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Laser aerosol time-of-flight mass spectrometry analysis of individual aerosol particles from photooxidation of toluene

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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
A laser aerosol time-of-flight mass spectrometry (ATOFMS) that can be used for real-time measurement of the size and composition of individual aerosol particles has been designed and manufactured in our laboratory. Particles are introduced into the instrument through a particle beam interface, sized by measuring the delay time between two scattering lasers, and compositionally analyzed using a laser desorption/ionization linear-time-of-flight mass spectrometry. Secondary organic aerosol particles from the photooxidation of toluene in the CH3ONO/NO/air mixture were generated in a home-made smog chamber and measured using it. Experimental results showed that the individual aerosol particles from photooxidation of toluene can be measured in real-time by this instrument. This unique capability is impossible in off-line methods such as chromatography and chemical method.
Czasopismo
Rocznik
Strony
5--13
Opis fizyczny
Bibliogr. 23 poz.,
Twórcy
autor
autor
autor
autor
autor
  • Laboratory of Environment Spectroscopy, Anhui Institute of Optics and Fine Mechanics, The Chinese Academy of Sciences, 230031 Hefei, China
Bibliografia
  • [1] SONG C., NA K., COCKER D.R., Impact of the hydrocarbon to NOx ratio on secondary organic aerosol formation, Environmental Science and Technology 39(9), 2005, pp. 3143–9.
  • [2] JANG M., KAMENS R.M., Characterization of secondary aerosol from the photooxidation of toluene in the presence of NOx and 1-propene, Environmental Science and Technology 35(18), 2001, pp. 3626–39.
  • [3] ATKINSON R., Atmospheric chemistry of VOCs and NOx, Atmospheric Environment 34(12–14), 2000, pp. 2063–101.
  • [4] SUH I., ZHANG R.Y, MOLINA L.T., MOLINA M.J., Oxidation mechanism of aromatic peroxy and bicyclic radicals from OH–toluene reactions, Journal of the American Chemical Society 125(41), 2003, pp. 12655–65.
  • [5] FORSTNER H.J.L., FLAGAN R.C., SEINFELD J.H., Secondary organic aerosol from the photooxidation of aromatic hydrocarbons: molecular composition, Environmental Science and Technology 31(5), 1997, pp. 1345–58.
  • [6] SUH I., ZHANG D., ZHANG R.Y., MOLINA L.T., MOLINA M.J., Theoretical study of OH addition reaction to toluene, Chemical Physics Letters 364(5–6), 2002, pp. 454–62.
  • [7] SATO K., KLOTZ B., HATAKEYAMA S., IMAMURA T., WASHIZU Y., MATSUMI Y., WASHIDA N., Secondary organic aerosol formation during the photo-oxidation of toluene: dependence on initial hydrocarbon concentration, Bulletin of the Chemical Society of Japan 77(4), 2004, pp. 667–71.
  • [8] ODUM J.R., HOFFMANN T., BOWMAN F., COLLINS D., FLAGAN R.C., SEINFELD J.H., Gas/particle partitioning and secondary organic aerosol yields, Environmental Science and Technology 30(8), 1996, pp. 2580–5.
  • [9] STROUD C.A., MAKAR P.A., MICHELANGELI D.V., MOZURKEWICH M., HASTIE D.R., BARBU A., HUMBLE J., Simulating organic aerosol formation during the photooxidation of toluene/NOx mixtures: comparing the equilibrium and kinetic assumption, Environmental Science and Technology 38(5), 2004, pp. 1471–9.
  • [10] EDNEY O., DRISCOLL D.J., WEATHERS W.S., KLEINDIENST T.E., CONVER T.S., MCIVER C.D., LI W., Formation of polyketones in irradiated toluene/propylene/NOx /air mixtures, Aerosol Science and Technology 35(6), 2001, pp. 998–1008.
  • [11] KLEINDIENST E., CONVER T.S., MCIVER C.D., ENDEY E.O., Determination of secondary organic aerosol products from the photooxidation of toluene and their implications in ambient PM2.5, Journal of Atmospheric Chemistry 47(1), 2004, pp. 79–100.
  • [12] JAOUI M., KLEINDIENST T.E., LEWANDOWSKI M., EDNEY E.O., Identification and quantification of aerosol polar oxygenated compounds bearing carboxylic or hydroxyl groups. 1. Method development, Analytical Chemistry 76(16), 2004, pp. 4765–78.
  • [13] SUESS D.T.PRATHER K.A., Mass spectrometry of aerosols, Chemical Reviews 99(10), 1999, pp. 3007–35.
  • [14] PRATHER K.A., NORDMEYER T., SALT K., Real-time characterization of individual aerosol particles using time-of-flight mass spectrometry, Analytical Chemistry 66(9), 1994, pp. 1403–7.
  • [15] NORDMEYER T., PRATHER K.A., Real-time measurement capabilities using aerosol time-of-flight mass spectrometry, Analytical Chemistry 66(20), 1994, pp. 3540–2.
  • [16] GARD E., MAYER J.E., MORRICAL B.D., DIENES T., FERGENSON D.P., PRATHER K.A., Real-time analysis of individual atmospheric aerosol particles: design and performance of a portable ATOFMS, Analytical Chemistry 69(20), 1997, pp. 4083–91.
  • [17] SILVA P.J., PRATHER K.A., Interpretation of mass spectra from organic compounds in aerosol time-of-flight mass spectrometry, Analytical Chemistry 72(15), 2000, pp. 3553–62.
  • [18] SU Y., SIPIN M.F., FURUTANI H., PRATHER K.A., Development and characterization of an aerosol time-of-flight mass spectrometer with increased detection efficiency, Analytical Chemistry 76(3), 2004, pp. 712–9.
  • [19] XIA Z.-H., FANG L., ZHENG H.-Y., HU R., ZHANG Y.Y., KONG X.-H., GU X.-J., ZHU Y., ZHANG W.-J., BAO J., XIONG L.-Y., Real-time measurement of the aerodynamic size of individual aerosol particles, Acta Physica Sinica 53(1), 2004, pp. 320–4.
  • [20] XIA Z.-H., FANG L., ZHENG H.-Y., KONG X.-H., ZHOU L.-Z., GU X.-J., ZHU Y., ZHANG W.-J., Real-time measurement of chemical compositions of individual aerosol particles, Chinese Journal of Analytical Chemistry 32(7), 2004, pp. 973–6.
  • [21] NIE J.S., QIN M., YANG Y., ZHANG W.-J., The structure and performance of a kind of photo chemical smog chamber, Chinese Journal of Atomic and Molecular Physics 19, 2002, pp. 179–83.
  • [22] LIU D.Y., WENZEL R.J., PRATHER K.A., Aerosol time-of-flight mass spectrometry during the Atlanta supersite experiment: 1. Measurements, Journal of Geophysical Research 108(D7), 2003, pp. SOS14-1–16.
  • [23] AYRES R.U., AYRES L.W., The life-cycle of chlorine, part IV: accounting for persistent cyclic organo-chlorines, Journal of Industrial Ecology 3(2–3), 2000, pp. 121–59.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BPW4-0008-0001
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