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Concentration of selected natural radionuclides in the thermal groundwater of Uniejów, Poland

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EN
Activities of the main radionuclides from the 238U and 232Th series in the Uniejów geothermal water were determined by combining liquid scintillation counting with a/b separation and g-spectrometry methods. The 222Rn and 226Ra activities were measured after extraction of radon from 10 ml water samples to 10 ml of an Ultima Gold F scintillation cocktail directly in 22 ml scintillation vials. The samples were counted in a new generation portable liquid scintillation counter, Betascout, without separation of the phases over the period of 30 days after extraction. The average values of the specific activities were equal to 2.95 and 0.64 Bq/dm3 for 222Rn and 226Ra, respectively. The 210Po radionuclide before counting was preconcentrated from 1 dm3 water samples on hydrated manganese oxide and deposited on silver discs. The discs were immersed in 10 ml of the scintillator and their activity was measured also by the same method. The average 210Po concentration was 0.052 Bq/dm3. Activity of the remaining radionuclides was determined by g-spectrometry after their preconcentration on hydrated manganese oxides from 10 dm3 samples. The activities of two radium radionuclides, 224Ra and 226Ra, can be calculated from their basic gamma-lines, whereas 228Ra can be determined from its decay product - 228Ac, and were equal to 0.40, 0.65 and 0.58 Bq/dm3, respectively. The activities of 210Pb and 238U (234Th) were below the detection limit of the method equal to 0.03 Bq/dm3. Based upon the obtained results, it can be concluded that there are not any radiological restrictions for using this water as a heat source or for balneological purposes. However, it cannot be used as drinking water, because the calculated committed effective dose from its one year consumption exceeds the WHO recommended value of 0.1 mSv.
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1--5
Opis fizyczny
Bibliogr. 21 poz., rys.
Twórcy
autor
  • Institute of Applied Radiation Chemistry, Technical University of Lódź, 116 Żeromskiego Str., 90-924 Lódź, Poland, Tel.: +48 42/ 631 31 95, Fax: +48 42/ 636 50 08
autor
  • Institute of Applied Radiation Chemistry, Technical University of Lódź, 116 Żeromskiego Str., 90-924 Lódź, Poland, Tel.: +48 42/ 631 31 95, Fax: +48 42/ 636 50 08
autor
  • Institute of Applied Radiation Chemistry, Technical University of Lódź, 116 Żeromskiego Str., 90-924 Lódź, Poland, Tel.: +48 42/ 631 31 95, Fax: +48 42/ 636 50 08
Bibliografia
  • 1. Atlas of geothermal energy resources in the Polish Lowland (1995) Górecki W (ed.) ZSE AGH, Towarzystwo Geosynoptyków GEOS, Kraków (in Polish)
  • 2. Baradacs E, Hunyadi I, Dezso Z, Csige I, Szerbin P (2001) 226Ra in geothermal and bottled mineral waters of Hungary. Radiat Meas 34:385−390
  • 3. Bem H, Bem EM, Majchrzak I (1998) Comparison of two methods for 226Ra determination in mineral water. Nukleonika 43;4:459−468
  • 4. Bujakowski W (1999) Geothermal projects in Poland. Technika Poszukiwań Geologicznych Geosynoptyka i Geotermia 4/5:132−141
  • 5. De Oliveira J, Mazzilli B, De Oliveira Sampa MH, Silva B (1998) Seasonal variations of 226Ra and 222Rn in mineral spring waters of Aquas da Prata, Brazil. Appl Radiat Isot 49;4:423−427
  • 6. Dickson BL (1990) Radium in ground water. In: The environmental behaviour of radium. Vol. 1. IAEA, Vienna, pp 335−372
  • 7. Gellermann R, Wiegand J, Funke L, Gerler J (2000) Mineral water with anomalous radium concentration from the orthern Harz Mountain region. In: Proc of the 5th Int Conf on High Levels of Natural Radiation and Radon Areas held n Münich, 4−7 September 2000, Germany. Bundesamt für Strahlenschutz, Salzgitter, vol. 2, pp 83−86
  • 8. Guidelines for drinking-water quality (1993) Vol. 1. Recommendations, 2nd ed. WHO, Geneva
  • 9. Guidelines for drinking-water quality (2003) 3rd ed. http://www.who.int/docstore/water_sanitation_health/GDWQ/Updating/draftguidel/draftchap9.htm
  • 10. Kępińska B (2002) Thermal springs and spas in Poland. Geo-Heat Center Bulletin 3:10−17
  • 11. Kozłowska B, Hetman A, Dorda J, Zipper W (2001) Radonenriched spring waters in the South of Poland. Radiat Phys Chem 61;3/6:677−678
  • 12. Nieri NA, Mazzilli B (1998) Evaluation of 210Po and 210Pb in some mineral spring waters in Brazil. J Environ Radioact 41:11−18
  • 13. Pietruszko SM, Wiśniewski G, Chwieduk D, Wnuk R (1996) Potential of renewable energies in Poland. Renewable Energy 9:1124−1126
  • 14. Przylibski TA, Dorda J, Kozłowska B (2002) The occurrence of 226Ra and 228Ra in groundwaters of the Polish Sudety Mountains. Nukleonika 47;2:59−64
  • 15. Przylibski TA, Kozłowska B, Dorda J, Kiełczawa B (2002) 222Rn and 226Ra concentrations in mineralized groundwaters of Gorzanow (Klodzko Basin, Sudeten Mountains, SW Poland). J Radional Nucl Chem 253:1−19
  • 16. Rihs S, Condomines M (2002) An improved method for Raisotope (224Ra, 226Ra, 228Ra) measurements by gamma spectrometry in natural water. Chem Geol 182:409−421
  • 17. Regulation of Polish Minister of Health (2002) Dziennik Ustaw of 5th December 2002, 02.203.1718
  • 18. Skwarzec B (1997) Radiochemical method for the determination of polonium, radiolead, uranium and plutonium in environmental samples. Chem Anal 42:117−122
  • 19. Sokołowski J (1993) Geothermal resources of Poland and possibility of their utilisation in environmental protection. Technika Poszukiwań Geologicznych Geosynoptyka i Geotermia 5/6:67−80
  • 20. Sturchio NC, Banner JL, Binz CM, Heraty LB, Musgrove M (2001) Radium geochemistry of ground waters in Paleozoic carbonate aquifers, mid-continent, USA. Appl Geochem 16:109−122
  • 21. Żak A, Jankowski J, Brzozowski R (1999) Natural radioactivity of underground water. Medycyna Pracy 1:51−60 (in Polish)
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-article-BUJ6-0005-0040
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