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Reactive separation (RS) is the combination of a chemical (catalytic) reaction and a separation technique. For reactive distillation (RD), the reaction is combined with distillation. Rapid development of RS is the result of growing environmental demands and increasing energy costs. Several processes are performed using RD, such as esterification, etherification (fuel antiknocks), and hydrodesulphurisation. Other RS techniques also develop rapidly. However, the success has not come without some serious problems. The heterogeneous proton catalysts still do not meet the requirements of many processes. The column internals with a built-in catalyst are rather sparse and expensive and their characteristics are not studied well enough. Therefore intensive studies are still being performed. This study presents a brief summary of the processes realisable with the usage of reactive distillation, catalysts, and column internals. Some interesting research results and application examples are also quoted.
Czasopismo
Rocznik
Tom
Strony
11--20
Opis fizyczny
Bibliogr. 23 poz., rys., tab.
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autor
autor
autor
autor
- Institute of Chemical Engineering Polish Academy of Sciences, Bałtycka 5, 44-100 Gliwice, ask@iich.gliwice.pl
Bibliografia
- [1] Backhaus A.A., U.S. 1,400,849 (1921).
- [2] Backhaus A.A., U.S. 1,403,224 (1922).
- [3] Krishna R., 2002. Chem. Eng. Sci. 57, 1491.
- [4] Higler A., Taylor R., Krishna R., 1997. Proceedings of the AIChE Annual Meeting, Los Angeles, California.
- [5] Huang C., Yang L., Ng F.T.T., Rempel G.L., 1998. Chem. Eng. Sci. 53, 3489.
- [6] Pöpken T., Geisler R., Götze L., Brehm A., Moritz P., Gmehling J., 1999. Chemie Ingenieur Technik 71, 96.
- [7] Xu Z.P., Chuang K.T., 1997. Chem. Eng. Sci 52, 3011.
- [8] Taylor R., Krishna R., 2000. Chem. Eng. Sci. 55, 5183.
- [9] Ellenberger J., Krishna R., 1999. Chem. Eng. Sci. 54, 1339.
- [10] Van Gulijk C., 1998. Computers Chem. Eng. 22, S767.
- [11] Xu X., Zhao Z., Tian S., 1997. Trans. IchemE 75, 625.
- [12] Kreul L.U., Górak A., Dittrich C., Barton P.I., 1998. Computers Chem. Eng. 22, S371.
- [13] Moritz P., Hasse H., 1999. Chem. Eng. Sci. 54, 1367.
- [14] Götze L., Bailer O., Moritz P., von Scala C., 2001. Catalysis Today 69, 201.
- [15] Kolodziej A., Jaroszynski M., Hoffmann A., Gorak A., 2001. Catalysis Today 69, 115.
- [16] „Intelligent column internals for reactive separations”. Web-page summarizing the INTINT project [Internet]. Available from: http://www.cpi.umist.ac.uk/intint [Accessed 26 January 2002].
- [17] Kołodziej A., Jaroszyński M., Sałacki W., Orlikowski W., Frączek K., Klöker M., Kenig E., Górak A., 2004. Chem. Eng. Res. Design 82 (A2), 129.
- [18] Miesiąc I., Alejski K., Kaczor A., 2006. Przem. Chem. 85, 627.
- [19] Vargas-Villamil F.D., Marroquin J.O., de la Paz C., Rodriguez E., 2004. Chem. Eng. Process. 43, 1309.
- [20] Zielińska-Nadolska I., Warmuziński K., Richter J., 2005. Catalysis Today 114, 226.
- [21] Mrowiec-Bialon J., Szymanska K., Maresz K., 2004. Inz. Chem. Proc. 25, 1367.
- [22] Lebens P.J.M., Heiszwolf J.J., Kapteijn F., Sie S.T., Moulijn J.A., 1999. Chem. Eng. Sci. 54, 5119.
- [23] Jaroszyński M., Bylica I., Kołodziej A., Górak A., Janus B., 2008. Chem. Process Eng. 29, 623-637.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BAT8-0018-0009