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1 Bulletin of the Polish Academy of Sciences. Chemistry

1 2002

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129Xe NMR of adsorbed xenon and 1H NMR imaging: new methods to study the diffusion of gaseous hydrocarbons in a fixed bed of zeolite

N'Gokoli-Kekele P., Springuel-Huet M.-A., Bonardet J.-L., Dereppe J.-M., Fraissard J.

Bulletin of the Polish Academy of Sciences. Chemistry

2002

Vol. 50, No. 2

249-258

129Xe NMR of adsorbed xenon used as a probe and (1)H NMR imaging have been used to study the diffusion of hydrocarbons (benzene, n-hexane, paraxylene) during their adsorption or desorption in a fixed bed of zeolite crystallites. The simulation of experimental (129)Xe spectra using the nonuniform or the shrinking core models gives the concentration profiles of hydrocarbons, in the bed and in the zeolite crystallites, during their adsorption and leads to intracrystalline diffusion coefficients in good agreement with the literature. The (1)H NMR imaging allows one to visualize the progression of the diffusing molecules in the zeolite bed and also to determine their intracrystalline diffusion coefficients in the simplest cases.