Synthesis, structure and Magnetic Property of a New Neodymium-Adipate Coordination Polymer with Large Guest Molecules

• Autorzy: Duan L. , Ye L. , Liu Y. , Xie F. , Yu J. , Xu J.
• Języki publikacji: EN

Abstrakty

EN

A new lanthanide-adipate coordination polymer, Nd2(ad)3(H2O)4](H2ad)_4H2O}n (1) (H2ad = adipic acid), has been hydrothermally synthesized and structurally characterized by X-ray single crystal structure analysis, elemental analysis, infrared spectrum, thermogravimetric analysis and temperature-dependent magnetic susceptibility. The three-dimensional structure of compound 1 is based on edge-sharing NdO8(H2O)2 polyhedron chains, which were interconnected by twisted or extended carbon chains of the adipate ligands in [010] and [001] directions, respectively. The network contains large channels with adipic acid and lattice water acting as guest molecules. Above 50 K, the magnetic susceptibility data of 1 can be fitted to the Curie-Weiss law with teta = - 41.0 K and c = 3.52 emu Kmol-1.

Słowa kluczowe

EN

neodymium compound; adipic acid; guest molecules; hydrothermal synthesis

• Wydawca: Polskie Towarzystwo Chemiczne
• Czasopismo: Polish Journal of Chemistry
• Rocznik: 2005
• Tom: Vol. 79 / nr 12
• Strony: 1835--1842
• Opis fizyczny: Bibliogr. 18 poz.

Twórcy

autor

Duan L.

• State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, P. R. China
• College of Chemistry, Inner Mongolia University for Nationalities, Tongliao 028000, P. R. China

autor

Ye L.

• State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, P. R. China
• Key Laboratory of Supramolecular Structure and Materials of Ministry of Education, Jilin University, Changchun 130012, P. R. China

autor

Liu Y.

• State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, P. R. China
• College of Chemistry, Inner Mongolia University for Nationalities, Tongliao 028000, P. R. China

autor

Xie F.

• State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, P. R. China

autor

Yu J.

• State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, P. R. China

autor

Xu J.

• State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130023, P. R. China

Bibliografia

• 1.Liang Y., Cao R., Su W., Hong M.C. and Zhang W., Angev. Chum Int. Ed., 39, 3304 (2000).
• 2.Ma L.. Evans O.R., Foxman B.M. and Lin W., Inorg. Chem., 38, 5837 (1999).
• 3.Serpaggi F. and Ferey G., J. Mater. Chem., 8, 2749 (1998).
• 4.Lengendziewicz J.. Borzechowska M., Oczko G. and Meyer G., New J. Chem., 24, 53 (2000).
• 5.Cao R., Sun D.F.. Liang Y.C., Hong M.C., Tazuyuki K. and Shi Q., Inorg. Chem., 41, 2087 (2002).
• 6.Wu C.D., Lu C.Z., Yang W.B., Lu S.F., Zhuang H.H. and Huang J.S., Eur. J. Inorg. Chem., 797 (2002).
• 7.Scrrc C., Millange F., Marrot J. and Ferey G., Chem. Mater., 14, 2409 (2002).
• 8.Reineke T.M., Eddaoudi M., KeelTe M.O. and Yaghi O.M., Angew. Chem. Int. Ed., 38, 2590 (1999).
• 9.Sun D.F., Cao R., Liang Y.C., Shi Q. and Hong M.C., J. Chem. Soc., Dalton Trans., 1847 (2002).
• 10.Zhang X.J., Jin L.P. and Lu S.Z., Eur. J. Inorg. Chem., 3356 (2002).
• 11.Pan L., Huang X.Y., Li J., Wu Y.G. and Zheng N.W., Angew. Chem. Int. Ed., 39, 527 (2000).
• 12.Wang Z., JinC.M., ShaoT., Li Y.Z., Zhang K.L. and You X.Z., Inorg. Chem. Commun., 5,642 (2002).
• 13.Kiritsis V., Michaelides A., Skoulika S., Golhen S. and Ouahab L., Inorg. Chem., 37, 3407 (1998).
• 14.Dimos A., TsaousisD., Michaelides A., Skoulika S., Golhen S., Ouahab L., Didierjean C. and Aubry A., Chem. Mater., 14, 2616 (2002).
• 15.Kim Y., Suh M. and Jung D.Y., Inorg. Chem., 43, 245 (2004).
• 16.Sun Z.G., Ren Y.P., Long L.S., Huang R.B. and Zheng L.S., Inorg. Chem. Commun., 5, 629 (2002).
• 17.Lauren A.B. and Christopher L.C., Inorg. Chem. Commun., 7, 725 (2004).
• 18.Duan L.M., Xu J.Q., Xie F.T., Liu Y.B. and Ding H., Inorg. Chem.Commun., 7, 216 (2004).