Wyniki wyszukiwania - BazTech

1

Synthesis and Antimicrobial Activities of Novel Palladium (II) Complexes of Active Schiff’s Base Ligand Derived from 5-Bromo Isatin

Patange A. N., Yadav U. M., Desai P. A., Singare P. U.

International Letters of Chemistry, Physics and Astronomy

|

2015

|

Vol. 52

22--27

EN

This paper presents the synthesis and antimicrobial studies of Palladium (II) complexes of ThioSemicarbazone Pd (L1H)2Cl2 and Semicarbazone Pd (L2H)2Cl2 derived from 5-Bromo Isatin. All complexes reported here had been characterised by1H NMR and IR spectral studies .the complexes are diamagnetic in nature and showing square planner geometry. The IR spectral data reveals that both the Schiff’s bases behave as bidentate ligands and are co-ordinated to Pd (II) metal through the sulfur and hydrogenic nitrogen atom. All the new synthesized compounds were screened for antibacterial activity against four of the test organisms like Bacillus pumilus, Micrococcus Lutes, E.coli, Salmonella abony.

2

Studies on Toxic Heavy Metals in Sediment Ecosystem of Mahim Creek near Mumbai, India

Singare P. U., Ferns S. E. L., Agharia E. R.

International Letters of Chemistry, Physics and Astronomy

|

2015

|

Vol. 43

62--70

EN

The present study was performed for the period of one year from June 2012 to May 2013 in order to understand the level of toxic heavy metals in the sediments of Mahim Creek near Mumbai. The annual average concentration of heavy metals like Pb, Cd, Cr, Zn, Cu, Ni and Hg was found to be 9.88, 2.33, 1.41, 33.31, 22.07, 32.21 and 32.06 ppm respectively. It is feared that this heavy metals accumulated in the creek sediments might affect the benthic macro invertebrates whose metabolic activities contribute to aquatic productivity. The results of present study indicates that the existing situation if mishandled can cause toxic effect on sediment dwelling organisms and fish, resulting in decrease survival, reduced growth, or impaired reproduction and lowered species diversity.

3

Studies on Sediment Physico-Chemical Properties of the Ulhas River Flowing along Dombivli City near Mumbai

Jadhav A. M., Singare P. U.

International Letters of Chemistry, Physics and Astronomy

|

2015

|

Vol. 52

11--21

EN

Ulhas River which is one of the most polluted rivers of Mumbai receives heavy pollution load from the nearby Dombivali industrial belt. Previous studies reported along the Dombivali industrial belt has indicated that the pollution level is so much alarming that it has created threat to nearby residential areas and also to the Ulhas River flowing in the outskirts of the Dombivali City. It is feared that the toxic chemicals present in the industrial waste might affect the sediment ecosystem of the river. Hence this has provoked us to carry the systematic and detailed study of physico chemical properties of the sediment samples collected along the Ulhas River. The study was done during the year 2012 and 2013, at the sites where the industrial discharge from Dombivli industrial belt Phase I and Phase II joins the Ulhas River. The study was performed to understand the physico chemical properties such as pH, alkalinity, chloride and phosphates. Results of the study reveal that there is an urgent requirement for systematic and regular monitoring of pollution level along the Ulhas River which will further help in improving the industrial waste treatment procedure adopted, along the Dombivli industrial belt. It is expected that such scientific studies will be useful to determine the extent of pollution control measures required in order to avoid long term irreparable damage to the Ulhas River ecosystem.

4

Thermodynamics of uni-univalent H+/K+ and uni-bivalent H+/Ca2+ ion exchange reactions using nuclear grade resin Indion-223

Singare P. U., Mohammed A. L. K., Dixit N. N.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 14, iss. 2

190-198

EN

The present paper deals with the thermodynamic of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223. It was observed that with rise in temperature the equilibrium constants K values for H+/K+ uni-univalet ion exchange reaction increases from 0.01710 to 0.02374. Similarly for H+/Ca2+ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in K values with rise in temperature for both the reactions indicates its endothermic nature having the enthalpy change values of 22.72 and 38.92 kJ/ mol respectively. The technique used here can be extended further to standardise the process parameters in order to bring about the efficient separation of the desired ionic species from the solution.

5

Thermodynamics of Ion-exchange reaction in predicting the ionic selectivity of Auchlite ARA-9366 and Auchlite A-378 anion exchange resins

Singare P. U., Patange A. N.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 6

1--7

EN

The paper deals with predicting the iodide ion selectivity of nuclear and non-nuclear grade anion exchange resins. The ionic selectivity prediction was made on the basis of thermodynamic data of Clˉ/I ˉ ion exchange reaction. It was observed that with rise in temperature from 30.0 °C to 45.0 °C, the equilibrium constant (K) values were observed to decreases from 59.77x10-2 to 23.77x10-2 for Auchlite ARA-9366 resins and from 9.01x10-2 to 4.05x10-2 for Auchlite A-378 resins. The decrease in K values with rise in temperature, indicate exothermic ion exchange reactions having enthalpy values of -47.87 and -39.51 kJ/mol respectively. The high K and low enthalpy values obtained for Auchlite ARA-9366 resins indicate their greater selectivity for the iodide ions in the solution as compared to Auchlite A-378 resins, when both the resins are present in chloride form.

6

Thermodynamic study to evaluate the selectivity behaviour of nuclear grade resin Indion-223 towards some univalent ions

Singare P. U., Mohammed A. L. K., Dixit N. N.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 15

22--29

EN

The present paper deals with the application of thermodynamic concept in understanding the preferential selectivity of nuclear grade anion exchange resin Indion-223 in H+ form towards Na+ and K+ ions in the solution. In the study it was observed that the equilibrium constants K values for H+/Na+ and H+/K+ uni-univalet ion exchange reactions increases from 0.01389 to 0.01855 and from 0.01710 to 0.02374 respectively as the temperature increases from 35.0 °C to 45.0 °C. The increase in K values with rise in temperature suggests endothermic ion exchange reactions having the enthalpy change values of 25.55 and 22.72 kJ/ mol respectively. Based on difference in K values and enthalpy values for the two uni-univalent ion exchange reactions, the preferential selectivity of the resin for the univalent ions in the solution was predicted. From the results of present study, it appears that the experimental technique used here can be applied further to understand the ionic selectivity of different industrial grade ion exchange resins. It is expected that such studies will provide valuable information in order to decide about the selection of those resins for efficient separation of various ionic species present in the industrial waste water effluents.

7

Study on preferential selectivity of nuclear grade resin Indion-223 towards some bivalent ions

Singare P. U., Mohammed A. L. K., Dixit N. N.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 15

11--21

EN

In the present paper attempts are made to understand the selectivity of nuclear grade cation exchange resin Indion-223 in H+ form towards Ca2+ and Mg2+ bivalent ions in the solution based on thermodynamic concept. It was observed that with rise in temperature the equilibrium constant K values for H+/Ca2+ uni-bivalet ion exchange reactions increases from 0.000397 to 0.000639. Similarly for H+/Mg2+ uni-bivalet ion exchange reactions the equilibrium constant K values increases from 0.000177 to 0.000333. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 38.92 and 51.46 kJ/ mol respectively. The difference in K values and enthalpy values were used to predict the selectivity behaviour of the resin towards the Ca2+ and Mg2+ bivalent ions in the solution. The thermodynamic concept of the present study can be applied to understand the selectivity behaviour of different nuclear as well as non-nuclear grade resins towards wide range of ionic species present in the exchanging liquid medium.

8

Study on Halide Ions Selectivity of Nuclear Grade Anion Exchange Resin Auchlite ARA-9366

Singare P. U., Patange A. N.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 11, iss. 1

67-73

EN

The selectivity behaviour of nuclear grade anion exchange resin Auchlite ARA-9366 in chloride form towards iodide and bromide ions in the solution was studied. The trend in selectivity of the resin was predicted on the basis of thermodynamics of Clˉ/Iˉ and Clˉ/Brˉ uni-univalent ion exchange reactions. It was observed that the equilibrium constants K values for Clˉ/Iˉ ion exchange reaction were higher than that calculated for Clˉ/Brˉ exchange under identical experimental conditions. Also the enthalpy values for the two uni-univalent ion exchange reactions were calculated as -47.87 and -36.14 kJ/mol respectively. The high K and low enthalpy values obtained for Clˉ/Iˉ ion exchange reaction as compared to that obtained during Clˉ/Brˉ exchange supports higher selectivity of the resin towards iodide ions as compared to that towards bromide ions, when both the ions are present in the same solution.

9

Study on Halide Ions Selectivity of Industrial Grade Anion Exchange Resin Auchlite A-378

Singare P. U., Patange A. N.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 11, iss. 1

44-50

EN

The thermodynamic approach was applied to predict the trend selectivity of industrial grade anion exchange resin Auchlite A-378 in chloride form towards iodide and bromide ions in the solution. The study was conducted by performing the Clˉ/Iˉ and Clˉ/Brˉ uni-univalent ion exchange reactions under gradually increasing temperature conditions. The thermodynamic equilibrium constants K values were used to calculate the enthalpies of the two uni-univalent ion exchange reactions. It was observed that the K values for Clˉ/Iˉ ion exchange reaction were higher than Clˉ/Brˉ exchange reaction under identical experimental conditions. Also the enthalpy values for the two uni-univalent ion exchange reactions were calculated as -39.51 and -18.38 kJ/mol respectively. The high K and low enthalpy values obtained for Clˉ/Iˉ ion exchange reaction is responsible for higher selectivity of the resin towards iodide ions as compared to that towards bromide ions, when both the ions are present in the same solution.

10

Study of uni-univalent H+/K+ and uni-bivalent H+/Mg2+ ion exchange reactions using nuclear grade resin Indion-223

Singare P. U., Mohammed A. K. L., Dixit N. N.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 14, iss. 2

231-239

EN

In the present paper the uni-univalent and uni-bivalent ion exchange reactions were investigated using nuclear grade anion exchange resin Indion-223 in H+ form. For both H+/K+ uni-univalet ion exchange reactions and H+/Mg2+ uni-bivalet ion exchange reactions, the equilibrium constant K values increases from 0.01710 to 0.02374 and from 0.000177 to 0.000333 respectively as the reaction temperature rises from 35.0 °C to 45.0 °C. The increase in K values with temperature suggest endothermic ion exchange reactions having the enthalpy change values of 22.72 and 51.46 kJ/ mol respectively. The results of such studies will help in selection of suitable ion exchange resins in order to bring about efficient separation of different ionic species present in the waste water effluents released from nuclear as well as chemical process industries.

11

Study of Toxic Heavy Metals in Mahim Creek of Mumbai

Singare P. U., Ferns S. E. L.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 17, iss. 1

98--106

EN

The present study was performed for the period of one year from June 2012 to May 2013 in order to understand the level of toxic heavy metals in the water of Mahim Creek near Mumbai. It was observed that the annual average concentration of heavy metals like Pb, Cd, Cr, Fe, Zn, Cu and Ni and Hg was found to be 0.68, 0.28, 0.15, 0.04, 2.93, 0.64, 1.29 and 0.31 ppm respectively. The average concentrations of Hg and Pb were found to be above the maximum permissible limit of 0.01 ppm and 0.1 ppm respectively set for inland surface water by Central Pollution Control Board (CPCB) of India. The results suggest that there is a need to have such regular scientific monitoring for longer time period in order to understand the variation in level of these toxic heavy metals discharged in to the creek water. It is feared that the existing problem if ignored may increase the pollution problem of the creek due to the toxic heavy metals resulting in threat to the biological life of an aquatic ecosystem. From the results of the present investigation it seems that the time has come to move towards ecosystem specific discharge standards to maintain the health and productivity of natural resources on which the majority of human population is dependent.

12

Studies on Pollution due to discharge of effluent from Pharmaceutical Industries of Dombivali Industrial Belt of Mumbai, India

Singare P. U., Dhabarde S. S.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 3

16-23

EN

The paper deals with monitoring of pollution arising due to pharmaceutical based industries located along the Dombivali industrial belt of Mumbai, India. The study was carried for the period of one year from June, 2012 to May, 2013 to study the level of toxic heavy metals and the physico-chemical properties of waste water effluents discharged from the above industries. The concentration level of majority of toxic heavy metals like Cu, Cr, Pb, Fe and Zn were found to be maximum of 14.06, 0.57, 0.42, 18.93 and 3.31 ppm respectively in the month of February, while Ni concentration was found to be maximum of 0.43 ppm in the month of June. The pH and BOD values were reported to be maximum of 12.54 and 546 ppm respectively in the month of October. The conductivity and total solid content was found to be maximum of 27400 μmhos/cm and 9401 ppm respectively in the month of June. The cyanide content was maximum of 0.13 ppm in the month of April. The alkalinity, hardness, salinity, chloride, phosphate and COD content was reported maximum of 852, 694, 10.36, 4821, 46.32 and 1271 ppm respectively in the month of February. The DO content was found to be minimum of 3.00 ppm in the month of February. It was observed that the level of many of these toxic heavy metals except Zn and various physico-chemical parameters were above the tolerable limit set for inland surface water. From the results of the present investigation it seems that the time has come to move towards ecosystem specific discharge standards to maintain the health and productivity of natural resources on which the majority of Indians are dependent.

13

Studies on pollution discharge scenario of effluents released from fine chemicals manufacturing industries along Dombivali industrial belt of Mumbai, India

Singare P. U., Dhabarde S. S.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 3

56-63

EN

The paper deals with monitoring of pollution arising due to fine chemicals manufacturing industries located along the Dombivali industrial belt of Mumbai, India. The study was carried for the period of one year from June, 2012 to May, 2013 to study the level of toxic heavy metals and the physico-chemical properties of waste water effluents discharged from the above industries. The concentration levels of heavy metals like Cu, Ni, Cr, Pb, Fe and Zn was found to be maximum of 45.94, 1.05, 7.50, 4.76, 145.87 and 21.96 ppm respectively in the effluents released during the months of February to April. The majority of physco-chemical parameters like alkalinity, salinity and chloride content were found to be maximum in the month of October having the concentration values of 1482, 4.91, 2710 ppm respectively, while the DO content in the effluents released in the same month was reported to be very much low having the value of 2.90 ppm. The effluents released during the month of June were reported to have high hardness, total solid (TS) content and COD values of 3713, 13638 and 6951 ppm respectively. The cyanide content (0.08 ppm), phosphate content (131.32 ppm) and BOD content (631 ppm) were found to be maximum in the months of December, February and May respectively. From the results it appears that as India moves towards stricter regulation of industrial effluents to control water pollution, greater efforts are required to reduce the risk to public health as toxic pollutants which are mainly colourless and odourless can be expected to be released into the ecosystems.

14

Pollution Scenario due to discharge of effluent from Agrochemicals and Pesticides Manufacturing Industries of Dombivali Industrial Belt of Mumbai, India

Singare P. U., Dhabarde S. S.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 3

8-15

EN

The paper deals with monitoring of pollution arising due to agrochemicals and pesticides manufacturing industries located along the Dombivali industrial belt of Mumbai, India. The study was carried for the period of one year from June, 2012 to May, 2013 to study the level of toxic heavy metals and the physico-chemical properties of waste water effluents discharged from the above industries. The average concentration of Cu, Ni, Cr, Pb and Zn was found to be maximum of 29.86, 0.90, 1.16 and 1.19 ppm respectively in summer season, while average Fe concentration was maximum of 51.10 ppm in winter season. The average pH value of the effluent was found to be maximum of 12.95 in summer season, while average conductivity value was maximum of 21085 μmhos/cm in rainy season. The majority of physco-chemical parameters like alkalinity, hardness, salinity, chloride, cyanide, phosphate, total solid, BOD and COD content were found to be maximum in summer season having the average values of 1918, 186, 4, 11.20, 0.07, 81, 6391, 685 and 2556 ppm respectively. The average DO content was found to be low of 4.5 ppm in winter season. It was observed that the concentration level of majority of the toxic heavy metals and physico-chemical properties were above the tolerable limit set for inland surface water. The results of present study indicates that the existing situation if mishandled can cause irreparable ecological harm in the long term well masked by short term economic prosperity due to extensive industrial growth.

15

Pollution due to Textile Industries along Dombivali Industrial Belt of Mumbai, India

Singare P. U., Dhabarde S. S.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 3

24-31

EN

The paper deals with monitoring of pollution arising due to textile based industries located along the Dombivali industrial belt of Mumbai, India. The study was carried for the period of one year from June, 2012 to May, 2013 to study the level of toxic heavy metals and the physico-chemical properties of waste water effluents discharged from the above industries. The concentration level of majority of toxic heavy metals like Cu, Ni, Pb, and Zn were reported to be maximum of 45.58, 2.00, 2.06 and 9.20 ppm respectively in the month of April, while Cr and Fe concentration levels were found to be 2.50 and 55.30 ppm in the month of March. The effluent samples collected in the month of July was reported to show high BOD content of 564 ppm, while COD content was maximum of 2436 ppm in the month of October. The effluent samples collected in the month of January was having very low DO content of 3.21 ppm and high cyanide content of 0.09 ppm. The alkalinity, hardness and chloride content were maximum of 2158, 198 and 2765 ppm respectively in the effluent samples collected in the month of February. The effluents were having high total solid content of 8269 ppm during the month of April, while the salinity and phosphate contents were reported high of 5.64 and 125.70 ppm during the month of May. It was observed that the concentration level of majority of toxic heavy metals and the values of various physico-chemical parameters were above the tolerable limit set for inland surface water. The present experimental data on environmental risk assessment studies due to textile industries may be regarded as an aid towards a better understanding of the problem arising due to such industries. There is a need to convey the message that prevention of adverse health effects and promotion of health are profitable investments for employers and employees as a support to a sustainable development of economics.

16

Pollution discharge Scenario of Oil and Surfactants Manufacturing Industries along Dombivali Industrial Belt of Mumbai, India

Singare P. U., Dhabarde S. S.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 3

32-39

EN

The paper deals with monitoring of pollution arising due to oil and surfactants manufacturing industries located along the Dombivali industrial belt of Mumbai, India. The study was carried for the period of one year from June, 2012 to May, 2013 to study the level of toxic heavy metals and the physico-chemical properties of waste water effluents discharged from the above industries. The maximum concentration of majority of heavy metals like Cu, Ni, Cr, Pb and Fe were recorded as 13.48, 3.90, 13.30, 1.75 and 15.89 ppm respectively, which were above the tolerable limit set for inland surface water. The maximum pH and conductivity values of the industrial waste water effluent were recorded as 10.05 and 27800 μmhos/cm respectively. The majority of physico-chemical parameters like chloride, cyanide, phosphate and total solid content were found to be maximum in the month of March having the respective values of 2340, 0.09, 35.2 and 8755 ppm. The effluent samples collected in the month of May was found to have low DO content of 3.33 ppm and high BOD content of 643 ppm. The alkalinity and COD values were reported to be maximum of 1988 and 4410 ppm respectively in the month of February. The hardness and salinity content was reported maximum of 131 and 5.76 ppm during the month of December and June respectively. The results of present research work indicates that time has come to move towards ecosystem specific discharge standards to maintain the health and productivity of natural resources on which the majority of Indians are dependent.

17

Pollution discharge Scenario of Metallurgical Industries along Dombivali Industrial Belt of Mumbai, India

Singare P. U., Dhabarde S. S.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 3

40-47

EN

The paper deals with monitoring of pollution arising due to metallurgical industries located along the Dombivali industrial belt of Mumbai, India. The study was carried for the period of one year from June, 2012 to May, 2013 to study the level of toxic heavy metals and the physico-chemical properties of waste water effluents discharged from the above industries. The concentration levels of Cu, Ni, Cr, Pb, Fe and Zn were found to be maximum of 41.00, 1.47, 5.97, 2.55, 46.86 and 12.97 ppm respectively during winter and summer seasons starting from December to May. The pH value was found to be maximum of 10.30 in the month of February, while the conductivity was found to be maximum of 25067 μmhos/cm in the month of July. The majority of physco-chemical parameters like salinity, chloride content, and total solids (TS) were observed to be maximum in the month of June having values of 6.32, 2411 and 20738 ppm respectively. The high cyanide (0.09 ppm), phosphate (117.21 ppm), COD (13640 ppm) and low DO content of 5.79 ppm were observed in the effluents released during the month of February. The alkalinity content in the effluent was maximum of 1395 ppm in the month of May. The hardness and BOD values of the effluents were reported maximum of 490 and 557 ppm in the month of October. From the results of the present investigation it seems that the time has come to implement proper effluent water treatment techniques and enforcement of pollution control by the regulatory authority on the indiscriminate discharge of industrial wastewater into water bodies.

18

Ion-exchange reaction thermodynamics to study the selectivity behaviour of nuclear and non-nuclear grade anion exchange resins

Singare P. U., Patange A. N.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 6

8--15

EN

In the present investigation, attempts were made to understand the difference in bromide ion selectivity of the two closely related anion exchange resins Auchlite ARA-9366 and Auchlite A-378 in chloride form. The selectivity difference was predicted based on the thermodynamic equilibrium constants and enthalpy values of Clˉ/Brˉ ion exchange reactions performed by using the two resins. During Clˉ/Brˉ exchange reactions, with rise in temperature from 30.0 °C to 45.0 °C, the equilibrium constant (K) values were observed to decreases from 8.15x10-2 to 6.06x10-2 for Auchlite ARA-9366 resins and from 2.16x10-2 to 1.10x10-2 for Auchlite A-378 resins. The decrease in K values with rise in temperature, indicate exothermic ion exchange reactions having enthalpy values of -36.14 and -18.38 kJ/mol respectively. The high K and low enthalpy values obtained for Auchlite ARA-9366 resins indicate their greater selectivity for the bromide ions in the solution as compared to Auchlite A-378 resins.

19

Ion exchange equilibrium studies of uni-univalent H+/Na+ and uni-bivalent H+/Mg2+ ion exchange reactions using nuclear grade resin Indion-223

Singare P. U., Mohammed A. L. K., Dixit N. N.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 14, iss. 2

199-207

EN

In the present investigation the uni-univalent and uni-bivalent ion exchange reactions were studied using nuclear grade anion exchange resin Indion-223 in H+ form. It was observed that for H+/Na+ uni-univalet ion exchange reaction, with rise in temperature the equilibrium constants K values increases from 0.01389 to 0.01855. Similarly increase in K values was observed from 0.000177 to 0.000333 for H+/Mg2+ uni-bivalet ion exchange reaction. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 25.55 and 51.46 kJ/ mol respectively. It is expected that the present study will provide valuable information in order to decide about the selection of those resins for efficient separation of various ionic species present in the industrial waste water effluents.

20

Comparative study of uni-univalent H⁺/Na⁺ and uni-bivalent H⁺/Ca²⁺ ion exchange reactions using nuclear grade resin Indion-223

Singare P. U., Mohammed A. L. K., Dixit N. N.

International Letters of Chemistry, Physics and Astronomy

|

2014

|

Vol. 14, iss. 2

127-135

EN

The present paper deals with the ion exchange equilibrium studies of uni-univalent and uni-bivalent ion exchange reactions using nuclear grade anion exchange resin Indion-223 in H⁺ form towards Na⁺ and Ca²⁺ ions in the solution. It was observed that with rise in temperature the equilibrium constants K values for H⁺/Na⁺ uni-univalet ion exchange reaction increases from 0.01389 to 0.01855. Similarly for H⁺/Ca²⁺ uni-bivalet ion exchange reaction the equilibrium constants K values increases from 0.000397 to 0.000639. The increase in equilibrium constant values with rise in temperature indicate endothermic ion exchange reactions having the enthalpy change values of 25.55 and 38.92 kJ/ mol respectively.