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Kinetics of corrosion on the intermetallic phase matrix FeAl in high temperature

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Języki publikacji
EN
Abstrakty
EN
Purpose: Alloys on intermetallic phase matrix of iron and aluminium are considered the future materials for high-temperature applications as they are highly resistant to oxidation to temperature of 1100°C. The paper presents results of tests concerning kinetics of corrosion processes of alloy on intermetallic phase matrix FeAl type Fe40Al5CrTiB after vacuum casting and plastic treatment with the use of co-extrusion method and comparably for flameproof steel X12CrCoNi2120. Design/methodology/approach: Corrosion tests were conducted in gas environment including 0.08% SO2, 0.02% HCl, 9% O2 and nitrogen in temperature from 900°C to 1100°C in time of 100 hours. Kinetics of corrosion processes was marked, the condition of the surface of samples after tests was characterized with the use of electron scanning microscope and also the chemical composition of corrosion products was determined. Findings: It was stated, on the basis of tests results that the increase of weight of corrosion products in time function has a parabolic character, where the highest mass was weighed for samples after test conducted in temperature of 1100°C. A significantly higher corrosive resistance of alloys was found in comparison with the resistance of flameproof steel types CrNi with austenitic structure. Practical implications: The last feature is the reason to conduct the research for this group of materials as corrosion resistance materials. Especially FeAl intermetallic phase based alloys are objects of research in Poland and around the world in recent years. Originality/value: The aim of this paper was to determine the influence of passivation in gas environment including 0.08% SO2, 0.02% HCl, 9% O2 and nitrogen in temperature from 900°C to 1100°C in time of 100 hours on corrosion resistance of Fe40Al5CrTiB intermetallic phase based alloy.
Rocznik
Strony
7--14
Opis fizyczny
Bibliogr. 23 poz., rys., tab.
Twórcy
autor
  • Faculty of Materials Science and Metallurgy, Sielsian University of Technology, ul. Krasińskiego 8, 40-019 Katowice, Poland
autor
  • Faculty of Materials Science and Metallurgy, Sielsian University of Technology, ul. Krasińskiego 8, 40-019 Katowice, Poland
Bibliografia
  • [1] P.J. Maziasz, G.M. Goodwin, D.J. Alexander, S. Viswanathan, Nickel and iron aluminides, Processing, properties and applications, ASM International Materials, Park OH, 01997, 157.
  • [2] R. Viswanathan, J.F. Henry, J. Tanzosh, G. Stanko, J.P. Shingledecker, B. Vitalis, U.S. Program on materials technology for ultra supercritical stream coal - fired power plants, Materials for Advanced Power Engineering, Energy Technology 53 (2006) 893.
  • [3] M. Muller, Estimation of the risk of hot corrosion in gas turbines by thermodynamic modeling, Energy Materials: Materials Science and Engineering for Energy Systems 1/4 (2006) 223-226.
  • [4] M. Rozmus, Mechanical production of alloys on intermetallic phase matrix from Ti-Al-Nb system and their characteristics, PhD thesis, Cracow 2006 (in Polish).
  • [5] H.T. Wang, C.J. Li, G.J. Yang, C.X. Li, Effect of heat treatment on the microstructure and property of cold-sprayed nanostructure FeAl/Al2O3 intermetallic composite coating, Vacum 83 (2009) 146-152.
  • [6] M. Jabłońska, Tests of key mechanical properties of alloys in Fe-Al system, Metallurgical Engineering News 8 (2009) 124-128 (in Polish).
  • [7] M. Kupka, Structure and properties of alloys on phase matrix FeAl achieved in metallurgical processes, Publishing House of University of Silesia, 2005 (in Polish).
  • [8] M. Palm, G. Sauthoff, Deformation behavior and oxidation resistance of single-phase and two-phase L21-ordered Fe-Al-Ti alloys, Intermetallics 12 (2004) 1345-1359.
  • [9] T. Grosdidier, J.X. Zou, N. Stein, C. Boulanger, S.Z. Hao, C. Dong, Texture modification grain refinement and improved hardness/corrosion balance of a FeAl alloy by pulsed electron beam surface treatment in the “heating mode”, Scripta Materialia 58 (2008) 1058-1061.
  • [10] Z. Bojarski, W. Przetakiewicz, Metal materials with participation of intermetallic phase, Publishing House of BEL Studio, Warsaw, 2006 (in Polish).
  • [11] J. Xia, C.X. Li, H. Dong, Thermal oxidation treatment of B2 iron aluminide for improved wear resistance, Wear 258 (2005) 1804-1812.
  • [12] W.Z. Zhu, S.C. Deevi, Dispersion of iron aluminide with polyelectrolyte in water, Materials Research Bulletin 38 (2003) 1227-1233.
  • [13] L. Yuan, H.M. Wang, Hot corrosion behaviors of a Cr13Ni5Si2-based metal silicide alloy in Na2SO4+25 wt.% K2SO4 and Na2SO4+ 25wt.% NaCl molten salts, Intermetallics 18 (2010) 324-329.
  • [14] H. Shi, D. Guo, Y. Ouyang, Structural evolution of mechanically alloyed nanocrystalline FeAl intermetallics, Journal of Alloys and Compounds (2008) 207-209.
  • [15] J. Cebulski, S. Lalik, Changes in the structure of alloy on the matrix of FeAl intermetallic phase after primary crystallization and homogenizing treatment, Journal of Materials Processing Technology 162-163 (2005) 4-8.
  • [16] S.C. Deevi, V.K. Sikka, Nickel and iron aluminides, An overview on properties, processing and applications, Intermetallics 4 (1996) 357-375.
  • [17] J. Bystrzycki, R. A. Varin, Z. Bojar, Progress in testing alloys on the basis of ordered intermetallic phases with aluminium content, Materials Engineering 5 (1994) 137-149 (in Polish).
  • [18] D.J. Alexander, P.J. Maziasz, J.L. Wright, Processing and alloying effects on tensile and impact properties of FeAl alloys, Materials Science and Engineering A 258 (1998) 276-285.
  • [19] L.A. Dobrzański, Engineering materials and designing materials, The principles of materials sciences and physical metallurgy, Publishing House WNT, Warsaw, 2006 (in Polish).
  • [20] M. Kciuk, A. Kurc-Lisiecka, The influence heat treatment on structure, mechanical properties and corrosion resistance of steel X10CrNi18-8, Archives of Materials Science 55/2 (2012) 62-69
  • [21] J. Cebulski, S. Lalik, R. Michalik, Corrosion resistance of FeAl intermetallic phase based alloy in water solution of NaCl, Journal of Achievements in Materials and Manufacturing Engineering 27/ 1 (2008) 15-18.
  • [22] M. Jabłońska, I. Bednarczyk, E. Bernstock-Kopczyńska, Microstructural analysis of alloys from Fe-Al system by means of EBSD, Steel Research International 81/9 (2010) 274-277.
  • [23] M. Jabłońska, K. Rodak, G. Niewielski , Characterization of the structure of feal alloy after hot deformation, Journal of Achievements in Materials and Manufacturing Engineering 18/1-2 (2006) 107-110.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-443b882f-2e0f-431f-8067-47556b08311a
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