysed Pol ish de tri tal zir con cores are of Late Archaean age (2.90–2.60 Ga) and about 70% are Palaeoproterozoic (2.10–1.90 Ga), sim i lar to the age dis tri bu tions of de tri tal zir con from Svecofennian meta sedi ments ex posed in Cen tral Swe den and South ern Fin land. The youn gest de tri tal zir con sub-groups in di cate max i mum de po si tion ages of about 1.86 Ga, sim i lar to the ages of ex posed Svecofennian sed i men tary bas ins. Pos si ble source rocks of com pa ra ble ages and af fin i ties can be found within Fennoscandia, Green land and Sarmatia.

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Wczesnokarboński wiek intruzji platformowych w podłożu krystalicznym NE Polski

Krzemińska E., Wiszniewska J., Williams I.S.

Przegląd Geologiczny

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2006

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Vol. 54, nr 12

1093-1098

EN

Three mafic-alkaline intrusive bodies in NE Poland: Ełk, Pisz and Tajno, have been dated recently with U-Pb SHRIMP method. An earlier Rb-Sr whole rock isochron of Ełk syenites pointed to an age 355š4 Ma, while K-Ar age estimates suggested a Late Paleozoic age of Pisz and Tajno rocks, however, in a wide range between 349-291 Ma and 327-289 Ma, respectively. In the paper, we present new geochronological results and discuss the problem of the closure temperatures for different minerals and different isotopic systems used in previous age determinations. Much of the early dating works has been done using K-Ar method. Biotite and K-feldspar retain radiogenic Ar quantitatively below 280 -200şC. Only if magmatic bodies cooled quickly and remained unmetamorphosed, K-Ar and Rb-Sr ages estimate accurately the intrusion emplacement. Zircon used for U-Pb datings has a closure temperature over 800şC, that is comparable to the temperature of magma’s solidus. Therefore U-Pb magmatic zircons dates could be interpreted as an intrusion emplacement ages. The obtained U-Pb results of 347.7 š8 Ma (Ełk) and 345.5š5 Ma (Pisz) have shown very consistent Early Carboniferous age of platform mafic-alkaline magmatic activity. This new U-Pb SHRIMP dating indicates that Ełk and Pisz intrusions are coeval and together with the Tajno alkaline-carbonatite massif could be affined with the Late Devonian Kola Alkaline Carbonatite Province (KACP).

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Rewizja wieku "najstarszych" skał w podłożu krystalicznym północno-wschodniej Polski

Krzemińska E., Wiszniewska J., Williams I.S.

Przegląd Geologiczny

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2006

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Vol. 54, nr 11

967-967, 973

EN

The oldest geochronological results between 2.69–2.57 Ga was previously obtained by using K–Ar method on biotite from pegmatite from Jastrzębna IG–1 borehole. In consequence, in many published reports up to 1998, the Mazowsze (or Masovian) granitoid massif has been regarded as Archean age structure. Therewithal, other rocks in the area, e.g. Bargłów gneiss sequence traditionally were described as Archean in age. In the paper we present new U–Pb SHRIMP zircon and monazite results for above mentioned rocks which have been considered as Archean. Cathodoluminescence images and SHRIMP analysis were carried out for zircons and monazites from Jastrzebna IG–1 pegmatite of 514 m depth (a historical sample previously dated by K–Ar method) and for zircon magmatic cores from Bargłów IG–2 orthogneiss of the 708 m depth. The obtained U–Pb ages of 1826 š12 Ma (zircon) and 1789š34 Ma (monazite), and 1835š28 Ma (zircon) for two rock samples respectively have shown Paleoproterozoic origin. Only 4 of the 24 analysed zircons have clearly discordant results, which are all from the Jastrzebna pegmatite, where Pb–loss was possible (in partially metamict U–rich zircon grains). The new U–Pb SHRIMP dating indicates that Jastrzębna pegmatite and Bargłów magmatic protolith of the orthogneiss is only Late Paleoproterozoic in age and in general about 700 Ma younger than previously reported by K–Ar method. Therefore, there is no unequivocal evidence of the presence of Archean rocks in crystalline basement of NE Poland. This study has been undertaken as a part of a collaborative research agreement between the Polish Geological Institute and Geochronology and Isotope Geochemistry Research School of Earth Sciences of the Australian National University in Canberra.