Germanate glasses co-doped with Ce3+/Ln3+ (Ln = Pr, Tb, Dy) for white light emitting diodes

• Autorzy: Górny Agata , Sołtys Marta , Pisarska Joanna , Pisarski Wojciech A.

Identyfikatory

DOI

10.5277/oa190301

• Języki publikacji: EN

Abstrakty

EN

Glasses doped with lanthanides ions may be good white light emitters due to their interesting physical and spectroscopic properties. In this paper, the optical spectroscopy of rare earths doped glasses with a special emphasis on application as white LED were presented. The luminescent glass materials containing Ln³⁺ (Ln = Pr, Tb, Dy) and Ce³⁺ ions were obtained. The glasses samples were prepared by a traditional melt-quenching technique. The optical properties of glasses containing various concentrations of rare earth ions were analyzed. It was observed that luminescence bands corresponding to characteristic transitions of Ln³⁺ and cerium ions are present on spectra measured under direct excitation of Ce³⁺. Therefore, it indicates that the energy transfer process between Ce³⁺ /Pr³⁺, Ce³⁺ /Tb³⁺, Ce³⁺ / Dy³⁺ ions in glasses occurs. Some parameters such as correlated color temperature (CCT) and chromaticity coordinates (CIE) that characterize white LEDs were analyzed and discussed in detail.

Słowa kluczowe

EN

glasses; rare earth ions; white luminescence

• Wydawca: Oficyna Wydawnicza Politechniki Wrocławskiej
• Czasopismo: Optica Applicata
• Rocznik: 2019
• Tom: Vol. 49, nr 3
• Strony: 383--391
• Opis fizyczny: Bibliogr. 30 poz., rys.

Twórcy

autor

Górny Agata

• University of Silesia, Institute of Chemistry, Katowice, Poland

autor

Sołtys Marta

• University of Silesia, Institute of Chemistry, Katowice, Poland

autor

Pisarska Joanna

• University of Silesia, Institute of Chemistry, Katowice, Poland

autor

Pisarski Wojciech A.

• University of Silesia, Institute of Chemistry, Katowice, Poland

Bibliografia

• [1] YU C., YANG Z., ZHAO J., ZHU J., HUANG A., QIU J., SONG Z., ZHOU D., Luminescence enhancement and white light generation of Eu3+ and Dy3+ single-doped and co-doped tellurite glasses by Ag nanoparticles based on Ag+-Na+ ion-exchange, Journal of Alloys and Compounds 748, 2018, pp. 717–729, DOI: 10.1016/j.jallcom.2018.03.191.
• [2] SHAMSHAD L., ROOH G., KIRDSIRI K., SRISITTIPOKAKUN N., DAMDEE B., KIM H. J., KAEWKHAO J., Photoluminescence and white light generation behavior of lithium gadolinium silicoborate glasses, Journal of Alloys and Compounds 695, 2017, pp. 2347–2355, DOI: 10.1016/j.jallcom.2016.11.105.
• [3] JHA K., JAYASIMHADARI M., Spectroscopic investigation on thermally stable Dy3+ doped zinc phosphate glasses for white light emitting diodes, Journal of Alloys and Compounds 688, 2016, pp. 833–840, DOI: 10.1016/j.jallcom.2016.07.024.
• [4] MUNGRA M., STEUDEL F., AHRENS B., SCHWEIZER S., Tm/Tb/Eu triple-doped lithium aluminoborate glass for white light generation, Journal of Luminescence 192, 2017, pp. 71–76, DOI: 10.1016/j.jlu min.2017.06.028.
• [5] MENDHE M.S., PUPPALWAR S.P., DHOBLE S.J., Novel single-component CaLaAlO4 :Tb3+, Eu3+ phosphor for white light emission, Optical Materials 82, 2018, pp. 47–55, DOI: 10.1016/j.optmat.2018.05.037.
• [6] LAYA KRISHNAN M., NEETHISH M.M., RAVI KANTH KUMAR V.V., Structural and optical studied of rare earth-free bismuth silicate glasses for white light generation, Journal of Luminescence 201, 2018, pp. 442–450, DOI: 10.1016/j.jlumin.2018.05.023.
• [7] LONG S., MA D., ZHU Y., YANG M., LIN S., WANG B., Temperature dependence of white light emission and energy transfer in Dy3+ and Tm3+ co-doped LiNbO3 single crystals, Journal of Luminescence 192, 2017, pp. 728–733, DOI: 10.1016/j.jlumin.2017.07.049.
• [8] LOVISA L.X., SANTIAGO A.A.G., FARIAS M.B., BARROS B.S., LONGO E., LI M.S., PASKOCIMAS C.A., BOMIO M.R.D., MOTTA F.V., White light emission from single-phase Y2MoO6:xPr3+ (x = 1, 2, 3 and 4 mol%) phosphor, Journal of Alloys and Compounds 769, 2018, pp. 420–429, DOI: 10.1016/j.jall com.2018.07.339.
• [9] JAMALAIAH B.C., PAKARDIN G., LOKESWARA REDDY G.V., VIJAYA KUMAR M.V., White light generation in Dy2O3- doped NBSAZB glasses, Optical Materials 73, 2017, pp. 545–549, DOI: 10.1016/j.opt mat.2017.09.009.
• [10] VIJAYALAKSHMI L., NAVEEN KUMAR K., SRINIVASA RAO K., HWANG P., Bright up-conversion white light emission from Er3+ doped lithium fluoro zinc borate glasses for photonic applications, Journal of Molecular Structure 1155, 2018, pp. 394–402, DOI: 10.1016/j.molstruc.2017.11.025.
• [11] TABANLI S., ERYUREK G., DI BARTOLO B., White light emission from Er2O3 nano-powder excited by infrared radiation, Optical Materials 69, 2017, pp. 207–213, DOI: 10.1016/j.optmat.2017.04.007.
• [12] SRIHARI T., JAYASANKAR C.K., Fluorescence properties and white light generation from Dy3+-doped niobium phosphate glasses, Optical Materials 69, 2017, pp. 87–95, DOI: 10.1016/j.optmat.2017.04.001.
• [13] MEZA-ROCHA A.N., SPEGHINI A., LOZADA-MORALES R., CALDINO U., Blue and white light emission in Tm3+ and Tm3+/Dy3+ doped zinc phosphate glasses upon UV light excitation, Optical Materials 58, 2016, pp. 183–187, DOI: 10.1016/j.optmat.2016.05.043.
• [14] SOŁTYS M., GÓRNY A., PISARSKA J., PISARSKI W.A., Lead borate glasses triply doped with Dy3+/Tb3+/ Eu3+ ions for white emission, Optical Materials 82, 2018, pp. 110–115, DOI: 10.1016/j.optmat.201 8.05.043.
• [15] ZHU Z., ZHANG Y., QIAO Y., LIU H., LIU D., Luminescence properties of Ce3+/Tb3+/Sm3+ co-doped CaO–SiO2 –B2O3 glasses for white light emitting diodes, Journal of Luminescence 134, 2013, pp. 724 –728, DOI: 10.1016/j.jlumin.2012.07.003.
• [16] BEI J., QIAN G., LIANG X., YUAN S., YANG Y., CHEN G., Optical properties of Ce3+-doped oxide glasses and correlations with optical basicity, Materials Research Bulletin 42(7), 2007, pp. 1195–1200, DOI: 10.1016/j.materresbull.2006.10.020.
• [17] KINDRAT I.I., PADLYAK B.V., MAHLIK S., KUKLIŃSKI B., KULYK Y.O., Spectroscopic properties of the Ce-doped borate glasses, Optical Materials 59, 2016, pp. 20–27, DOI: 10.1016/j.optmat.2016.03.053.
• [18] NAKAUCHI D., OKADA G., FUJIMOTO Y., KAWANO N., KAWAGUCHI N., YANAGIDA T., Optical and radiation-induced luminescence properties of Ce-doped magnesium aluminoborate glasses, Optical Materials 72, 2017, pp. 190–194, DOI: 10.1016/j.optmat.2017.05.063.
• [19] MALCHUKOVA E., BOIZOT B., Tunable luminescence from Ce-doped aluminoborosilicate glasses, Journal of Rare Earths 32(3), 2014, pp. 217–220, DOI: 10.1016/S1002-0721(14)60055-7.
• [20] ISOKAWA Y., HIRANO S., KAWANO N., OKADA G., KAWAGUCHI N., YANAGIDA T., Dosimetric and scintillation properties of Ce-doped Li3PO4-B2O3 glasses, Journal of Non-Crystalline Solids 487, 2018, pp. 1–6, DOI: 10.1016/j.jnoncrysol.2018.02.015.
• [21] KAWANO N., KAWAGUCHI N., OKADA G., FUJIMOTO Y., YANAGIDA T., Scintillation and dosimetric properties of Ce-doped strontium aluminoborate glasses, Journal of Non-Crystalline Solids 482, 2018, pp. 154–159, DOI: 10.1016/j.jnoncrysol.2017.12.030.
• [22] TORIMOTO A., MASAI H., OKADA G., KAWAGUCHI N., YANAGIDA T., Emission properties of Ce-doped alkaline earth borate glasses for scintillator applications, Optical Materials 73, 2017, pp. 517–522, DOI: 10.1016/j.optmat.2017.09.006.
• [23] ZUO CH., ZHOU Z., ZHU L., XIAO A., CHEN Y., ZHANG X., DING X., GE Q., Spectroscopic properties of Ce3+-doped borosilicate glasses under UV excitation, Materials Research Bulletin 83, 2016, pp. 155 –159, DOI: 10.1016/j.materresbull.2016.06.001.
• [24] ZUO C., XIAO A., ZHOU Z., CHEN Y., ZHANG X., DING X., WANG X., GE Q., Spectroscopic properties of Ce3+-doped BaO-Gd2O3-Al2O3-B2O3-SiO2 glasses, Journal of Non-Crystalline Solids 452, 2016, pp. 35–39, DOI: 10.1016/j.jnoncrysol.2016.08.016.
• [25] WEN J.-Q., ZHANG J.-M., QIU Z.-G., YANG X., LI Z.-Q., The investigation of Ce doped ZnO crystal: the electronic, optical and magnetic properties, Physica B: Condensed Matter 534, 2018, pp. 44–50, DOI: 10.1016/j.physb.2018.01.035.
• [26] NAKAUCHI D., KOSHIMIZU M., OKADA G., YANAGIDA T., Floating zone growth and scintillation properties of undoped and Ce-doped GdTaO4 crystals, Radiation Measurements 106, 2017, pp. 129–133, DOI: 10.1016/j.radmeas.2017.03.033.
• [27] TANG Y., ZHOU S., YI X., HAO D., SHAO X., CHEN J., The characterization of Ce/Pr-doped YAG phosphor ceramics for the white LEDs, Journal of Alloys and Compounds 745, 2018, pp. 84–89, DOI: 10.1016/j.jallcom.2018.02.129.
• [28] ZHANG Z., ZHANG Y., FENG Z., WANG C., XIA H., ZHANG X., Luminescent properties of Ce3+/Tb3+ co-doped glass ceramics containing YPO4 nanocrystals for W-LEDs, Journal of Rare Earths 34(5), 2016, pp. 464–469, DOI: 10.1016/S1002-0721(16)60050-9.
• [29] HE W., WANG X., ZHENG J., YAN X., Optical property of Dy3+- and Ce3+-doped Si-B-Na-Sr glasses, Journal of American Ceramics Society 97(6), 2014, pp. 1750–1755, DOI: 10.1111/jace.12973.
• [30] SOŁTYS M., GÓRNY A., ZUR L., FERRARI M., RIGHINI G.C., PISARSKI W.A., PISARSKA J., White light emission through energy transfer processes in barium gallo-germanate glasses co-doped with Dy3+-Ln3+ (Ln = Ce, Tm), Optical Materials 87, 2019, pp. 63–69, DOI: 10.1016/j.optmat.2018.05.071

Uwagi

PL

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).