The aim of the research was to initially assess the changes in the physicochemical composition of water in the reservoirs of the city moat (Wrocław) in the context of the analysis of the type of pollutants flowing into the inner-city water reservoirs and in relation to the impact of air quality directly in the vicinity of the reservoirs. As an element of the urban landscape, the inner-city water reservoirs play an important role in improving the local climatic conditions, increasing the biodiversity of the landscape, and eliminating the negative impact of urban heat islands. The measurement campaign was conducted for 11 months. The following parameters were determined in the analyzed water samples: turbidity, pH, electrolytic conductivity, as well as concentrations of nitrogen forms (ammonium nitrogen, nitrite nitrogen, and nitrate nitrogen), total phosphorus and sulfates. Additionally, the air quality parameters in the direct location of the reservoirs were analyzed, including: concentrations of nitrogen oxides, nitrogen dioxide, sulfur dioxide, humidity level and selected meteorological data, i.e. daily precipitation and average daily air temperature. The average concentrations of nitrogenous forms in the waters of the downtown water reservoir were as follows: ammonium nitrogen 0.155 mg•dm-3, nitrite nitrogen 0.084 mg•dm-3, and nitrate nitrogen 1.15 mg•dm-3. The sulfate concentrations showed greater variability 67.805–180.973 mg•dm-3. On the basis of the conducted observations and analyses, a statistically significant relationship was found between the quality parameters of water in municipal water reservoirs and external factors such as air quality, and in particular the correlation of air humidity with the concentration of nitrite and nitrate ions in the water. The conducted research confirms the influence of air quality on the levels of pollutants in the waters collected in the urban water reservoir.
The paper deals with the problem of wastewater treatment with specific physicochemical composition (increased ammonium nitrogen concentration) which were generated in Motor Rest Areas (MRA). Conventional biological wastewater treatment systems with activated sludge were used to purify the wastewater from sanitary equipment used in MRA. On the basis of the research conducted on four MRA, an attempt was made to determine the impact of the wastewater quality on biological wastewater treatment processes. The wastewater supplied to the treatment system was characterized by predominance of biologically non-degradable organic matter (average BOD/ COD ratio 4.39 – 10.42) as well as high concentration of ammonium nitrogen 273.9 – 334.55 mgN-NH4/dm3. The wastewater alkalinity determined by high content of ammonium nitrogen had a negative impact on the biological treatment processes. Unequal pollution load and temporary, high hydraulic load caused leaching of solid suspension from settling tank as well as leaching of particles of activated sludge from the reactor’s chamber. The lack of organic matter susceptible to biological decomposition makes it difficult to develop the biocenosis of activated sludge, and the limits of ammonium nitrogen concentration inhibit the nitrification processes.
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