1,2-Dinitroguanidine (DNG), (1), is a novel explosive with reported high performance and moderate sensitivity [1, 2]. Synthesis of DNG and its salts has recently been reported [3]. X-ray studies on the crystal structure of DNG and its thermal stability can also be found in the literature [4, 5]. In this paper, complementary studies on the synthesis, reactivity and thermal characteristics of this compound and some of its derivatives are presented.
2
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In this paper, the synthesis of two energetic plasticisers (2,2-dinitro-1,3-bis(2-azido acetoxy) propane and 2,2-dinitro-1 ,3-bis(formyloxy)propane is outlined. The attempted syntheses of even further derivatives are described. The prepared compounds were characterised and evaluated as plasticisers. Their glass transition temperatures are acceptable to excellent, but both of them are thermally unstable.
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