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A model of thermal-chemical interactions at the ceramic mould – molten nickel alloy interface was described. Studies were carried out on mould coated with a layer of modifier based on zirconium silicate and cobalt aluminate. The thermodynamic calculations indicated the possibility of chemical reactions taking place between the chemically active nickel alloy constituents (Al, Ti, Hf, Ta and Nb) and components of the modifying coating. The result of such interactions is possible formation on the surface of mould and casting of "new compounds" which can be the source of casting defects, like burns-on, pitting, etc., the fact proved by extensive X-ray microanalysis. In addition, the possibility of crack formation on mould surface and of the molten metal penetration into thus formed crevices was observed.
Czasopismo
Rocznik
Tom
Strony
5--8
Opis fizyczny
Bibliogr. 10 poz., rys., tab.
Twórcy
autor
- Silesian University of Technology, Chair of Materials Technology, Krasińskiego Str. 8, 40-019 Katowice, Poland
autor
- Silesian University of Technology, Chair of Materials Technology, Krasińskiego Str. 8, 40-019 Katowice, Poland
autor
- Silesian University of Technology, Chair of Materials Science, Krasińskiego Str. 8, 40-019 Katowice, Poland
Bibliografia
- [1] F. Zupanic, T. Boncina, A. Krizman, F.D. Tichelaar, Structure of continuously cast Ni-based superalloy Inconel 713C, Journal of Alloys and Compounds, volume 329, issue 1-2, November 14, 2001, pp. 290-297.
- [2] M.Tabuchi, K. Kubo, K. Yagi, A.T. Yokobori Jr, A. Fuji, Results of a Japanese round robin on creep crack growth evaluation methods for Ni-base superalloys, Engineering Fracture Mechanics, volume 62, issue 1, January 1999, pp. 47-60.
- [3] A. Smith, A. Mainwood, M. Watkins: The kinetics of the capture of nitrogen by nickel defects in diamond , Diamond and Related Materials, Volume 11, issue 3-6, March-June, 2002, pp. 312-315.
- [4] M. Lachowicz, Characteristics of microstructural changes and fracture mechanism during welding and heat treatment of Inconel 713C superalloy, Doctor’s Thesis, Wrocław University of Technology, 2006 (in Polish).
- [5] D. Hartman, U. Muerrle, G. Reber, The effects of electron beam refining on the cast ability of IN 713 C, Metall, 1992, nr 5, pp. 443-447.
- [6] F. Binczyk, J. Śleziona, J. Cwajna, S. Roskosz, ATD and DSC analysis of nickel super alloys, Archives of Foundry Engineering, Vol. 8, issue 3, 2008, pp. 5-9.
- [7] F. Binczyk, J. Śleziona, Macrostructure of IN-713C superalloy after volume modification, Archives of Foundry Engineering, Vol. 9, issue 2, 2009, pp.105-108.
- [8] F. Binczyk, J. Śleziona, Phase transformations and microstructure of IN-713C nickel superalloy, Archives of Foundry Engineering, Vol. 9, issue 2, 2009, pp.109-112.
- [9] F. Binczyk, J. Śleziona, A. Kościelna, Effect of modification and cooling rate on the macrostructure of IN-713C alloy, Archives of Foundry Engineering, Vol. 9, issue 3, 2009, pp.13-16.
- [10] A. Roine, HSC Chemistry Ver.(4), Copyright (C), Outokumpu Research Oy, Pori, Finland.
Typ dokumentu
Bibliografia
Identyfikator YADDA
bwmeta1.element.baztech-4da3dffb-427c-4698-a94e-b307a2ade92b