Synthesis, structure and properties of V(IV) complex with N’-[(E)-(2,3-dihydroxyphenyl)metylidene]-2- phenylacetohydrazide

• Autorzy: Szklarzewicz Janusz , Jurowska Anna , Hodorowicz Maciej , Gryboś Ryszard

Identyfikatory

DOI

10.5604/01.3001.0013.1484

• Języki publikacji: EN

Abstrakty

EN

The synthesis and physicochemical properties of new vanadium(IV) complex of formula [VO(L)(phen)] is described. The L denotes ONO tridentate Schiff base derived from 2,3-dihydroxybenzaldehyde and phenylacetic hydrazide, while phen = 1,10-phenanthroline used as a co-ligand to stabilize the V(IV) oxidation state. The single crystal X-Ray crystal structure indicates on octahedral geometry of vanadium centre, with 1,10-phenanthroline nitrogen trans to the V=O bond. The complex crystalizes in a monoclinic P21/c space group, very unusual is that only one isomer is present in the crystal structure. The structure is stabilized by very weak hydrogen bonds and H··π and π···π interactions. The phenyl ring of hydrazide is strongly curved from ONO ligand plane by 70.95˚. The spectroscopic characterization (IR, UV-Vis) as well as the cyclic voltammetry measurements are presented and discussed

Słowa kluczowe

EN

vanadium; complex; Schiff base; structure; 2,3-dihydroxybenzaldehyde; phenylacetic hydrazide

PL

wanad; kompleks; baza Schiffa; struktura; 2,3-dihydroksybenzaldehyd; hydrazyd fenylooctowy

• Wydawca: Państwowa Wyższa Szkoła Zawodowa w Tarnowie
• Czasopismo: Science, Technology and Innovation
• Rocznik: 2019
• Tom: Vol. 4, no. 1
• Strony: 1--8
• Opis fizyczny: Bibliogr. 38 poz., rys., tab.

Twórcy

autor

Szklarzewicz Janusz

• Jagiellonian University, Faculty of Chemistry, Gronostajowa 2, 30-387 Kraków, Poland

autor

Jurowska Anna

• Jagiellonian University, Faculty of Chemistry, Gronostajowa 2, 30-387 Kraków, Poland

autor

Hodorowicz Maciej

• Jagiellonian University, Faculty of Chemistry, Gronostajowa 2, 30-387 Kraków, Poland

autor

Gryboś Ryszard

• Jagiellonian University, Faculty of Chemistry, Gronostajowa 2, 30-387 Kraków, Poland

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Uwagi

Opracowanie rekordu w ramach umowy 509/P-DUN/2018 ze środków MNiSW przeznaczonych na działalność upowszechniającą naukę (2019).