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Hydrogeochemical modelling of chloride mineral water from Rabka spa (Carpathian Mountains, Poland)

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Treść / Zawartość
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Warianty tytułu
Języki publikacji
EN
Abstrakty
EN
Rabka has resources of chloride water, currently accessible in nine boreholes with depths from 20 to 1215 m. The waters are of the Cl-Na+I+(Fe) type, and in the Rabka IG 2 borehole of the Cl-Na+I+21°C type, while their total dissolved solids (TDS) contents vary between 17.2 and 24.6 g/dm3. These therapeutic waters are associated with the Carpathian flysch strata of the strongly disturbed zone of tectonic contact between the Magura Nappe with the underlying Fore-Magura Group of units. This structure is also a trap for hydrocarbons, and so strong methane (CH4) emanations are present in Rabka both at the surface and in the boreholes providing mineral water. The strong tectonic disturbances of the study area considerably hinder the flow of underground water, extend the water resistance time at the water-rock contact and significantly limit the possibility of water exchange within the water-bearing system. Such conditions of hindered flow and limited water exchange control the unique chemical composition of the chloride water at Rabka. The components dissolved in these waters originate from the primary synsedimentary water (elision stage) accumulated in the rock matrix, from which they filter into the flow of water (infiltration stage) of various geneses, i.e., palaeoinfiltration, infiltration and dehydration, moving through the water-bearing system of the mineral water of Rabka. Modelling with the Geochemist’s Workbench Standard 8.0 program has demonstrated the proposed origin of the mineral water in Rabka.
Rocznik
Strony
681--690
Opis fizyczny
Bibliogr. 29 poz., rys., wykr.
Twórcy
autor
  • Faculty of Geology, Geophysics and Environment Protection, AGH University of Science and Technology, Mickiewicza 30, 30-059 Kraków, Poland
autor
  • Faculty of Geology, Geophysics and Environment Protection, AGH University of Science and Technology, Mickiewicza 30, 30-059 Kraków, Poland
Bibliografia
  • 1. BACOVA N. (2009) - Significance of the graphic analysis of hydrogeochemical data for interpretation of origin of mineral water of Flysch Belt and Foredeep of Western Carpathians (in Slovak with English summary). Miner. Slov., 41: 225-242.
  • 2. BETHKE C. (2008) - Geochemical and biogeochemical reaction modeling. 2nd ed. Cambridge University Press.
  • 3. BIRKENMAJER K. and OSZCZYPKO N. (1989) - Cretaceous and Paleogene lithostratigraphic units of the Magura Nappe, Krynica Subunit, Carpathians. Ann. Soc. Geol. Pol., 59 (1-2): 145-181.
  • 4. BORYSŁAWSKI A., OSZCZYPKO N. and TOMAŚ A. (1980) - Chemical composition of Carpathian saline waters - a statistical analysis. Biul. Państw. Inst. Geol., 323: 57-86.
  • 5. CHRZĄSTOWSKI J. (1965) - The phenomena of methane exhalations on the ground of geological structure in the health resort of Rabka (in Polish with English summary). Zesz. Nauk. AGH, 81 (6): 75-100.
  • 6. CHRZĄSTOWSKI J. (1969) - Wody mineralne Rabki. Spraw. Pos. Kom. PAN Oddz. w Krakowie, 13 (2): 576-580.
  • 7. CHRZĄSTOWSKI J. (1971) - Wody mineralne Szczawy na tle budowy geologicznej. Problemy zagospodarowania ziem górskich. Komitet Zagospodarowania Ziem Górskich PAN, 9: 100-136.
  • 8. DOMINIKIEWICZ M. (1951) - Wody mineralne Polski. Państw. Zakł. Wyd. Leśnych, Warszawa.
  • 9. DOWGIAŁŁO J. (1976) - Problems of the origin of Cl-HCO3-Na mineral waters of the Polish flysch Carpathians. In: Proceedings of the International Symposium on Water-Rock Interaction, Czechoslovakia 1974. Geological Survey, Prague: 12-22.
  • 10. DOWGIAŁŁO J. and SŁAWIŃSKI A. (1978) - Remarks on the origin of saline ground waters at Rabka. In: Hydrogeochemistry of Mineralized Waters (eds. B. Słowańska, Z. Pakulska): 195-203. Proceedings of the IAH Conference of Cieplice Spa (Poland), 1978. Inst. Geol., Warszawa.
  • 11. DREVER J. I. (1988) - The geochemistry of natural water. 2nd ed. Prentce-Hall.
  • 12. FRANCZUKOWSKI Z., ed. (2008) - The Great Book of Polish Spas, Seaside resorts and places with Spa-climatic Qualities (in Polish with English summary). Wyd. Mirex, Bydgoszcz.
  • 13. FRANKO O. and MICHALICEK M. (1982) - Jodobromove vody Slovenska. Zapadne Karpaty, seria hydrogeologia a inzinierska geologia. Geologický ústav Dionýza Stúra, Bratislava, 4: 97-133.
  • 14. KOZŁOWSKA-SZCZĘSNA B., ed. (2002) - Bioklimat uzdrowisk polskich i możliwości jego wykorzystania w lecznictwie. AN IG i PZ im. S. Leszczyckiego, Warszawa.
  • 15. LEŚNIAK P.M. and DOWGIAŁŁO J. (1986) - About genesis of chloride water in Carpathians. The polemics (in Polish with English summary). Prz. Geol., 34 (7): 394-398.
  • 16. MARCIN D. (2004) - Conditions of formation mineral waters in Sarissky Stiavnik and Radoma. Env. Geol., 46: 646-650.
  • 17. OSZCZYPKO N. (1991) - Stratigraphy of the Palaeogene deposits of the Bystrica Subunit (Magura Nappe, Poll sh Outer Carpathians). Bull. Pol. Acad. Sc., Earth Sc., 39: 415-431.
  • 18. OSZCZYPKO-CLOWES M. and OSZCZYPKO N. (2004) - The position and age of the youngest deposits in the Mszana Dolna and Szczawa tectonic windows (Magura Nappe, Western Carpathians, Poland). Acta Geol. Pol., 54: 339-407.
  • 19. OSZCZYPKO N. and ZUBER A. (2002) - Geological and isotopic evidence of diagenetic waler in the Polish Flysch Carpathians. Geol. Carpath., 53 (4): 1-13.
  • 20. OSZCZYPKO N., ŚLACZKA A. and ŻYTKO K. (2008) - Tectonic subdivision of Poland: Polish Outer Carpathians and their foredeep (in Polish with English summary). Prz. Geol., 56 (10): 927-935.
  • 21. PAUL Z. and RYŁKO W. (1986) - Szczegółowa mapa geologiczna Polski 1:50 000, ark. Rabka. Wyd. Geol., Warszawa
  • 22. PAUL Z. and RYŁKO W. (1987) - Objaśnienia do Szczegółowej mapy geologicznej Polski 1:50 000, ark. Rabka. Wyd. Geol., Warszawa, 1-89.
  • 23. RAJCHEL L (2009) - Occurrences and utilization of chloride waler in Rabka spa (in Polish with English summary). Geologia, 35 (2/1): 271-278.
  • 24. RAJCHEL L. (2011) - Utilization of geothermal water in the Rabka spa in Polish with English summary). In: Atlas of Geothermal Water and Energy Resources in the Western Carpathians (ed. W. Górecki): 148-151. Ministerstwo Środowiska.
  • 25. RAJCHEL L., ZUBER A., DULIŃSKI M. and RAJCHEL J. (2004) - Occurrences and genesis of chloride waters in Sól (S Poland) (in Polish with English summary). Prz. Geol., 52 (12): 1179-1186.
  • 26. ŚWIDZIŃSKI H. (1954) - Zagadnienia geologiczne wód mineralnych w szczególności na Niżu Polskim i w Karpatach. Materiały pozjazdowe Zjazdu Naukowo-Technicznego w Krynicy w roku 1954. Katowice: 33-73.
  • 27. ZAKOVIC M., POTFAJ M., FENDEK M. and BODIS D. (2009) - Iodine-brome groundwaler in the area of Oravska Polhora (in Slovak with English summary). Podzemna Voda, 15 (2/2009): 230-239.
  • 28. ZUBER A., ed. (2007) - Metody znacznikowe w badaniach hydrogeologicznych. Oficyna Wyd. PWroc., Wrocław.
  • 29. ZUBER A., CHOWANIEC J. and BOROWIEC M. (2010) - On the origin of chloride walers in the Polish Flysch Carpathians (in Polish with English summary). Biul. Państw. Inst. Geol., 441: 201-208.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-905991eb-a09c-4c5a-8749-ed3824e208f6
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