Dictyonema black shale and Triassic sandstones as potential sources of uranium

• Autorzy: Kiegiel K. , Zakrzewska-Kołtuniewicz G. , Gajda D. , Miśkiewicz A. , Abramowska A. , Biełuszka P. , Danko B. , Chajduk E. , Wołkowicz S.

Identyfikatory

DOI

10.1515/nuka-2015-0096

• Konferencja: International Conference on Development and Applications of Nuclear Technologies NUTECH 2014 (21-24.09.2014, Warsaw, Poland)
• Języki publikacji: EN

Abstrakty

EN

The main objective of the present study was an assessment of the possibility of uranium recovery from domestic resources in Poland. In the fi rst stage uranium was leached from the ground uranium ore by using acidic (sulfuric acid or hydrochloric acid) or alkaline (carbonate) solutions. The leaching efficiencies of uranium were dependent on the type of ore and it reached 81% for Dictyonemic shales and almost 100% for sandstones. The novel leaching routes, with the application of the helical membrane contactor equipped with rotating part were tested. The obtained postleaching solutions were concentrated and purifi ed using solvent extraction or ion exchange chromatography. New methods of solvent extraction, as well as hybrid processes for separation and purifi cation of the product, were studied. Extraction with the use of membrane capillary contactors that has many advantages above conventional methods was also proposed as an alternative purification method. The fi nal product U3O8 could be obtained by the precipitation of ‘yellow cake’, followed by calcination step. The results of precipitation of ammonium diuranate and uranium peroxide from diluted uranium solution were presented.

Słowa kluczowe

EN

uranium ores; leaching; extraction; ion-exchange chromatography; precipitation

• Wydawca: Institute of Nuclear Chemistry and Technology
• Czasopismo: Nukleonika
• Rocznik: 2015
• Tom: Vol. 60, No. 3, part 2
• Strony: 515--522
• Opis fizyczny: Bibliogr. 18 poz., rys.

Twórcy

autor

Kiegiel K.

• Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: [phone], Fax: [phone]

autor

Zakrzewska-Kołtuniewicz G.

• Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: [phone], Fax: [phone]

autor

Gajda D.

• Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: [phone], Fax: [phone]

autor

Miśkiewicz A.

• Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: [phone], Fax: [phone]

autor

Abramowska A.

• Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: [phone], Fax: [phone]

autor

Biełuszka P.

• Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: [phone], Fax: [phone]

autor

Danko B.

• Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: [phone], Fax: [phone]

autor

Chajduk E.

• Institute of Nuclear Chemistry and Technology, 16 Dorodna Str., 03-195 Warsaw, Poland, Tel.: [phone], Fax: [phone]

autor

Wołkowicz S.

• Polish Geological Institute-National Research Institute, 4 Rakowiecka Str., 00-975 Warsaw, Poland

Bibliografia

• 1. Ministry of Economy, Government Commissioner for Nuclear Energy. (2014). Program of Polish Nuclear Energy. Warsaw.
• 2. Uranium 2014: Resources, production and demand. (2014). A Joint Report by the OECD Nuclear Energy Agency and the International Atomic Energy Agency. Paris: OECD.
• 3. Strzelecki, R., & Wołkowicz, S. (2011). Uran. In S. Wołkowicz, T. Smakowski & S. Speczik (Eds.), Bilans perspektywicznych zasobów kopalin Polski wg stanu na 31 XII 2009 r. (pp. 71–75). Warsaw: PIG-PIB.
• 4. Miecznik, J. B., Strzelecki, R., & Wołkowicz, S. (2011). Uranium in Poland – history of prospecting and chances for fi nding new deposits. Prz. Geol., 59, 688–697.
• 5. Zakrzewska-Koltuniewicz, G., Herdzik-Koniecko, I., Cojocaru, C., & Chajduk, E. (2014). Experimental design and optimization of leaching process for recovery of valuable chemical elements (U, La, V, Mo and Yb and Th) from low-grade uranium ore. J. Hazard. Mater., 275, 136–145. DOI: 10.1016/j.jhazmat.2014.04.066.
• 6. Edwards, C. R., & Oliver, A. J. (2000). Uranium processing: A review of current methods and technology. JOM, Sept., 12–20.
• 7. Frąckiewicz, K., Kiegiel, K., Herdzik-Koniecko, I., Chajduk, E., Zakrzewska-Trznadel, G., Wołkowicz, S., Chwastowska, J., & Bartosiewicz, I. (2012).Extraction of uranium from low-grade Polish ores: dictyonemic shales and sandstones. Nukleonika, 58, 451–459.
• 8. Gajda, D., Kiegiel, K., Zakrzewska-Koltuniewicz, G., Chajduk, E., Bartosiewicz, I., & Wolkowicz, S. (2015). Mineralogy and uranium leaching of ores from Triassic Peribaltic sandstones. J. Radioanal. Nucl. Chem., 303, 521–529.
• 9. Chajduk, E., Bartosiewicz, I., Pyszynska, M., Chwastowska, J., & Polkowska-Motrenko, H. (2013). Determination of uranium and selected elements in Polish dictyonema shales and sandstones by ICP-MS. J. Radioanal. Nucl. Chem., 295, 1913–1919.
• 10. Ladeira, A. C. Q., & Gonçalves, C. R. (2007). Influence of anionic species on uranium separation from acid mine water using strong base resins. J. Hazard. Mater., 148, 499–504.
• 11. Kumar, J. R., Kim, J. -S., Lee, J. -Y., & Yoon, H. -S. (2011). A brief review on solvent extraction of uranium from acidic solution. Sep. Purif. Rev., 40, 77–125.
• 12. Zhu, Z., Pranolo, Y., & Cheng, C. Y. (2013). Uranium solvent extraction and separation from vanadium in alkaline solutions. Sep. Sci. Technol., 48, 1402–1408.
• 13. Hausen, D. M. (1998). Characterizing and classifying uranium yellow cakes: a background. JOM, Dec., 45–47.
• 14. Paik, S., Biswas, S., Bhattacharya, S., & Roy, S. B. (2013). Effect of ammonium nitrate on precipitation of ammonium di-uranate (ADU) and its characteristics. J. Nucl. Mater., 440, 34–38.
• 15. Zakrzewska-Trznadel, G., Jaworska-Sobczuk, A., Miśkiewicz, A., Łada, W., Dłuska, E., & Wroński, S. (2012). Method of obtaining and separation of valuable metallic elements, specifi cally from low grade uranium ores and radioactive liquid wastes. Patent Application No. 12196071.0-2122.
• 16. Biełuszka, P., Zakrzewska-Trznadel, G., Chajduk, E., & Dudek, J. (2014). Liquid-liquid extraction of uranium(VI) in the system with a membrane contactor. J. Radioanal. Nucl. Chem., 299, 611–619.
• 17. Pochopień, H., & Szyndler, K. (2013). Projekt procesowy instalacji pozyskiwania uranu z rud uranowych. Gliwice: Centrum Projektowe Polimex--Mostostal.
• 18. Analiza możliwości pozyskiwania uranu dla energetyki jądrowej z zasobów krajowych. Sprawozdanie z zadania 1-7, POIG.01.01.02-14-094/09 (Vol. 1-2). Konsorcjum: Instytut Chemii i Technologii Jądrowej i Państwowy Instytut Geologiczny-Państwowy Instytut Badawczy. Warsaw: IChTJ.